Preparation of Polymeric Stationary Phase for Use in Inverse Gas Chromatography

The preparation of ground low-density poly(ethylene) (LDPE), high-density poly(ethylene) (HDPE), and poly(ethylene terephthalate) (PET) materials suitable for use by inverse gas chromatography (IGC) experiments is described. Materials prepared showed a smaller and more uniform particle size, 83-86 µ...

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Published inPolymer-plastics technology and engineering Vol. 42; no. 5; pp. 959 - 970
Main Authors Suloff, E. C., Marcy, J. E., Brooks, D. R., Love, B. J.
Format Journal Article
LanguageEnglish
Published Philadelphia, PA Taylor & Francis Group 01.11.2003
Taylor & Francis
Subjects
Applied sciences
BET surface area
Exact sciences and technology
Inverse gas chromatography
Miscellaneous
Organic polymers
Physicochemistry of polymers
Properties and characterization
Stationary phase
Ethylene terephthalate polymer
Gas chromatography
Reversed phase chromatography
Particle size
Low density ethylene polymer
Preparation
High density ethylene polymer
Surface area
Density
Stationary phase
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Abstract The preparation of ground low-density poly(ethylene) (LDPE), high-density poly(ethylene) (HDPE), and poly(ethylene terephthalate) (PET) materials suitable for use by inverse gas chromatography (IGC) experiments is described. Materials prepared showed a smaller and more uniform particle size, 83-86 µm (200 mesh), than commercially available Chromosorb ® W solid chromatography support. In addition, the BET surface area of polymeric materials, 0.367-0.559 m 2 /cm 3 , was much greater than the surface area of 150- to 212-µm-diameter glass beads. The use of polymeric materials with uniform particle sizes and defined surface areas have several advantages over polymer coated Chromosorb ® W and glass beads in IGC experiments.
AbstractList The preparation of ground low-density poly(ethylene) (LDPE), high-density poly(ethylene) (HDPE), and poly(ethylene terephthalate) (PET) materials suitable for use by inverse gas chromatography (IGC) experiments is described. Materials prepared showed a smaller and more uniform particle size, 83-86 mum (200 mesh), than commercially available Chromosorb W solid chromatography support. In addition, the BET surface area of polymeric materials, 0.367-0.559m2/cm3, was much greater than the surface area of 150- to 212-*mm-diameter glass beads. The use of polymeric materials with uniform particle sizes and defined surface areas have several advantages over polymer coated Chromosorb R W and glass beads in IGC experiments.
The preparation of ground low-density poly(ethylene) (LDPE), high-density poly(ethylene) (HDPE), and poly(ethylene terephthalate) (PET) materials suitable for use by inverse gas chromatography (IGC) experiments is described. Materials prepared showed a smaller and more uniform particle size, 83-86 µm (200 mesh), than commercially available Chromosorb ® W solid chromatography support. In addition, the BET surface area of polymeric materials, 0.367-0.559 m 2 /cm 3 , was much greater than the surface area of 150- to 212-µm-diameter glass beads. The use of polymeric materials with uniform particle sizes and defined surface areas have several advantages over polymer coated Chromosorb ® W and glass beads in IGC experiments.
Author Marcy, J. E.
Brooks, D. R.
Love, B. J.
Suloff, E. C.
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Cites_doi 10.1002/app.1994.070511108
10.1016/0021-9797(81)90374-X
10.1002/app.1984.070291229
10.1364/AO.28.003985
10.1021/ma60032a014
10.1080/02652039709374573
10.1021/ja01269a023
10.1021/bk-1989-0391.ch002
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Issue 5
Keywords Ethylene terephthalate polymer
Gas chromatography
Reversed phase chromatography
Particle size
Low density ethylene polymer
Preparation
High density ethylene polymer
Surface area
Density
Stationary phase
Language English
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References CIT50070001
CIT50070012
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Jillavenkatesa A. (CIT50070007) 2001
CIT50070003
CIT50070005
CIT50070006
Su S.‐C. (CIT50070008) 1998; 46
Gavara R. (CIT50070004) 1997; 14
CIT50070009
Quirk R. P. (CIT50070010) 1989
Lawton E. L. (CIT50070011) 1989
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  doi: 10.1002/app.1994.070511108
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  doi: 10.1016/0021-9797(81)90374-X
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  volume-title: Polymer Handbook
  year: 1989
  ident: CIT50070011
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  doi: 10.1002/app.1984.070291229
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– start-page: V/15
  volume-title: Polymer Handbook
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– volume-title: National Institute of Standards and Technology Publication 960‐1‐Particle Size Characterization
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  doi: 10.1080/02652039709374573
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– volume: 46
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  year: 1998
  ident: CIT50070008
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  doi: 10.1021/ja01269a023
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SubjectTerms Applied sciences
BET surface area
Exact sciences and technology
Inverse gas chromatography
Miscellaneous
Organic polymers
Physicochemistry of polymers
Properties and characterization
Stationary phase
Title Preparation of Polymeric Stationary Phase for Use in Inverse Gas Chromatography
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