Facile fabrication of multi superlyophobic nano soil coated-mesh surface with excellent corrosion resistance for efficient immiscible liquids separation

• Published in: Separation and purification technology Vol. 284; p. 120266
• Main Authors: Kang, Lei, Zeng, Qiao, Wang, Bin, Zeng, Jinsong, Liao, Bokai, Wu, Huixiang, Cheng, Zheng, Guo, Xingpeng
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.02.2022
• Subjects: Corrosion resistance; Immiscible liquids separation; Low-cost; Soil; Low-cost; Corrosion resistance; Soil; Immiscible liquids separation
• DOI: 10.1016/j.seppur.2021.120266
• ISSN: 1383-5866

A novel strategy for spraying nanosized soil particles on steel mesh to prepare the superlyophobic soil mesh by a facile surface treatment technology, and successfully apply it to various immiscible liquids separation. [Display omitted] •A multifunctional, sustainable material for immiscible liquid mixtures separation.•Under nonpolar (polar) liquid superlyophobicity of polar (nonpolar) liquid.•Used chemical properties-structure relationships to give material performance.•Low cost manufacturing, environment friendly, dimplicity of operator.•Good corrosion resistance in acidic, alkaline and high salt environment. Immiscible liquids separation has recently become a worldwide challenge due to the expanding industrial activity. It is still thorny to put forward a universal strategy for constructing multi-superlyophobic surfaces in immiscible liquids systems due to a thermodynamic contradiction. Herein, a low-cost, environmentally friendly pre-wetted nanosized soil coated-mesh (NSCM) was prepared, which shows the property of under-nonpolar-liquid superlyophobic to polar liquid, or under-polar-liquid superlyophobic to nonpolar liquid. The NSCM was fabricated in aqueous solutions by spraying melamine formaldehyde resin modified nanosized soil particles on a stainless-steel mesh for selective immiscible liquid separation. After the NSCM is prewetted with heavy liquid, heavy liquid can be removed from the light immiscible liquid mixtures by gravity. The as-prepared NSCM showed a high separation efficiency of above 99% for a series of immiscible liquids mixtures, even after 60 separation cycles. More importantly, the electrochemical tests indicated that the NSCM exhibited the outstanding durability after being immersed in alkali (pH = 10.0, NaOH), acidic (pH = 4.0, HCl) and high-concentrated salt solutions (3.5 wt% NaCl) for 30 days. The calculated Rt values were approximately 1.04 × 107, 2.65 × 106 and 7.59 × 105 Ω·cm2, respectively. And the corresponding corrosion rates were 0.013712, 0.96438, and 2.5818 μm/year, respectively. These excellent performances of the NSCM make it an ideal candidate material for separation, and even in a wider field of sea wastewater treatment.