Upconversion emission of SrYbF5：Er3＋nanosheets modified by Tm3＋ions
Through a hydrothermal route, the Er3＋and Tm3＋co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, th...
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| Published in | Journal of rare earths Vol. 31; no. 11; pp. 1053 - 1058 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.11.2013
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| Abstract | Through a hydrothermal route, the Er3＋and Tm3＋co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3＋ions centered at 474 nm （1G4→3H6）, 679 nm （3F2→3H6）, 699 nm （3F3→3H6）, 803 nm （3H4→3H6） and emissions of Er3＋ions centered at 522 nm （2H11/2→4I15/2）, 543 nm （4S3/2→4I15/2）, 654 nm （4F9/2→4I15/2） were observed. The upconversion emissions of Er3＋ions were adjusted by the concentration of Tm3＋ions. The energy transfer mechanisms among Er3＋-Yb3＋-Tm3＋in SrYbF5 nanosheets were discussed. |
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| AbstractList | Through a hydrothermal route, the Er3+ and Tm3+ co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spectra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3+ ions centered at 474 nm (1G4a3H6), 679 nm (3F2a3H6), 699 nm (3F3a3H6), 803 nm (3H4a3H6) and emissions of Er3+ ions centered at 522 nm (2H11/2a4I15/2), 543 nm (4S3/2a 4I15/2), 654 nm (4F9/2a4I15/2) were observed. The upconversion emissions of Er3+ ions were adjusted by the concentration of Tm3+ ions. The energy transfer mechanisms among Er3+-Yb3+-Tm3+ in SrYbF5 nanosheets were discussed. Through a hydrothermal route, the Er3＋and Tm3＋co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3＋ions centered at 474 nm （1G4→3H6）, 679 nm （3F2→3H6）, 699 nm （3F3→3H6）, 803 nm （3H4→3H6） and emissions of Er3＋ions centered at 522 nm （2H11/2→4I15/2）, 543 nm （4S3/2→4I15/2）, 654 nm （4F9/2→4I15/2） were observed. The upconversion emissions of Er3＋ions were adjusted by the concentration of Tm3＋ions. The energy transfer mechanisms among Er3＋-Yb3＋-Tm3＋in SrYbF5 nanosheets were discussed. Through a hydrothermal route, the Er3+ and Tm3+ co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spectra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3+ ions centered at 474 nm (1G4→3H6), 679 nm (3F2→3H6), 699 nm (3F3→3H6), 803 nm (3H4→3H6) and emissions of Er3+ ions centered at 522 nm (2H11/2→4I15/2), 543 nm (4S3/2→ 4I15/2), 654 nm (4F9/2→4I15/2) were observed. The upconversion emissions of Er3+ ions were adjusted by the concentration of Tm3+ ions. The energy transfer mechanisms among Er3+-Yb3+-Tm3+ in SrYbF5 nanosheets were discussed. Upconversion PL emission spectra of SrYbF5:2 mol.%Er3+ nanosheets and SrYbF5: 2 mol.%Er3+/1 mol.%Tm3+ nanosheets under 980 nm excitation |
| Author | 刘晴 颜晓红 陈远 王祥夫 |
| AuthorAffiliation | College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China School of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210046, China |
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| CitedBy_id | crossref_primary_10_3390_ma16010061 crossref_primary_10_1016_j_jfluchem_2020_109696 crossref_primary_10_1016_S1002_0721_17_60930_X crossref_primary_10_1007_s10854_017_7534_x crossref_primary_10_1021_acs_inorgchem_8b00484 crossref_primary_10_1088_2053_1583_abb6b8 crossref_primary_10_1016_j_jphotochem_2019_111908 crossref_primary_10_1088_1742_6596_2680_1_012040 crossref_primary_10_1002_bio_4603 crossref_primary_10_1016_S1002_0721_14_60443_9 |
| Cites_doi | 10.1364/OL.22.001849 10.1080/10587250210466 10.1103/PhysRevLett.72.416 10.1103/PhysRevB.61.3337 10.1016/0040-6090(94)06255-J 10.1021/ja052583o 10.1021/ja3016236 10.1002/adma.200400772 10.1016/j.cplett.2009.03.008 10.1016/S1002-0721(10)60553-4 10.1088/0022-3727/35/20/307 10.1021/cr020357g 10.1002/1521-4095(200110)13:20<1557::AID-ADMA1557>3.0.CO;2-W 10.1364/OL.30.001437 10.1016/j.optcom.2009.01.013 10.1038/35035045 10.1002/adfm.200305044 10.1063/1.371177 10.1039/c2cp40523g 10.1007/s10853-013-7163-6 10.1063/1.126092 10.1021/nl025562q |
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| Copyright | 2013 The Chinese Society of Rare Earths |
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| DocumentTitleAlternate | Upconversion emission of SrYbF5：Er3＋nanosheets modified by Tm3＋ions |
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| Keywords | upconversion luminescence Tm3 Er3 nanosheets rare earths |
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| Notes | Through a hydrothermal route, the Er3＋and Tm3＋co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and luminescence spec-tra. Under the excitation of 980 nm laser irradiation, the upconversion emissions of Tm3＋ions centered at 474 nm （1G4→3H6）, 679 nm （3F2→3H6）, 699 nm （3F3→3H6）, 803 nm （3H4→3H6） and emissions of Er3＋ions centered at 522 nm （2H11/2→4I15/2）, 543 nm （4S3/2→4I15/2）, 654 nm （4F9/2→4I15/2） were observed. The upconversion emissions of Er3＋ions were adjusted by the concentration of Tm3＋ions. The energy transfer mechanisms among Er3＋-Yb3＋-Tm3＋in SrYbF5 nanosheets were discussed. 11-2788/TF LIU Qing YAN Xiaohong CHEN Yuan WANG Xiangfu （1. College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, China; 2. School of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210046, China） nanosheets; upconversion; luminescence; Er3＋; Tm3＋; rare earths ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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| PublicationTitle | Journal of rare earths |
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| Snippet | Through a hydrothermal route, the Er3＋and Tm3＋co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction,... Through a hydrothermal route, the Er3+ and Tm3+ co-doped SrYbF5 nanosheets were synthesized. The resulting samples were characterized by X-ray diffraction,... |
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| SubjectTerms | Emission spectroscopy Er3 Luminescence Nanocomposites Nanomaterials nanosheets Nanostructure Rare earth metals rare earths Spectra Tm3 Upconversion X射线光谱 X射线衍射 上转换发光 扫描电子显微镜 离子修饰 纳米 能量色散 铒离子 |
| Title | Upconversion emission of SrYbF5：Er3＋nanosheets modified by Tm3＋ions |
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