Vibrational and electronic spectra and bonding in ionic transition metal hexacarbonyls

• Published in: Journal of molecular spectroscopy Vol. 30; no. 1; pp. 29 - 50
• Main Authors: Abel, E.W., McLean, R.A.N., Tyfield, S.P., Braterman, P.S., Walker, A.P., Hendra, P.J.
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 1969

The IR and Raman spectra of the metal hexacarbonyl ions V(CO) 6 − and Re(CO) 6 + in solution and solid are reported. Twelve of the 13 fundamental frequencies of V(CO) 6 − and 11 of those of Re(CO) 6 + were assigned, together with combination and overtone frequencies. Approximate CO stretching force...