The absorption spectrum of the Ag2 molecule

The high dispersion absorption spectrum of the Ag2 molecule has been photographed in the ∼5300–1500-Å region. Observations include the previously reported A ← X, B ← X, C ← X, D ← X, and E ← X transitions and a new H ← X transition which occurs in the vacuum ultraviolet. Extensive spectral blending...

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Published inJournal of molecular spectroscopy Vol. 69; no. 1; pp. 25 - 36
Main Authors Brown, C.M, Ginter, M.L
Format Journal Article
LanguageEnglish
Published Elsevier Inc 01.01.1978
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Abstract The high dispersion absorption spectrum of the Ag2 molecule has been photographed in the ∼5300–1500-Å region. Observations include the previously reported A ← X, B ← X, C ← X, D ← X, and E ← X transitions and a new H ← X transition which occurs in the vacuum ultraviolet. Extensive spectral blending precluded detailed rotational analyses, but the band structures are consistent with ΔΩ = 0 and ΔΩ≥1 for D-X and C-X, respectively. The H state is perturbed and probably predissociated. The following molecular constants (in cm−1) were obtained from fitting bandhead data to the usual expressions: StateTeωcXωtX0.0192.00.58B35 838.6151.80.87C37 631.6171.00.84D39 014.5168.21.20E40 159.9146.11.58H58 273.1165.92.46
AbstractList The high dispersion absorption spectrum of the Ag2 molecule has been photographed in the ∼5300–1500-Å region. Observations include the previously reported A ← X, B ← X, C ← X, D ← X, and E ← X transitions and a new H ← X transition which occurs in the vacuum ultraviolet. Extensive spectral blending precluded detailed rotational analyses, but the band structures are consistent with ΔΩ = 0 and ΔΩ≥1 for D-X and C-X, respectively. The H state is perturbed and probably predissociated. The following molecular constants (in cm−1) were obtained from fitting bandhead data to the usual expressions: StateTeωcXωtX0.0192.00.58B35 838.6151.80.87C37 631.6171.00.84D39 014.5168.21.20E40 159.9146.11.58H58 273.1165.92.46
Author Ginter, M.L
Brown, C.M
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Cites_doi 10.1051/anphys/195913041111
10.1364/AO.12.001858
10.1364/JOSA.67.001323
10.1364/JOSA.67.000607
10.1088/0022-3700/6/1/017
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