Binding Energies in Atomic Negative Ions: II

This article updates a ten‐year‐old review of this subject [J. Chem. Phys. Ref. Data 4, 539 (1975)]. A survey of the electron affinity determinations for the elements up to Z=85 is presented, and based upon these data, a set of recommended electron affinities is established. Recent calculations of a...

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Bibliographic Details
Published inJournal of physical and chemical reference data Vol. 14; no. 3; pp. 731 - 750
Main Authors Hotop, H., Lineberger, W. C.
Format Journal Article
LanguageEnglish
Published Melville, NY American Institute of Physics 01.07.1985
Subjects
Atomic and molecular physics
Atomic properties and interactions with photons
Exact sciences and technology
Ionization potentials, electron affinities
Physics
Properties of atoms and atomic ions
ANIONS
ELEMENTS
PHOTOELECTRON SPECTROSCOPY
atomic energy levels and spectra
ATOMIC IONS
FINE STRUCTURE
AFFINITY
BINDING ENERGY
ions
electron affinity
Electron binding energy
Electron affinity
Atomic ions
Electron photodetachment
Theoretical study
Negative ion
Review
Experimental study
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Summary:This article updates a ten‐year‐old review of this subject [J. Chem. Phys. Ref. Data 4, 539 (1975)]. A survey of the electron affinity determinations for the elements up to Z=85 is presented, and based upon these data, a set of recommended electron affinities is established. Recent calculations of atomic electron affinities and the major semiempirical methods are discussed and compared with experiment. The experimental methods which yield electron binding energy data are described and intercompared. Fine structure splittings of these ions and excited state term energies are given.
ISSN:0047-2689
1529-7845
DOI:10.1063/1.555735