Luminescence of irradiated lithium, sodium and magnesium fluorides nanocrystals: Formation of self-assembled structures and point defects with new properties

• Published in: Journal of luminescence Vol. 224; p. 117287
• Main Authors: Voitovich, A.P., Kalinov, V.S., Kostik, O.E., Lastovskii, S.B., Mashko, V.V., Novikov, A.N., Pushkarou, A.V., Stupak, A.P.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.08.2020
• Subjects: Intrinsic point defects; Lithium, sodium and magnesium fluorides; Nanocrystals; Photoluminescence; Self-assembled nanostructures; X-ray diffraction; X-ray diffraction; Intrinsic point defects; Nanocrystals; Lithium, sodium and magnesium fluorides; Self-assembled nanostructures; Photoluminescence
• ISSN: 0022-2313; 1872-7883
• DOI: 10.1016/j.jlumin.2020.117287

The luminescence and absorption properties of LiF, NaF and MgF2 nanocrystals containing radiation-induced point defects with new properties are investigated. The influence of temperature, at which nanocrystals are maintained after their manufacture, on the efficiency and kinetics of such defects formation is examined. For LiF samples, the activation energy of fotmation processes is determined. X-ray diffraction reflections are compared for LiF nanocrystals, unannealed and annealed after fabrication, unannealed and irradiated with γ-rays or electrons, as well as those manufactured by fragmentation of an irradiated crystal plate. Conclusions are drawn about the processes of self-assembled nanostructures formation, the presence of which is a prerequisite for the creation of radiation-induced point defects with new properties. •Self-assembled nanostructures are formed in nanocrystals made by grinding a crystal.•The formation of nanostructures does not change the X-ray diffraction pattern.•Nanostructures are not formed in frozen nanocrystals.•Presence of nanostructures changes the properties of radiation defects.•Activation energies of nanostructures formation and vacancies diffusion are the same.