Ferrocenylsubstituted α,β-unsaturated ketones in the synthesis of dihydropyrimidinethiones
The reaction has been studied of ferrocenylsubstituted α,β-unsaturated ketones with thiourea in alkaline ethanol leading to the corresponding dihydropyrimidinethiones. Products were isolated as yellow or orange crystals with yields of 65–95%. Structures were proved by high resolution 1H NMR spectra....
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| Published in | Journal of organometallic chemistry Vol. 456; no. 2; pp. 235 - 238 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
07.09.1993
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| Online Access | Get full text |
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| Abstract | The reaction has been studied of ferrocenylsubstituted α,β-unsaturated ketones with thiourea in alkaline ethanol leading to the corresponding dihydropyrimidinethiones. Products were isolated as yellow or orange crystals with yields of 65–95%. Structures were proved by high resolution
1H NMR spectra. Ferrocenylsubstituted dihydropyrimidinethiones have been shown to convert quantitatively into the initial α,β-unsaturated ketones under heating with alkaline ethanol in the presence of water. |
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| AbstractList | The reaction has been studied of ferrocenylsubstituted α,β-unsaturated ketones with thiourea in alkaline ethanol leading to the corresponding dihydropyrimidinethiones. Products were isolated as yellow or orange crystals with yields of 65–95%. Structures were proved by high resolution
1H NMR spectra. Ferrocenylsubstituted dihydropyrimidinethiones have been shown to convert quantitatively into the initial α,β-unsaturated ketones under heating with alkaline ethanol in the presence of water. |
| Author | Hocke, Ines Goncharov, Alexander V. Postnov, Vyacheslav N. Krut'ko, Dmitry P. |
| Author_xml | – sequence: 1 givenname: Vyacheslav N. surname: Postnov fullname: Postnov, Vyacheslav N. – sequence: 2 givenname: Alexander V. surname: Goncharov fullname: Goncharov, Alexander V. – sequence: 3 givenname: Ines surname: Hocke fullname: Hocke, Ines – sequence: 4 givenname: Dmitry P. surname: Krut'ko fullname: Krut'ko, Dmitry P. |
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| Cites_doi | 10.1139/v79-442 10.1135/cccc19870395 |
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| Copyright | 1993 |
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| Title | Ferrocenylsubstituted α,β-unsaturated ketones in the synthesis of dihydropyrimidinethiones |
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