Luminescence and scintillation properties of Ce3+-doped SiO2–Al2O3–BaF2–Gd2O3 glasses

Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration o...

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Published inOptical materials Vol. 98; p. 109468
Main Authors Chewpraditkul, Weerapong, Pattanaboonmee, Nakarin, Yawai, Nattasuda, Chewpraditkul, Warut, Lertloypanyachai, Prapon, Sreebunpeng, Krittiya, Yoshino, Masao, Liu, Liwan, Chen, Danping
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LanguageEnglish
Published Elsevier B.V 01.12.2019
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Abstract Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration of PL decay was observed with increasing Gd2O3 content. The scintillation efficiency of about 100% of the Bi4Ge3O12 scintillator was obtained for a 10%Gd2O3 containing glass while a high light yield (LY) of 2050 photons/MeV and energy resolution of 15.8% at 662 keV γ rays was obtained for a 15%Gd2O3 containing glass. The integrating-time dependence of LY value and LY ratio (α/γ ratio) under excitation with α- and γ-rays were also measured. •Scintillation properties of Ce3+-doped Gd2O3 containing glasses were investigated.•Decay time shortening was achieved with increasing Gd2O3 content.•High RL intensity comparable to BGO was obtained for 10% Gd2O3 containing glass.•Light yield of 2100 photons/MeV was obtained for 15% Gd2O3 containing glass.
AbstractList Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching method. The photoluminescence (PL) emission due to Ce3+: 5d1 → 4f transition was red-shifted with increasing Gd2O3 content. The acceleration of PL decay was observed with increasing Gd2O3 content. The scintillation efficiency of about 100% of the Bi4Ge3O12 scintillator was obtained for a 10%Gd2O3 containing glass while a high light yield (LY) of 2050 photons/MeV and energy resolution of 15.8% at 662 keV γ rays was obtained for a 15%Gd2O3 containing glass. The integrating-time dependence of LY value and LY ratio (α/γ ratio) under excitation with α- and γ-rays were also measured. •Scintillation properties of Ce3+-doped Gd2O3 containing glasses were investigated.•Decay time shortening was achieved with increasing Gd2O3 content.•High RL intensity comparable to BGO was obtained for 10% Gd2O3 containing glass.•Light yield of 2100 photons/MeV was obtained for 15% Gd2O3 containing glass.
ArticleNumber 109468
Author Chewpraditkul, Weerapong
Sreebunpeng, Krittiya
Lertloypanyachai, Prapon
Pattanaboonmee, Nakarin
Chewpraditkul, Warut
Yoshino, Masao
Chen, Danping
Yawai, Nattasuda
Liu, Liwan
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  organization: Institute for Materials Research, Tohoku University, Sendai, Miyagi, 980-8577, Japan
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  givenname: Liwan
  surname: Liu
  fullname: Liu, Liwan
  organization: Shanghai Institute of Optics and Fine Mechanics, CAS, Shanghai, 201800, PR China
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  givenname: Danping
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  organization: Shanghai Institute of Optics and Fine Mechanics, CAS, Shanghai, 201800, PR China
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Keywords Ce3
Scintillating glass
Light yield
Gd3
Luminescence
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Snippet Ce3+-doped glasses with composition of (65-x)SiO2 − 20Al2O3 –15BaF2 -xGd2O3 (x = 5, 10, 15, 20 and 25) were synthesized under CO atmosphere by melt-quenching...
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elsevier
SourceType Enrichment Source
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Publisher
StartPage 109468
SubjectTerms Ce3
Gd3
Light yield
Luminescence
Scintillating glass
Title Luminescence and scintillation properties of Ce3+-doped SiO2–Al2O3–BaF2–Gd2O3 glasses
URI https://dx.doi.org/10.1016/j.optmat.2019.109468
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