Preparation and cis-to- trans transformation study of square-planar [Pt(L n ) 2Cl 2] complexes bearing cytokinins derived from 6-benzylaminopurine (L n ) by view of NMR spectroscopy and X-ray crystallography

• Published in: Polyhedron Vol. 27; no. 12; pp. 2710 - 2720
• Main Authors: Szüčová, Lucie, Trávníček, Zdeněk, Popa, Igor, Marek, Jaromír
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 21.08.2008
• Subjects: Cytokinins; In vitro cytotoxicity; NMR spectroscopy; Pt(II) complexes; X-ray structures; Cytokinins; In vitro cytotoxicity; NMR spectroscopy; Pt(II) complexes; X-ray structures

Mononuclear, square-planar platinum(II) complexes involving derivatives of aromatic cytokinins as the ligands, and having the general formula cis-[Pt(L n ) 2Cl 2] ( 1– 3) and trans-[Pt(L n ) 2Cl 2] ( 4– 6), where n = 1–3, L 1 = 2-chloro-6-(benzylamino)-9-isopropylpurine, L 2 = 2-chloro-6-[(4-methoxy...