A facile synthesis of TiO2/BiOCl and TiO2/BiOCl/La2O3 heterostructure photocatalyst for enhanced charge separation efficiency with improved UV-light catalytic activity towards Rhodamine B and Reactive Yellow 86
[Display omitted] •TiO2/BiOCl/La2O3 NCs are synthesized by solid-state powder grind approach.•High photocatalytic activity was observed for TiO2/BiOCl/La2O3 NCs material.•Degradation percentage was achieved as 95% and 92% for RhB and RY 86 dyes.•Outstanding performance of dye degradation can be used...
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| Published in | Inorganic chemistry communications Vol. 130; p. 108715 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.08.2021
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| Subjects | |
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| Abstract | [Display omitted]
•TiO2/BiOCl/La2O3 NCs are synthesized by solid-state powder grind approach.•High photocatalytic activity was observed for TiO2/BiOCl/La2O3 NCs material.•Degradation percentage was achieved as 95% and 92% for RhB and RY 86 dyes.•Outstanding performance of dye degradation can be used for water purification.
A novel three-step synthesis approach of TiO2/BiOCl/La2O3 heterostructures was successfully prepared by hydrothermal, co-precipitation and solid-state reaction for enhances the photocatalytic activity through the degradation of Rhodamine B (RhB) and Reactive Yellow 86 (RY 86) organic dyes under UV-light illumination. The as-prepared photocatalysts were studied by using various physicochemical characterization tools like Powder X-ray diffraction (PXRD), UV–visible diffused reflectance spectroscopy (UV–Vis DRS), and Field emission scanning electron microscopy (FE-SEM) with EDX color mapping. The photocatalytic results were revealed TiO2/BiOCl and TiO2/BiOCl/La2O3 nanocatalyst effectively degrade RhB and RY 86 dyes molecules under UV light illumination within 120 min irradiation compare to pure TiO2. This prominent enhancement of UV-light photocatalytic activity can be ascribed to the efficient separation of photogenerated charge carriers by the effective construction of TiO2/BiOCl/La2O3 heterojunction. |
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| AbstractList | [Display omitted]
•TiO2/BiOCl/La2O3 NCs are synthesized by solid-state powder grind approach.•High photocatalytic activity was observed for TiO2/BiOCl/La2O3 NCs material.•Degradation percentage was achieved as 95% and 92% for RhB and RY 86 dyes.•Outstanding performance of dye degradation can be used for water purification.
A novel three-step synthesis approach of TiO2/BiOCl/La2O3 heterostructures was successfully prepared by hydrothermal, co-precipitation and solid-state reaction for enhances the photocatalytic activity through the degradation of Rhodamine B (RhB) and Reactive Yellow 86 (RY 86) organic dyes under UV-light illumination. The as-prepared photocatalysts were studied by using various physicochemical characterization tools like Powder X-ray diffraction (PXRD), UV–visible diffused reflectance spectroscopy (UV–Vis DRS), and Field emission scanning electron microscopy (FE-SEM) with EDX color mapping. The photocatalytic results were revealed TiO2/BiOCl and TiO2/BiOCl/La2O3 nanocatalyst effectively degrade RhB and RY 86 dyes molecules under UV light illumination within 120 min irradiation compare to pure TiO2. This prominent enhancement of UV-light photocatalytic activity can be ascribed to the efficient separation of photogenerated charge carriers by the effective construction of TiO2/BiOCl/La2O3 heterojunction. |
| ArticleNumber | 108715 |
| Author | Sridevi, A. Ramji, B.R. Sugumaran, V. Prasanna Venkatesan, G.K.D. Selvakumar, P. |
| Author_xml | – sequence: 1 givenname: A. surname: Sridevi fullname: Sridevi, A. email: sridevigunasekaranphd@gmail.com organization: Department of Electronics and Communication Engineering, M.Kumarasamy College of Engineering, Karur 639113, Tamil Nadu, India – sequence: 2 givenname: B.R. surname: Ramji fullname: Ramji, B.R. organization: Department of Industrial Engineering and Management, B.M.S. College of Engineering, Bangalore 560019, Karnataka, India – sequence: 3 givenname: G.K.D. surname: Prasanna Venkatesan fullname: Prasanna Venkatesan, G.K.D. organization: Faculty of Engineering, Karpagam Academy of Higher Education, Coimbatore 641021, Tamil Nadu, India – sequence: 4 givenname: V. surname: Sugumaran fullname: Sugumaran, V. organization: School of Mechanical Engineering, Vellore Institute of Technology, Chennai 600 127, Tamil Nadu, India – sequence: 5 givenname: P. surname: Selvakumar fullname: Selvakumar, P. organization: Department of Engineering and Sciences, Western Norway University of Applied Sciences, Bergen, Norway |
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| Keywords | Photodegradation UV-light photocatalytic activity Facile synthesis TiO2/BiOCl/La2O3 heterostructure Dye pollutants |
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•TiO2/BiOCl/La2O3 NCs are synthesized by solid-state powder grind approach.•High photocatalytic activity was observed for TiO2/BiOCl/La2O3... |
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| SubjectTerms | Dye pollutants Facile synthesis Photodegradation TiO2/BiOCl/La2O3 heterostructure UV-light photocatalytic activity |
| Title | A facile synthesis of TiO2/BiOCl and TiO2/BiOCl/La2O3 heterostructure photocatalyst for enhanced charge separation efficiency with improved UV-light catalytic activity towards Rhodamine B and Reactive Yellow 86 |
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