Encapsulated dichloroethane-mediated interlocked supramolecular polymeric assembly of A1/A2-dihydroxy-octyloxy pillar[5]arene 1,2-dichloroethane monosolvate

Crystals of 1-(1,4-dihydroxy)-2,3,4,5-(1,4-dioctyloxy)-pillar[5]arene, C 99 H 158 O 10 ·C 2 H 4 Cl 2 , were grown from a 1,2-dicholoroethane/ n -hexane solvent system. In the crystal, the encapsulated 1,2-dichloroethane solvent is stabilized by C—H...π interactions and mediates the formation of an i...

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Published inActa crystallographica. Section E, Crystallographic communications Vol. 74; no. 10; pp. 1471 - 1474
Main Authors Al-Azemi, Talal F., Vinodh, Mickey, Mohamod, Abdirahman A., Alipour, Fatemeh H.
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.10.2018
Subjects
crystal structure
hydroxy functionalization
octyloxy pillararene
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Summary:Crystals of 1-(1,4-dihydroxy)-2,3,4,5-(1,4-dioctyloxy)-pillar[5]arene, C 99 H 158 O 10 ·C 2 H 4 Cl 2 , were grown from a 1,2-dicholoroethane/ n -hexane solvent system. In the crystal, the encapsulated 1,2-dichloroethane solvent is stabilized by C—H...π interactions and mediates the formation of an interlocked supramolecular polymer via C—H...Cl interactions.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989018013415