Dinuclear oxidovanadium(V) complexes incorporating N, N, O, O coordinating ligands: Synthesis, structure, spectral, DFT and TDDFT study

• Published in: Polyhedron Vol. 54; pp. 228 - 236
• Main Authors: Mondal, Pallab, Hens, Amar, Rajak, Kajal Krishna
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 30.04.2013; Elsevier
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Crystallography; DFT studies; Oxidovanadium(V) complexes; Physical Sciences; Science & Technology; Spectral study; X-ray structure; Spectral study; DFT studies; Oxidovanadium(V) complexes; X-ray structure; OXIDATION; CONSISTENT PERTURBATION-THEORY; SPECTROSCOPIC PROPERTIES; OXOVANADIUM(V) COMPLEXES; REACTIVITY; VANADIUM; SCHIFF-BASES; CHEMISTRY; DENSITY-FUNCTIONAL THEORY; BINDING

Three new dinuclear oxidovanadium(V) complexes have been synthesized using N, N, O, O coordinating ligands. The complexes are isolated and characterized by different spectroscopic techniques. X-ray structure of a representative complex has been determined. The electronic structure, absorption and CD...