An In(III)-MOF based on pore engineering for efficient capture SF6 from SF6/N2 mixture

• Published in: Separation and purification technology Vol. 327; p. 124929
• Main Authors: Yan, Jiang-Wen, Gang, Shu-Qi, Liu, Zi-Yue, Xu, Hao-Yu, Wang, Ruihan, Du, Jian-Long
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.12.2023
• Subjects: IAST selectivity; In(III)-MOF; Pore engineering; SF6 adsorption; SF6 adsorption; IAST selectivity; In(III)-MOF; Pore engineering

[Display omitted] •A new In(III)-MOF (HBU-21) was designed and synthesized according to pore engineering.•HBU-21 shows higher IAST selectivity of SF6/N2 (SF6/N2, v/v 10:90, 184.05).•DFT calculations reveal the importance of OMS for selective adsorption.•The cyclic adsorption experiments show its pot...