Post-combustion CO2 capture using nontoxic iron-based amino-MIL-101(Fe)
OFe3 cation and amino-BDC anion preliminary building blocks forming structure of amino-MIL-101(Fe). [Display omitted] •The application of amino-MIL-101(Fe) has been assessed for CO2 capture.•A hybrid model was applied to correlate the experimental data at low pressures.•Kinetic adsorption data have...
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| Published in | Inorganic chemistry communications Vol. 133; p. 108950 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.11.2021
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| Subjects | |
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| Abstract | OFe3 cation and amino-BDC anion preliminary building blocks forming structure of amino-MIL-101(Fe).
[Display omitted]
•The application of amino-MIL-101(Fe) has been assessed for CO2 capture.•A hybrid model was applied to correlate the experimental data at low pressures.•Kinetic adsorption data have been modeled by the theoretical micropore model.
Amino-MIL-101(Fe) was synthesized and assessed for post-combustion CO2 capture. A hybrid model has been applied which resulted in better agreement with the experimental data. The achieved adsorption values for the pure CO2 and N2 gases at 1 bar and 298 K were equal to 0.41 and 0.33 mmol.g−1. The kinetic modeling of adsorption data indicated that the adsorption of CO2 and N2 at low pressure was not kinetically controlled. The adsorption selectivity of CO2 over N2 was estimated using IAST, which was achieved equal to 1.6. |
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| AbstractList | OFe3 cation and amino-BDC anion preliminary building blocks forming structure of amino-MIL-101(Fe).
[Display omitted]
•The application of amino-MIL-101(Fe) has been assessed for CO2 capture.•A hybrid model was applied to correlate the experimental data at low pressures.•Kinetic adsorption data have been modeled by the theoretical micropore model.
Amino-MIL-101(Fe) was synthesized and assessed for post-combustion CO2 capture. A hybrid model has been applied which resulted in better agreement with the experimental data. The achieved adsorption values for the pure CO2 and N2 gases at 1 bar and 298 K were equal to 0.41 and 0.33 mmol.g−1. The kinetic modeling of adsorption data indicated that the adsorption of CO2 and N2 at low pressure was not kinetically controlled. The adsorption selectivity of CO2 over N2 was estimated using IAST, which was achieved equal to 1.6. |
| ArticleNumber | 108950 |
| Author | Sadeghzadeh Ahari, Jafar Halladj, Rouein Ganji Babakhani, Ensieh Mahdipoor, Hamid Reza Amjad-Iranagh, Sepideh |
| Author_xml | – sequence: 1 givenname: Hamid Reza surname: Mahdipoor fullname: Mahdipoor, Hamid Reza organization: Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 2 givenname: Ensieh surname: Ganji Babakhani fullname: Ganji Babakhani, Ensieh email: ganjie@ripi.ir organization: Department of Gas Processing and Transmission Development, Research Institute of Petroleum Industry, Tehran, Iran – sequence: 3 givenname: Rouein surname: Halladj fullname: Halladj, Rouein email: halladj@aut.ac.ir organization: Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 4 givenname: Jafar surname: Sadeghzadeh Ahari fullname: Sadeghzadeh Ahari, Jafar organization: Department of Gas Processing and Transmission Development, Research Institute of Petroleum Industry, Tehran, Iran – sequence: 5 givenname: Sepideh surname: Amjad-Iranagh fullname: Amjad-Iranagh, Sepideh organization: Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran |
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| CitedBy_id | crossref_primary_10_1016_j_colsurfa_2023_131971 crossref_primary_10_1021_acsami_2c13446 crossref_primary_10_1016_j_rechem_2023_101113 crossref_primary_10_1002_slct_202203314 |
| Cites_doi | 10.1016/j.jngse.2016.12.029 10.1002/aic.690110125 10.1038/natrevmats.2017.45 10.1021/ja01269a023 10.1016/j.cej.2009.09.013 10.1016/j.ijggc.2009.03.001 10.1039/D0RA09292D 10.1021/ic800538r 10.1016/j.colsurfa.2021.126554 10.1021/jp302808j 10.1021/ja02242a004 10.3390/ijerph17155438 10.1016/j.jhazmat.2020.122383 10.1016/j.apenergy.2017.12.016 10.1016/j.jes.2019.03.014 10.1080/09593331708616356 10.1016/S1387-1811(02)00545-0 10.1021/la046938d 10.1039/C5RA23154J 10.1002/anie.201000431 |
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| References | Mahdipoor, Halladj, Ganji Babakhani, Amjad-Iranagh, Sadeghzadeh Ahari (b0035) 2021; 619 Taheri, Babakhani, Towfighi (b0065) 2017; 38 Ruthven (b0100) 1984 Van Heest, Teich-McGoldrick, Greathouse, Allendorf, Sholl (b0055) 2012; 116 Liu, Yu (b0060) 2018; 211 Khan, Al-Waheab, Al-Haddad (b0090) 1996; 17 Al-Ghouti, Da'ana (b0045) 2020; 393 Zhang, Li, Liu, Zhao, Chen (b0070) 2016; 6 Pipitone, Bolland (b0010) 2009; 3 Trickett, Helal, Al-Maythalony, Yamani, Cordova, Yaghi (b0015) 2017; 2 D'Alessandro, Smit, Long (b0050) 2010; 49 Myers, Prausnitz (b0110) 1965; 11 Tumolo, Ancona, De Paola, Losacco, Campanale, Massarelli, Uricchio (b0025) 2020; 17 Foo, Hameed (b0040) 2010; 156 Bauer, Serre, Devic, Horcajada, Marrot, Férey, Stock (b0020) 2008; 47 Mukherjee, Okolie, Abdelrasoul, Niu, Dalai (b0005) 2019; 83 Brunauer, Emmett, Teller (b0085) 1938; 60 McCusker, Liebau, Engelhardt (b0075) 2003; 58 Ruthven, Farooq, Knaebel (b0105) 1994 Langmuir (b0080) 1918; 40 Mahdipoor, Halladj, Babakhani, Amjad-Iranagh, Ahari (b0030) 2021; 11 Marathe, Farooq, Srinivasan (b0095) 2005; 21 Ruthven (10.1016/j.inoche.2021.108950_b0105) 1994 Marathe (10.1016/j.inoche.2021.108950_b0095) 2005; 21 Mahdipoor (10.1016/j.inoche.2021.108950_b0030) 2021; 11 Ruthven (10.1016/j.inoche.2021.108950_b0100) 1984 Van Heest (10.1016/j.inoche.2021.108950_b0055) 2012; 116 Taheri (10.1016/j.inoche.2021.108950_b0065) 2017; 38 D'Alessandro (10.1016/j.inoche.2021.108950_b0050) 2010; 49 McCusker (10.1016/j.inoche.2021.108950_b0075) 2003; 58 Brunauer (10.1016/j.inoche.2021.108950_b0085) 1938; 60 Trickett (10.1016/j.inoche.2021.108950_b0015) 2017; 2 Liu (10.1016/j.inoche.2021.108950_b0060) 2018; 211 Langmuir (10.1016/j.inoche.2021.108950_b0080) 1918; 40 Myers (10.1016/j.inoche.2021.108950_b0110) 1965; 11 Bauer (10.1016/j.inoche.2021.108950_b0020) 2008; 47 Pipitone (10.1016/j.inoche.2021.108950_b0010) 2009; 3 Al-Ghouti (10.1016/j.inoche.2021.108950_b0045) 2020; 393 Foo (10.1016/j.inoche.2021.108950_b0040) 2010; 156 Mukherjee (10.1016/j.inoche.2021.108950_b0005) 2019; 83 Zhang (10.1016/j.inoche.2021.108950_b0070) 2016; 6 Tumolo (10.1016/j.inoche.2021.108950_b0025) 2020; 17 Khan (10.1016/j.inoche.2021.108950_b0090) 1996; 17 Mahdipoor (10.1016/j.inoche.2021.108950_b0035) 2021; 619 |
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Mater. doi: 10.1016/S1387-1811(02)00545-0 contributor: fullname: McCusker – volume: 21 start-page: 4532 year: 2005 ident: 10.1016/j.inoche.2021.108950_b0095 article-title: Modeling gas adsorption and transport in small-pore titanium silicates publication-title: Langmuir doi: 10.1021/la046938d contributor: fullname: Marathe – volume: 6 start-page: 4289 issue: 6 year: 2016 ident: 10.1016/j.inoche.2021.108950_b0070 article-title: Hexagonal microspindle of NH 2-MIL-101 (Fe) metal–organic frameworks with visible-light-induced photocatalytic activity for the degradation of toluene publication-title: RSC Adv. doi: 10.1039/C5RA23154J contributor: fullname: Zhang – volume: 49 start-page: 6058 issue: 35 year: 2010 ident: 10.1016/j.inoche.2021.108950_b0050 article-title: Carbon dioxide capture: prospects for new materials publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201000431 contributor: fullname: D'Alessandro |
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