Red- and NIR-emitting lanthanide complexes for photo- and electroluminescent nanothermometry in the cryogenic and high-temperature range
Ratiometric luminescent thermometers, particularly lanthanide-based, become very important, and long wavelength range is of particular interest due to low signal scattering. With this in mind, a series of new red and NIR emitting lanthanide Schiff base complexes were synthesized and characterized in...
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Published in | Optical materials Vol. 148; p. 114793 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.02.2024
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Abstract | Ratiometric luminescent thermometers, particularly lanthanide-based, become very important, and long wavelength range is of particular interest due to low signal scattering. With this in mind, a series of new red and NIR emitting lanthanide Schiff base complexes were synthesized and characterized in detail for use as components of luminescent thermometers. Red-emitting europium complexes demonstrated high temperature sensitivity (up to 7 %/K) in the cryogenic temperature range (80–200 K), where the ligand-to-europium luminescence intensity ratio (LIR) was used as a signal. In contrast, NIR emitting ytterbium complexes demonstrated no sensitivity in the cryogenic range; however, their luminescence was sensitive to high temperatures (300–600 K), which is currently of particular interest. Ytterbium and europium complexes were also tested in OLEDs, and due to high temperature sensitivity, europium complexes were used for the first electroluminescent thermometers.
•High sensitivity of red emitting europium complexes in the cryogenic temperature range (80–200 K) obtained.•High sensitivity of NIR emitting complexes towards the high temperatures (300–600 K) obtained.•The first electroluminescent thermometry based on europium complexes obtained. |
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AbstractList | Ratiometric luminescent thermometers, particularly lanthanide-based, become very important, and long wavelength range is of particular interest due to low signal scattering. With this in mind, a series of new red and NIR emitting lanthanide Schiff base complexes were synthesized and characterized in detail for use as components of luminescent thermometers. Red-emitting europium complexes demonstrated high temperature sensitivity (up to 7 %/K) in the cryogenic temperature range (80–200 K), where the ligand-to-europium luminescence intensity ratio (LIR) was used as a signal. In contrast, NIR emitting ytterbium complexes demonstrated no sensitivity in the cryogenic range; however, their luminescence was sensitive to high temperatures (300–600 K), which is currently of particular interest. Ytterbium and europium complexes were also tested in OLEDs, and due to high temperature sensitivity, europium complexes were used for the first electroluminescent thermometers.
•High sensitivity of red emitting europium complexes in the cryogenic temperature range (80–200 K) obtained.•High sensitivity of NIR emitting complexes towards the high temperatures (300–600 K) obtained.•The first electroluminescent thermometry based on europium complexes obtained. |
ArticleNumber | 114793 |
Author | Goloveshkin, Alexander S. Fedichkina, Anna D. Vashchenko, Andrey A. Dmitriev, Artem V. Lypenko, Dmitry A. Latipov, Egor V. Koshelev, Daniil S. Chernyadyev, Andrey Yu Utochnikova, Valentina V. Burlov, Anatolii S. |
Author_xml | – sequence: 1 givenname: Anna D. surname: Fedichkina fullname: Fedichkina, Anna D. organization: Materials Science Department, M.V. Lomonosov Moscow State University, 1/3 Leninskie Gory, Moscow, 119991, Russia – sequence: 2 givenname: Daniil S. orcidid: 0000-0001-8210-6690 surname: Koshelev fullname: Koshelev, Daniil S. organization: Materials Science Department, M.V. Lomonosov Moscow State University, 1/3 Leninskie Gory, Moscow, 119991, Russia – sequence: 3 givenname: Andrey A. surname: Vashchenko fullname: Vashchenko, Andrey A. organization: P.N. Lebedev Physical Institute, Leninsky prosp. 53, Moscow, 119992, Russia – sequence: 4 givenname: Alexander S. surname: Goloveshkin fullname: Goloveshkin, Alexander S. organization: A.N. Nesmeyanov Institute of Organoelement Compounds, Vavilova St. 28, Moscow, 119334, Russia – sequence: 5 givenname: Egor V. orcidid: 0000-0002-6809-1952 surname: Latipov fullname: Latipov, Egor V. organization: Department of Structural Analysis and Metrology, Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, Leninsky Prospect 32A, Moscow, 119334, Russia – sequence: 6 givenname: Anatolii S. surname: Burlov fullname: Burlov, Anatolii S. organization: Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia – sequence: 7 givenname: Artem V. orcidid: 0000-0001-5854-5669 surname: Dmitriev fullname: Dmitriev, Artem V. organization: A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prosp. 31, bld.4, Moscow, 119071, Russia – sequence: 8 givenname: Andrey Yu orcidid: 0000-0002-0266-4797 surname: Chernyadyev fullname: Chernyadyev, Andrey Yu organization: A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prosp. 31, bld.4, Moscow, 119071, Russia – sequence: 9 givenname: Dmitry A. orcidid: 0000-0002-5500-5613 surname: Lypenko fullname: Lypenko, Dmitry A. organization: A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prosp. 31, bld.4, Moscow, 119071, Russia – sequence: 10 givenname: Valentina V. surname: Utochnikova fullname: Utochnikova, Valentina V. email: valentina.utochnikova@gmail.com organization: Materials Science Department, M.V. Lomonosov Moscow State University, 1/3 Leninskie Gory, Moscow, 119991, Russia |
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