Luminescence and scintillation properties of Ce3+-doped SiO2–Al2O3–BaF2–Gd2O3 glasses
Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration o...
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Published in | Optical materials Vol. 98; p. 109468 |
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Abstract | Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration of PL decay was observed with increasing Gd2O3 content. The scintillation efficiency of about 100% of the Bi4Ge3O12 scintillator was obtained for a 10%Gd2O3 containing glass while a high light yield (LY) of 2050 photons/MeV and energy resolution of 15.8% at 662 keV γ rays was obtained for a 15%Gd2O3 containing glass. The integrating-time dependence of LY value and LY ratio (α/γ ratio) under excitation with α- and γ-rays were also measured.
•Scintillation properties of Ce3+-doped Gd2O3 containing glasses were investigated.•Decay time shortening was achieved with increasing Gd2O3 content.•High RL intensity comparable to BGO was obtained for 10% Gd2O3 containing glass.•Light yield of 2100 photons/MeV was obtained for 15% Gd2O3 containing glass. |
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AbstractList | Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration of PL decay was observed with increasing Gd2O3 content. The scintillation efficiency of about 100% of the Bi4Ge3O12 scintillator was obtained for a 10%Gd2O3 containing glass while a high light yield (LY) of 2050 photons/MeV and energy resolution of 15.8% at 662 keV γ rays was obtained for a 15%Gd2O3 containing glass. The integrating-time dependence of LY value and LY ratio (α/γ ratio) under excitation with α- and γ-rays were also measured.
•Scintillation properties of Ce3+-doped Gd2O3 containing glasses were investigated.•Decay time shortening was achieved with increasing Gd2O3 content.•High RL intensity comparable to BGO was obtained for 10% Gd2O3 containing glass.•Light yield of 2100 photons/MeV was obtained for 15% Gd2O3 containing glass. |
ArticleNumber | 109468 |
Author | Chewpraditkul, Weerapong Sreebunpeng, Krittiya Lertloypanyachai, Prapon Pattanaboonmee, Nakarin Chewpraditkul, Warut Yoshino, Masao Chen, Danping Yawai, Nattasuda Liu, Liwan |
Author_xml | – sequence: 1 givenname: Weerapong surname: Chewpraditkul fullname: Chewpraditkul, Weerapong email: weerapong.che@kmutt.ac.th organization: King Mongkut's University of Technology Thonburi, Bangkok, 10140, Thailand – sequence: 2 givenname: Nakarin surname: Pattanaboonmee fullname: Pattanaboonmee, Nakarin organization: King Mongkut's University of Technology Thonburi, Bangkok, 10140, Thailand – sequence: 3 givenname: Nattasuda surname: Yawai fullname: Yawai, Nattasuda organization: King Mongkut's University of Technology Thonburi, Bangkok, 10140, Thailand – sequence: 4 givenname: Warut surname: Chewpraditkul fullname: Chewpraditkul, Warut organization: King Mongkut's University of Technology Thonburi, Bangkok, 10140, Thailand – sequence: 5 givenname: Prapon surname: Lertloypanyachai fullname: Lertloypanyachai, Prapon organization: Faculty of Science and Technology, Muban Chombueng Rajabhat University, Ratchaburi, 70150, Thailand – sequence: 6 givenname: Krittiya surname: Sreebunpeng fullname: Sreebunpeng, Krittiya organization: Faculty of Science, Chandrakasem Rajabhat University, Bangkok, 10900, Thailand – sequence: 7 givenname: Masao surname: Yoshino fullname: Yoshino, Masao organization: Institute for Materials Research, Tohoku University, Sendai, Miyagi, 980-8577, Japan – sequence: 8 givenname: Liwan surname: Liu fullname: Liu, Liwan organization: Shanghai Institute of Optics and Fine Mechanics, CAS, Shanghai, 201800, PR China – sequence: 9 givenname: Danping surname: Chen fullname: Chen, Danping organization: Shanghai Institute of Optics and Fine Mechanics, CAS, Shanghai, 201800, PR China |
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