Electrochemical performances of asymmetric aqueous supercapacitor based on porous Cu3Mo2O9 petals and La2Mo3O12 nanoparticles fabricated through a simple co-precipitation method
[Display omitted] •Cu3Mo2O9 petals and La2Mo3O12 particles prepared by a simple co-precipitation route.•Cu3Mo2O9 and La2Mo3O12 exhibits capacity of 71.94 and 195.85 C g−1 at 2.5 A g−1.•ASC device shows retention of 119.4% of initial capacitance after 5000 cycles.•Energy density of ASC is found to be...
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| Published in | Applied surface science Vol. 512; p. 145648 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
15.05.2020
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| Online Access | Get full text |
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| Abstract | [Display omitted]
•Cu3Mo2O9 petals and La2Mo3O12 particles prepared by a simple co-precipitation route.•Cu3Mo2O9 and La2Mo3O12 exhibits capacity of 71.94 and 195.85 C g−1 at 2.5 A g−1.•ASC device shows retention of 119.4% of initial capacitance after 5000 cycles.•Energy density of ASC is found to be in the range of 21.84–2.92 Wh kg−1.•Power density is obtained in 1.61–10.86 kW kg−1 range.
Present work shows the electrochemical performances of asymmetric aqueous supercapacitor device based on Cu3Mo2O9 and La2Mo3O12 as a positive and a negative electrode respectively. The Cu3Mo2O9 and La2Mo3O12 were prepared by a simple co-precipitation route within 20 min and post annealing method. Crystalline phase purity of the electrodes is confirmed with powder X-ray diffraction, Raman and X-ray photoelectron spectroscopy techniques. The agglomerated nanoparticles and porous petals-like microstructures are observed for La2Mo3O12 and Cu3Mo2O9 respectively. The specific capacity of La2Mo3O12 and Cu3Mo2O9 is found to be 195.85 and 71.94 C g−1 at 2.5 A g−1 respectively. Charge storage mechanism of the electrodes is elucidated via Dunn’s and Trasatti’s approaches. The asymmetric supercapacitor (ASC) device exhibits a specific capacitance of 61.45 F g−1 at 2 A g−1. The ASC shows retention of 119.4% of initial specific capacitance after 5000 charging and discharging cycles and exhibits coulombic efficiency of 95.5% throughout the 5000 cycles. The ASC stores energy density of 21.84 Wh kg−1 at power density of 1.61 kW kg−1 and sustains the energy density as 2.92 Wh kg−1 at high power density of 10.86 kW kg−1. |
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| AbstractList | [Display omitted]
•Cu3Mo2O9 petals and La2Mo3O12 particles prepared by a simple co-precipitation route.•Cu3Mo2O9 and La2Mo3O12 exhibits capacity of 71.94 and 195.85 C g−1 at 2.5 A g−1.•ASC device shows retention of 119.4% of initial capacitance after 5000 cycles.•Energy density of ASC is found to be in the range of 21.84–2.92 Wh kg−1.•Power density is obtained in 1.61–10.86 kW kg−1 range.
Present work shows the electrochemical performances of asymmetric aqueous supercapacitor device based on Cu3Mo2O9 and La2Mo3O12 as a positive and a negative electrode respectively. The Cu3Mo2O9 and La2Mo3O12 were prepared by a simple co-precipitation route within 20 min and post annealing method. Crystalline phase purity of the electrodes is confirmed with powder X-ray diffraction, Raman and X-ray photoelectron spectroscopy techniques. The agglomerated nanoparticles and porous petals-like microstructures are observed for La2Mo3O12 and Cu3Mo2O9 respectively. The specific capacity of La2Mo3O12 and Cu3Mo2O9 is found to be 195.85 and 71.94 C g−1 at 2.5 A g−1 respectively. Charge storage mechanism of the electrodes is elucidated via Dunn’s and Trasatti’s approaches. The asymmetric supercapacitor (ASC) device exhibits a specific capacitance of 61.45 F g−1 at 2 A g−1. The ASC shows retention of 119.4% of initial specific capacitance after 5000 charging and discharging cycles and exhibits coulombic efficiency of 95.5% throughout the 5000 cycles. The ASC stores energy density of 21.84 Wh kg−1 at power density of 1.61 kW kg−1 and sustains the energy density as 2.92 Wh kg−1 at high power density of 10.86 kW kg−1. |
| ArticleNumber | 145648 |
| Author | Mariappan, C.R. Gajraj, V. |
| Author_xml | – sequence: 1 givenname: V. surname: Gajraj fullname: Gajraj, V. – sequence: 2 givenname: C.R. surname: Mariappan fullname: Mariappan, C.R. email: crm@nitkkr.ac.in |
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•Cu3Mo2O9 petals and La2Mo3O12 particles prepared by a simple co-precipitation route.•Cu3Mo2O9 and La2Mo3O12 exhibits capacity of 71.94 and... |
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| SubjectTerms | Copper molybdenum oxide Energy storage mechanism Hybrid supercapacitor Lanthanum molybdenum oxide |
| Title | Electrochemical performances of asymmetric aqueous supercapacitor based on porous Cu3Mo2O9 petals and La2Mo3O12 nanoparticles fabricated through a simple co-precipitation method |
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