Physicochemical insight into the metal atom effect on magnetocaloric behavior of paramagnetic metalloporphyrins

• Published in: Polyhedron Vol. 236; p. 116384
• Main Authors: Lomova, T.N., Korolev, V.V., Ramazanova, A.G., Ovchenkova, E.N., Bichan, N.G., Motorina, E.V., Tsaturyan, A.A.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.05.2023
• Subjects: Chemical structure; Cobalt(II); Complexes; Magnetization thermodynamics; Magnetocaloric effect; Manganese(III); Molybdenum(V); Porphyrins; Cobalt(II); Magnetocaloric effect; Magnetization thermodynamics; Chemical structure; Manganese(III); Complexes; Porphyrins; Molybdenum(V)

Heat capacities, magnetization thermodynamic parameters, and magnetocaloric effect in cobalt(II), manganese(III), and molybdenum(III) complexes with porphyrins were studied using DSC, the direct microcalorimetric method, and the DFT approach. Contribution of spin density distribution between a centr...