Molten Borates Fuel Cells — Mathematical modeling and identification of performances
The research presents an overview of the possibilities of using boron-containing compounds as electrolytes for fuel cells. The main assumption here is to develop a molten carbonate fuel cell type power source, where the molten electrolyte is kept by a ceramic matrix between the electrodes. In the ca...
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| Published in | Renewable & sustainable energy reviews Vol. 190; p. 113949 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
01.02.2024
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| ISSN | 1364-0321 1879-0690 |
| DOI | 10.1016/j.rser.2023.113949 |
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| Abstract | The research presents an overview of the possibilities of using boron-containing compounds as electrolytes for fuel cells. The main assumption here is to develop a molten carbonate fuel cell type power source, where the molten electrolyte is kept by a ceramic matrix between the electrodes. In the cases which are described in this study, attempts were made to develop electrolytes based on borates. Whereas the reported studies contain very little information on this subject, it was possible to identify several promising compounds and to extrapolate their performance to higher temperatures. Reported data on the temperature at eutectic points suggest that the operating range of such electrolytes is at a level like the molten carbonate fuel cell. The study presents a proposal for a mathematical model of a new type of fuel cell based on molten borates. The mathematical model is based on the reduced order model, supplemented with the influence of the ceramic matrix on the resulting ionic conductivity of the electrolyte layer. The model was used to determine potential performances for a few selected borates and a sensitivity analysis of selected geometric parameters was performed for the best of them. The results obtained were compared against the standard molten carbonate fuel cell.
•Conductivities of various boron compounds have been investigated and compared.•Application of boron-containing compounds in fuel cells electrolyte has been analyzed.•A model of molten borate fuel cell has been developed.•Borates occurring to have higher potential than carbonates what might result in higher efficiency. |
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| AbstractList | The research presents an overview of the possibilities of using boron-containing compounds as electrolytes for fuel cells. The main assumption here is to develop a molten carbonate fuel cell type power source, where the molten electrolyte is kept by a ceramic matrix between the electrodes. In the cases which are described in this study, attempts were made to develop electrolytes based on borates. Whereas the reported studies contain very little information on this subject, it was possible to identify several promising compounds and to extrapolate their performance to higher temperatures. Reported data on the temperature at eutectic points suggest that the operating range of such electrolytes is at a level like the molten carbonate fuel cell. The study presents a proposal for a mathematical model of a new type of fuel cell based on molten borates. The mathematical model is based on the reduced order model, supplemented with the influence of the ceramic matrix on the resulting ionic conductivity of the electrolyte layer. The model was used to determine potential performances for a few selected borates and a sensitivity analysis of selected geometric parameters was performed for the best of them. The results obtained were compared against the standard molten carbonate fuel cell.
•Conductivities of various boron compounds have been investigated and compared.•Application of boron-containing compounds in fuel cells electrolyte has been analyzed.•A model of molten borate fuel cell has been developed.•Borates occurring to have higher potential than carbonates what might result in higher efficiency. |
| ArticleNumber | 113949 |
| Author | Martsinchyk, Aliaxandr Milewski, Jarosław Szabłowski, Łukasz Dybinski, Olaf Świrski, Konrad Szczęśniak, Arkadiusz Siekierski, Maciej |
| Author_xml | – sequence: 1 givenname: Jarosław orcidid: 0000-0003-1215-1802 surname: Milewski fullname: Milewski, Jarosław email: jaroslaw.milewski@pw.edu.pl organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland – sequence: 2 givenname: Arkadiusz surname: Szczęśniak fullname: Szczęśniak, Arkadiusz organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland – sequence: 3 givenname: Łukasz orcidid: 0000-0002-6646-2297 surname: Szabłowski fullname: Szabłowski, Łukasz organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland – sequence: 4 givenname: Aliaxandr orcidid: 0000-0003-4342-149X surname: Martsinchyk fullname: Martsinchyk, Aliaxandr organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland – sequence: 5 givenname: Maciej surname: Siekierski fullname: Siekierski, Maciej organization: Faculty of Chemistry, Warsaw University of Technology, 3 Noakowskiego Street, 00-664, Warsaw, Poland – sequence: 6 givenname: Olaf orcidid: 0000-0002-9723-5310 surname: Dybinski fullname: Dybinski, Olaf organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland – sequence: 7 givenname: Konrad surname: Świrski fullname: Świrski, Konrad organization: Faculty of Power and Aeronautical Engineering, Warsaw University of Technology, Institute of Heat Engineering, 21/25 Nowowiejska Street, 00-665, Warsaw, Poland |
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| Cites_doi | 10.1063/1.357318 10.1016/j.ijhydene.2020.12.073 10.1063/1.555693 10.1149/2.0771805jes 10.1021/ic701059z 10.1002/adma.200602033 10.1016/j.jpowsour.2004.12.060 10.1016/j.electacta.2009.11.015 10.1016/j.ijhydene.2023.06.116 10.1063/1.359624 10.1016/j.ijhydene.2020.12.024 10.1016/j.ijhydene.2013.06.002 10.1016/S0196-8904(97)10022-X 10.1002/aic.15160 10.1016/S0196-8904(02)00253-4 10.1016/S0009-2509(98)00414-X 10.1016/j.jpowsour.2017.03.091 10.1155/2014/625893 10.1557/PROC-210-633 10.1016/j.applthermaleng.2011.09.023 10.1016/S0009-2509(02)00644-9 10.1109/60.815119 10.1063/1.1505980 10.5796/kogyobutsurikagaku.66.817 10.1002/pssa.2211380102 10.1021/acs.chemmater.7b01831 10.1016/j.ijhydene.2011.05.122 |
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| Keywords | Medium temperature fuel cell Electrolytes Molten borates Mathematical modeling Fuel cells |
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| SubjectTerms | Electrolytes Fuel cells Mathematical modeling Medium temperature fuel cell Molten borates |
| Title | Molten Borates Fuel Cells — Mathematical modeling and identification of performances |
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