Revisiting the Semi-Hydrogenation of Phenylacetylene to Styrene over Palladium-Lead Alloyed Catalysts on Precipitated Calcium Carbonate Supports
The quest for improved heterogeneous catalysts often leads to sophisticated solutions, which are expensive and tricky to scale up industrially. Herein, the effort to upgrade the existing inorganic nonmetallic materials has seldom been prioritized by the catalysis community, which could deliver cost-...
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| Published in | Catalysts Vol. 13; no. 1; p. 50 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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01.01.2023
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| Abstract | The quest for improved heterogeneous catalysts often leads to sophisticated solutions, which are expensive and tricky to scale up industrially. Herein, the effort to upgrade the existing inorganic nonmetallic materials has seldom been prioritized by the catalysis community, which could deliver cost-effective solutions to upgrade the industrial catalysts catalog. With this philosophy in mind, we demonstrate in this work that alloyed palladium-lead (Pd-Pb) deposited on novel precipitated calcium carbonate (PCC) supports could be considered an upgraded version of the industrial Lindlar catalyst for the semi-hydrogenation of phenylacetylene to styrene. By utilizing PCC supports of variable surface areas (up to 60 m2/g) and alloyed Pd-Pb loading, supported by material characterization tools, we showcase that achieving the “active-site isolation” feature could be the most pivotal criterion to maximize semi-hydrogenated alkenes selectivity at the expense of prohibiting the complete hydrogenation to alkanes. The calcite phase of our PCC supports governs the ultimate catalysis, via complexation with uniformly distributed alloyed Pb, which may facilitate the desired “active-site isolation” feature to boost the selectivity to the preferential product. Through this work, we also advocate increasing research efforts on mineral-based inorganic nonmetallic materials to deliver novel and improved cost-effective catalytic systems. |
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| AbstractList | The quest for improved heterogeneous catalysts often leads to sophisticated solutions, which are expensive and tricky to scale up industrially. Herein, the effort to upgrade the existing inorganic nonmetallic materials has seldom been prioritized by the catalysis community, which could deliver cost-effective solutions to upgrade the industrial catalysts catalog. With this philosophy in mind, we demonstrate in this work that alloyed palladium-lead (Pd-Pb) deposited on novel precipitated calcium carbonate (PCC) supports could be considered an upgraded version of the industrial Lindlar catalyst for the semi-hydrogenation of phenylacetylene to styrene. By utilizing PCC supports of variable surface areas (up to 60 m2/g) and alloyed Pd-Pb loading, supported by material characterization tools, we showcase that achieving the “active-site isolation” feature could be the most pivotal criterion to maximize semi-hydrogenated alkenes selectivity at the expense of prohibiting the complete hydrogenation to alkanes. The calcite phase of our PCC supports governs the ultimate catalysis, via complexation with uniformly distributed alloyed Pb, which may facilitate the desired “active-site isolation” feature to boost the selectivity to the preferential product. Through this work, we also advocate increasing research efforts on mineral-based inorganic nonmetallic materials to deliver novel and improved cost-effective catalytic systems. |
| Author | Dutta Chowdhury, Abhishek Li, Yining Gu, Lin Ftouni, Jamal Zheng, Yifan |
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| Cites_doi | 10.1021/jacs.8b04669 10.1021/ie000712y 10.1002/anie.201913453 10.1007/BF00765356 10.1021/acsami.0c17570 10.1016/j.jcou.2019.06.017 10.1021/acsomega.9b00042 10.1016/j.jcat.2011.06.025 10.1016/S1872-2067(19)63453-4 10.1126/science.1156660 10.1016/j.jcat.2010.04.018 10.2343/geochemj.19.245 10.1016/j.cej.2021.132018 10.1016/j.cej.2018.10.016 10.1016/j.jcat.2020.06.003 10.1016/j.jcat.2006.06.027 10.1021/acs.chemrev.9b00230 10.1039/D1CC06682J 10.1016/S0926-860X(02)00119-9 10.1021/acscatal.9b03113 10.1021/ie202342a 10.1021/acscatal.6b02207 10.1016/j.cattod.2020.03.057 10.1002/anie.200385146 10.1039/D0TA07705D 10.1016/j.carbon.2019.01.014 10.1021/acscatal.5b01933 10.1002/anie.202106459 10.1021/acscatal.9b04070 10.1016/j.colsurfb.2019.110720 10.1038/s41929-019-0364-x 10.1016/S0009-2509(03)00209-4 10.1021/acscatal.2c04883 10.5772/48751 10.1038/s41467-021-21374-2 10.1039/C7CY01858D 10.1021/acscatal.5b02953 10.1002/hlca.19520350205 10.1038/ncomms6787 10.1039/C7DT01607G 10.1021/cr200346z 10.1021/acs.jpcc.7b11473 10.1016/j.jcat.2008.04.008 10.1016/j.materresbull.2013.01.048 10.1016/S1872-2067(17)62847-X 10.1016/j.jechem.2018.08.006 10.1021/acscatal.7b02032 10.1021/jacs.1c11740 10.1002/cssc.201701127 10.1016/j.jcat.2022.02.020 10.1002/ange.200502071 10.1002/chem.201304795 10.1021/jacs.7b01471 10.1007/s00894-018-3685-9 10.1038/s41467-019-12460-7 10.1002/anie.201505073 |
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| References | Mon (ref_15) 2018; 140 By (ref_2) 2004; 43 Feng (ref_38) 2017; 139 (ref_1) 2002; 232 Li (ref_21) 2012; 51 (ref_34) 2008; 257 Prins (ref_41) 2012; 112 Lian (ref_40) 2020; 41 Bridier (ref_9) 2010; 273 Choe (ref_36) 2020; 59 Stachurski (ref_8) 1988; 1 Chaparro (ref_16) 2021; 368 Lindlar (ref_46) 2003; 46 Yaseen (ref_47) 2019; 4 Wang (ref_28) 2020; 10 Delgado (ref_35) 2017; 46 Li (ref_56) 2019; 9 Markov (ref_33) 2019; 358 Zhou (ref_18) 2016; 6 Song (ref_25) 2022; 12 Wang (ref_20) 2022; 429 (ref_23) 2006; 243 Li (ref_39) 2021; 13 Lindlar (ref_57) 1952; 35 Wang (ref_52) 2020; 389 Liang (ref_32) 2017; 7 Vergunst (ref_3) 2001; 40 Mitchell (ref_13) 2014; 20 Wu (ref_31) 2022; 58 Tew (ref_11) 2011; 283 Li (ref_48) 2020; 186 Shi (ref_54) 2016; 6 Huang (ref_30) 2019; 10 Pei (ref_19) 2017; 38 Zhang (ref_42) 2020; 120 Bugaev (ref_12) 2018; 122 Huang (ref_4) 2003; 58 Shamsiev (ref_44) 2018; 24 Yin (ref_37) 2020; 8 Yoshioka (ref_50) 1985; 19 (ref_14) 2022; 408 Ji (ref_55) 2017; 10 (ref_53) 2019; 2 Tykwinski (ref_6) 2006; 118 Zhu (ref_5) 2021; 12 Huang (ref_27) 2019; 33 Chaparro (ref_10) 2016; 6 Giammaria (ref_49) 2019; 33 Gao (ref_24) 2022; 144 Xia (ref_26) 2019; 145 Albani (ref_45) 2015; 54 Yu (ref_29) 2017; 7 Studt (ref_43) 2008; 320 Chan (ref_17) 2014; 5 Jin (ref_22) 2021; 60 ref_7 Gopi (ref_51) 2013; 48 |
| References_xml | – volume: 140 start-page: 8827 year: 2018 ident: ref_15 article-title: Isolated Fe(III)-O Sites Catalyze the Hydrogenation of Acetylene in Ethylene Flows under Front-End Industrial Conditions publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.8b04669 – volume: 40 start-page: 2801 year: 2001 ident: ref_3 article-title: Optimization of Geometric Properties of a Monolithic Catalyst for the Selective Hydrogenation of Phenylacetylene publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie000712y – volume: 59 start-page: 3650 year: 2020 ident: ref_36 article-title: Fast and Selective Semihydrogenation of Alkynes by Palladium Nanoparticles Sandwiched in Metal-Organic Frameworks publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201913453 – volume: 1 start-page: 67 year: 1988 ident: ref_8 article-title: Structural Aspects of the Lindlar Catalyst for Selective Hydrogenation publication-title: Catal. Lett. doi: 10.1007/BF00765356 – volume: 13 start-page: 2530 year: 2021 ident: ref_39 article-title: Highly Active and Stable Palladium Single-Atom Catalyst Achieved by a Thermal Atomization Strategy on an SBA-15 Molecular Sieve for Semi-Hydrogenation Reactions publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.0c17570 – volume: 33 start-page: 341 year: 2019 ident: ref_49 article-title: Catalytic Effect of Water on Calcium Carbonate Decomposition publication-title: J. CO2 Util. doi: 10.1016/j.jcou.2019.06.017 – volume: 4 start-page: 10160 year: 2019 ident: ref_47 article-title: Elucidation of Calcite Structure of Calcium Carbonate Formation Based on Hydrated Cement Mixed with Graphene Oxide and Reduced Graphene Oxide publication-title: ACS Omega doi: 10.1021/acsomega.9b00042 – volume: 283 start-page: 45 year: 2011 ident: ref_11 article-title: The Roles of Carbide and Hydride in Oxide-Supported Palladium Nanoparticles for Alkyne Hydrogenation publication-title: J. Catal. doi: 10.1016/j.jcat.2011.06.025 – volume: 41 start-page: 598 year: 2020 ident: ref_40 article-title: Unexpectedly Selective Hydrogenation of Phenylacetylene to Styrene on Titania Supported Platinum Photocatalyst under 385 Nm Monochromatic Light Irradiation publication-title: Chin. J. Catal. doi: 10.1016/S1872-2067(19)63453-4 – volume: 320 start-page: 1320 year: 2008 ident: ref_43 article-title: Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene publication-title: Science doi: 10.1126/science.1156660 – volume: 273 start-page: 92 year: 2010 ident: ref_9 article-title: Interplay between Carbon Monoxide, Hydrides, and Carbides in Selective Alkyne Hydrogenation on Palladium publication-title: J. Catal. doi: 10.1016/j.jcat.2010.04.018 – volume: 19 start-page: 245 year: 1985 ident: ref_50 article-title: Transformation of Aragonite to Calcite through Heating publication-title: Geochem. J. doi: 10.2343/geochemj.19.245 – volume: 429 start-page: 132018 year: 2022 ident: ref_20 article-title: CuPd Alloy Decorated SnNb2O6 Nanosheets as a Multifunctional Photocatalyst for Semihydrogenation of Phenylacetylene under Visible Light publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.132018 – volume: 358 start-page: 520 year: 2019 ident: ref_33 article-title: Particle Size Effect in Liquid-Phase Hydrogenation of Phenylacetylene over Pd Catalysts: Experimental Data and Theoretical Analysis publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2018.10.016 – volume: 389 start-page: 297 year: 2020 ident: ref_52 article-title: Nitrogen-Fixing of Ultrasmall Pd-Based Bimetallic Nanoclusters on Carbon Supports publication-title: J. Catal. doi: 10.1016/j.jcat.2020.06.003 – volume: 46 start-page: 89 year: 2003 ident: ref_46 article-title: Palladium Catalyst for Partial Reduction of Acetylenes publication-title: Org. Synth. – volume: 243 start-page: 74 year: 2006 ident: ref_23 article-title: Semihydrogenation of Phenylacetylene Catalyzed by Metallic Nanoparticles Containing Noble Metals publication-title: J. Catal. doi: 10.1016/j.jcat.2006.06.027 – volume: 120 start-page: 683 year: 2020 ident: ref_42 article-title: Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.9b00230 – volume: 58 start-page: 1191 year: 2022 ident: ref_31 article-title: Encapsulation of Atomically Dispersed Pt Clusters in Porous TiO2 for Semi-Hydrogenation of Phenylacetylene publication-title: Chem. Commun. doi: 10.1039/D1CC06682J – volume: 232 start-page: 289 year: 2002 ident: ref_1 article-title: Shiego Nishimura: Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis: Wiley, New York, Chichester, Weinheim, Brisbane, Singapore, Toronto, 2001 publication-title: Appl. Catal. A Gen. doi: 10.1016/S0926-860X(02)00119-9 – volume: 9 start-page: 11088 year: 2019 ident: ref_56 article-title: Distribution and Valence State of Ru Species on CeO2 Supports: Support Shape Effect and Its Influence on CO Oxidation publication-title: ACS Catal. doi: 10.1021/acscatal.9b03113 – volume: 51 start-page: 4934 year: 2012 ident: ref_21 article-title: Carbon Nanotubes Supported Mono- and Bimetallic Pt and Ru Catalysts for Selective Hydrogenation of Phenylacetylene publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie202342a – volume: 6 start-page: 7844 year: 2016 ident: ref_54 article-title: Enhanced Chemoselective Hydrogenation through Tuning the Interaction between Pt Nanoparticles and Carbon Supports: Insights from Identical Location Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy publication-title: ACS Catal. doi: 10.1021/acscatal.6b02207 – volume: 368 start-page: 181 year: 2021 ident: ref_16 article-title: Selective Continuous Flow Phenylacetylene Hydrogenation over Pd-Biogenic Calcium Carbonate publication-title: Catal. Today doi: 10.1016/j.cattod.2020.03.057 – volume: 43 start-page: 2324 year: 2004 ident: ref_2 article-title: Handbook of Commercial Catalysts. Heterogeneous Catalysts. By Howard F. Rase publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200385146 – volume: 8 start-page: 20925 year: 2020 ident: ref_37 article-title: Graphdiyne-Based Pd Single-Atom Catalyst for Semihydrogenation of Alkynes to Alkenes with High Selectivity and Conversion under Mild Conditions publication-title: J. Mater. Chem. A doi: 10.1039/D0TA07705D – volume: 145 start-page: 47 year: 2019 ident: ref_26 article-title: N-Doped Graphene Confined Pt Nanoparticles for Efficient Semi-Hydrogenation of Phenylacetylene publication-title: Carbonarbon doi: 10.1016/j.carbon.2019.01.014 – volume: 6 start-page: 1054 year: 2016 ident: ref_18 article-title: PdZn Intermetallic Nanostructure with Pd-Zn-Pd Ensembles for Highly Active and Chemoselective Semi-Hydrogenation of Acetylene publication-title: ACS Catal. doi: 10.1021/acscatal.5b01933 – volume: 60 start-page: 17430 year: 2021 ident: ref_22 article-title: A Top-Down Strategy to Realize Surface Reconstruction of Small-Sized Platinum-Based Nanoparticles for Selective Hydrogenation publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202106459 – volume: 10 start-page: 6763 year: 2020 ident: ref_28 article-title: Enhancement of Alkyne Semi-Hydrogenation Selectivity by Electronic Modification of Platinum publication-title: ACS Catal. doi: 10.1021/acscatal.9b04070 – volume: 186 start-page: 110720 year: 2020 ident: ref_48 article-title: Porous Calcite CaCO3 Microspheres: Preparation, Characterization and Release Behavior as Doxorubicin Carrier publication-title: Colloids Surf. B Biointerfaces doi: 10.1016/j.colsurfb.2019.110720 – volume: 2 start-page: 955 year: 2019 ident: ref_53 article-title: Control of Metal-Support Interactions in Heterogeneous Catalysts to Enhance Activity and Selectivity publication-title: Nat. Catal. doi: 10.1038/s41929-019-0364-x – volume: 58 start-page: 3465 year: 2003 ident: ref_4 article-title: Phenylacetylene Hydrogenation in a Three-Phase Catalytic Packed-Bed Reactor: Experiments and Model publication-title: Chem. Eng. Sci. doi: 10.1016/S0009-2509(03)00209-4 – volume: 12 start-page: 14846 year: 2022 ident: ref_25 article-title: Single-Atom Ni-Modified Al2O3-Supported Pd for Mild-Temperature Semi-Hydrogenation of Alkynes publication-title: ACS Catal. doi: 10.1021/acscatal.2c04883 – ident: ref_7 doi: 10.5772/48751 – volume: 12 start-page: 1329 year: 2021 ident: ref_5 article-title: A Tailored Multi-Functional Catalyst for Ultra-Efficient Styrene Production under a Cyclic Redox Scheme publication-title: Nat. Commun. doi: 10.1038/s41467-021-21374-2 – volume: 7 start-page: 4934 year: 2017 ident: ref_29 article-title: Nanosized Palladium on Phosphorus-Incorporated Porous Carbon Frameworks for Enhanced Selective Phenylacetylene Hydrogenation publication-title: Catal. Sci. Technol. doi: 10.1039/C7CY01858D – volume: 6 start-page: 2121 year: 2016 ident: ref_10 article-title: Selective Hydrogenation of Functionalized Alkynes to (E)-Alkenes, Using Ordered Alloys as Catalysts publication-title: ACS Catal. doi: 10.1021/acscatal.5b02953 – volume: 35 start-page: 446 year: 1952 ident: ref_57 article-title: Ein Neuer Katalysator Für Selektive Hydrierungen publication-title: Helv. Chim. Acta doi: 10.1002/hlca.19520350205 – volume: 5 start-page: 5787 year: 2014 ident: ref_17 article-title: Interstitial Modification of Palladium Nanoparticles with Boron Atoms as a Green Catalyst for Selective Hydrogenation publication-title: Nat. Commun. doi: 10.1038/ncomms6787 – volume: 46 start-page: 12381 year: 2017 ident: ref_35 article-title: Advances in the Preparation of Highly Selective Nanocatalysts for the Semi-Hydrogenation of Alkynes Using Colloidal Approaches publication-title: Dalt. Trans. doi: 10.1039/C7DT01607G – volume: 112 start-page: 2714 year: 2012 ident: ref_41 article-title: Hydrogen Spillover. Facts and Fiction publication-title: Chem. Rev. doi: 10.1021/cr200346z – volume: 122 start-page: 12029 year: 2018 ident: ref_12 article-title: Palladium Carbide and Hydride Formation in the Bulk and at the Surface of Palladium Nanoparticles publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.7b11473 – volume: 257 start-page: 87 year: 2008 ident: ref_34 article-title: Inorganic Materials as Supports for Palladium Nanoparticles: Application in the Semi-Hydrogenation of Phenylacetylene publication-title: J. Catal. doi: 10.1016/j.jcat.2008.04.008 – volume: 48 start-page: 1906 year: 2013 ident: ref_51 article-title: Aragonite–Calcite–Vaterite: A Temperature Influenced Sequential Polymorphic Transformation of CaCO3 in the Presence of DTPA publication-title: Mater. Res. Bull. doi: 10.1016/j.materresbull.2013.01.048 – volume: 38 start-page: 1540 year: 2017 ident: ref_19 article-title: Isolation of Pd Atoms by Cu for Semi-Hydrogenation of Acetylene: Effects of Cu Loading publication-title: Chin. J. Catal. doi: 10.1016/S1872-2067(17)62847-X – volume: 33 start-page: 31 year: 2019 ident: ref_27 article-title: Palladium Nanoclusters Immobilized on Defective Nanodiamond-Graphene Core-Shell Supports for Semihydrogenation of Phenylacetylene publication-title: J. Energy Chem. doi: 10.1016/j.jechem.2018.08.006 – volume: 7 start-page: 6567 year: 2017 ident: ref_32 article-title: Porous TiO2 /Pt/TiO2 Sandwich Catalyst for Highly Selective Semihydrogenation of Alkyne to Olefin publication-title: ACS Catal. doi: 10.1021/acscatal.7b02032 – volume: 144 start-page: 573 year: 2022 ident: ref_24 article-title: Pd/Fe2O3 with Electronic Coupling Single-Site Pd-Fe Pair Sites for Low-Temperature Semihydrogenation of Alkynes publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.1c11740 – volume: 10 start-page: 3427 year: 2017 ident: ref_55 article-title: Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots publication-title: ChemSusChem doi: 10.1002/cssc.201701127 – volume: 408 start-page: 43 year: 2022 ident: ref_14 article-title: Selective Semi-Hydrogenation of Internal Alkynes Catalyzed by Pd–CaCO3 Clusters publication-title: J. Catal. doi: 10.1016/j.jcat.2022.02.020 – volume: 118 start-page: 1050 year: 2006 ident: ref_6 article-title: Synthese von Polyin-Naturstoffen publication-title: Angew. Chem. Int. Ed. doi: 10.1002/ange.200502071 – volume: 20 start-page: 5926 year: 2014 ident: ref_13 article-title: From the Lindlar Catalyst to Supported Ligand-Modified Palladium Nanoparticles: Selectivity Patterns and Accessibility Constraints in the Continuous-Flow Three-Phase Hydrogenation of Acetylenic Compounds publication-title: Chem. Eur. J. doi: 10.1002/chem.201304795 – volume: 139 start-page: 7294 year: 2017 ident: ref_38 article-title: Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.7b01471 – volume: 24 start-page: 143 year: 2018 ident: ref_44 article-title: Adsorption of Phenylacetylene and Styrene on Palladium Surface: A DFT Study publication-title: J. Mol. Model. doi: 10.1007/s00894-018-3685-9 – volume: 10 start-page: 4431 year: 2019 ident: ref_30 article-title: Anchoring Cu1 Species over Nanodiamond-Graphene for Semi-Hydrogenation of Acetylene publication-title: Nat. Commun. doi: 10.1038/s41467-019-12460-7 – volume: 54 start-page: 11265 year: 2015 ident: ref_45 article-title: A Stable Single-Site Palladium Catalyst for Hydrogenations publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201505073 |
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| SubjectTerms | Adsorption Alkanes Calcite Calcium carbonate Carbon Catalysis Catalysts Chemical reactions Hydrogenation Lead Palladium Phase transitions Polymerization Scanning electron microscopy Selectivity Styrenes System effectiveness Transmission electron microscopy |
| Title | Revisiting the Semi-Hydrogenation of Phenylacetylene to Styrene over Palladium-Lead Alloyed Catalysts on Precipitated Calcium Carbonate Supports |
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| Volume | 13 |
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