Synthesis and properties of new tetrachlorocobaltate (II) and tetrachloromanganate (II) anion salts with dicationic counterions

• Published in: Polyhedron Vol. 30; no. 3; pp. 497 - 507
• Main Authors: Chang, Jui-Cheng, Ho, Wen-Yueh, Sun, I-Wen, Chou, Yu-Kai, Hsieh, Hsin-Hsiu, Wu, Tzi-Yi
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 21.02.2011; Elsevier
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Crystallography; Dication; Ionic liquid; Magnetic susceptibility; Physical Sciences; Science & Technology; Tetrachlorocobaltate (II) anion; Tetrachloromanganate (II) anion; Tetrachlorocobaltate (II) anion; Dication; Tetrachloromanganate (II) anion; Ionic liquid; Magnetic susceptibility; TRANSITION; BEHAVIOR; IONIC LIQUIDS

New tetrachlorocobaltate (II) and tetrachloromanganate (II) ionic compounds containing various counterdications were synthesized and characterized. These salts are soluble in polar solvents such as methanol and water. Physical properties such as thermal stability, melting point, and magnetic suscept...