The role of small molecular cations in the chemical flow of the interstellar environments

Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of ma...

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Published inPhysical chemistry chemical physics : PCCP Vol. 25; no. 35; pp. 2337 - 23383
Main Authors González-Sánchez, Lola, Sathyamurthy, N, Gianturco, Francesco A
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 13.09.2023
Subjects
Cations
Chemical energy
Chemical reactions
Energy flow
Flow paths
Interstellar chemistry
Interstellar matter
Molecular clouds
Molecular ions
Positive ions
Stellar envelopes
Online AccessGet full text
ISSN1463-9076
1463-9084
1463-9084
DOI10.1039/d3cp03000h

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Abstract Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H + , He and He + , atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments. Formation and destruction channels for HeH + are superimposed on this image depicting NGC 7027, or the "Jewel Bug" nebula, where it has been detected recently. Image by NASA, ESA, and J. Kastner (RIT).
AbstractList Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H+, He and He+, atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments.Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H+, He and He+, atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments.
Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H + , He and He + , atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments. Formation and destruction channels for HeH + are superimposed on this image depicting NGC 7027, or the "Jewel Bug" nebula, where it has been detected recently. Image by NASA, ESA, and J. Kastner (RIT).
Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H + , He and He + , atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments.
Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to Diffuse Clouds. Their role in the multitude of molecular processes which have been found to occur in those environments has been the subject of many studies over the years, so that we have acquired by now a complex body of data on their chemical structures, their possible function within chemical reactions and their most likely paths to formation. In the present work we review a broad range of such molecular ions, focusing exclusively on positive ions involving the smallest and simplest cations which have been either detected or conjectured as present in the interstellar medium (ISM). We therefore consider mainly molecular cations formed with components like H, H+, He and He+, atomic species which are by far the most abundant baryons in the ISM in general. Their likely structures and their roles in a variety of chemical energy flow paths are discussed and presented within the context of their interstellar environments.
Author Sathyamurthy, N
Gianturco, Francesco A
González-Sánchez, Lola
AuthorAffiliation Departamento de Química Física
Universität Innsbruck
Institut für Ionenphysik und Angewandte Physik
Indian Institute of Science Education and Research Mohali
University of Salamanca
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  name: Indian Institute of Science Education and Research Mohali
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  name: Institut für Ionenphysik und Angewandte Physik
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  surname: Sathyamurthy
  fullname: Sathyamurthy, N
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  givenname: Francesco A
  surname: Gianturco
  fullname: Gianturco, Francesco A
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Snippet Molecular ions have been ubiquitous in a variety of environments in the interstellar medium, from Circumstellar Envelopes to Dark Molecular Clouds and to...
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SubjectTerms Cations
Chemical energy
Chemical reactions
Energy flow
Flow paths
Interstellar chemistry
Interstellar matter
Molecular clouds
Molecular ions
Positive ions
Stellar envelopes
Title The role of small molecular cations in the chemical flow of the interstellar environments
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