Sustainable nanoparticles of Non-Zero-valent iron (nZVI) production from various biological wastes
Given the growing importance of biological wastes (such as leaves from pomegranate, green tea, oak, lemon, orange, peach, kiwi, and neem) based iron nanoparticles over the past ten years and their applications in the environment, it is important to investigate new methods for nanoparticle production...
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Published in | Journal of King Saud University. Science Vol. 36; no. 11; p. 103553 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.12.2024
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Abstract | Given the growing importance of biological wastes (such as leaves from pomegranate, green tea, oak, lemon, orange, peach, kiwi, and neem) based iron nanoparticles over the past ten years and their applications in the environment, it is important to investigate new methods for nanoparticle production. Significant research has been conducted in this field as synthesizing these materials now requires careful consideration of green chemistry principles, minimization of disposal, cleaner solvents, energy efficiency, and caring precursor ingredients. The goal of this work is to evaluate the characteristics of environmentally friendly, sustainable non-zero-valent Iron (nZVI) nanoparticle productionfrom different tree’s’ leaves. The requirements required for a product for environmental cleanup were taken into consideration when examining size, form, reactivity, and aggregation propensity. Three categories can be formed from the results of extracts in terms of antioxidant measurements (reported concentration of Fe (II)): >60 mmol/L, 20 mmol/L to 40 mmol/L, and 2 mmol/L to 5 mmol/L. Neem, oak, and green tea leaves yield the highest effects when compared to other tree leaves. It is possible to inject a different emulsion into the contaminated zone that contains nZVI, vegetable oil, and water. The best leaf extracts and operating conditions for generating sustainable nanoparticles from the bio-wastes of plant leaves must be chosen in order to use green nZVIs in environmental cleanup. These environmentally friendly nZVI nanoparticles can be used to treat impure waters to get rid of heavy metals and can useas an emulsion for paints. |
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AbstractList | Given the growing importance of biological wastes (such as leaves from pomegranate, green tea, oak, lemon, orange, peach, kiwi, and neem) based iron nanoparticles over the past ten years and their applications in the environment, it is important to investigate new methods for nanoparticle production. Significant research has been conducted in this field as synthesizing these materials now requires careful consideration of green chemistry principles, minimization of disposal, cleaner solvents, energy efficiency, and caring precursor ingredients. The goal of this work is to evaluate the characteristics of environmentally friendly, sustainable non-zero-valent Iron (nZVI) nanoparticle productionfrom different tree’s’ leaves. The requirements required for a product for environmental cleanup were taken into consideration when examining size, form, reactivity, and aggregation propensity. Three categories can be formed from the results of extracts in terms of antioxidant measurements (reported concentration of Fe (II)): >60 mmol/L, 20 mmol/L to 40 mmol/L, and 2 mmol/L to 5 mmol/L. Neem, oak, and green tea leaves yield the highest effects when compared to other tree leaves. It is possible to inject a different emulsion into the contaminated zone that contains nZVI, vegetable oil, and water. The best leaf extracts and operating conditions for generating sustainable nanoparticles from the bio-wastes of plant leaves must be chosen in order to use green nZVIs in environmental cleanup. These environmentally friendly nZVI nanoparticles can be used to treat impure waters to get rid of heavy metals and can useas an emulsion for paints. |
ArticleNumber | 103553 |
Author | Gupta, Anirudh Gupta, Manish Senthilkumar, N. Yusuf, Mohammad Raja, L. Masih, Jolly Singh, Vikash Sathish, T. Al-Enizi, Abdullah M. Pandit, Bidhan Kumar, Anuj |
Author_xml | – sequence: 1 givenname: T. surname: Sathish fullname: Sathish, T. email: Sathish.sailer@gmail.com organization: Department of Mechanical Engineering, Saveetha School of Engineering, SIMATS, Chennai, Tamil Nadu, India – sequence: 2 givenname: Jolly surname: Masih fullname: Masih, Jolly organization: School of Retail Management (Specialisation is Agribusiness), Symbiosis University of Applied Sciences, Indore, Madhya Pradesh, India – sequence: 3 givenname: Anirudh surname: Gupta fullname: Gupta, Anirudh organization: Department of Applied Chemistry, NIT Jalandhar, Jalandhar, Punjab, India – sequence: 4 givenname: Anuj surname: Kumar fullname: Kumar, Anuj organization: Department of Chemistry, GLA University, Mathura 281406, India – sequence: 5 givenname: L. surname: Raja fullname: Raja, L. organization: Department of Electronics and Communication Engineering, Sri Eshwar College of Engineering, Coimbatore, Tamil Nadu, India – sequence: 6 givenname: Vikash surname: Singh fullname: Singh, Vikash organization: Department of Civil Engineering, Institute of Engineering and Technology, Lucknow, Uttar Pradesh, India – sequence: 7 givenname: Abdullah M. surname: Al-Enizi fullname: Al-Enizi, Abdullah M. organization: Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia – sequence: 8 givenname: Bidhan surname: Pandit fullname: Pandit, Bidhan organization: Department of Materials, Imperial College London, London SW7 2AZ, United Kingdom – sequence: 9 givenname: Manish surname: Gupta fullname: Gupta, Manish organization: Chitkara Centre for Research and Development, Chitkara University, Himachal Pradesh,174103, India – sequence: 10 givenname: N. surname: Senthilkumar fullname: Senthilkumar, N. organization: Department of Chemistry, Allied Sciences, Graphic Era Hill University, Dehradun, Uttarakhand 248002, India – sequence: 11 givenname: Mohammad orcidid: 0000-0003-2442-5161 surname: Yusuf fullname: Yusuf, Mohammad email: mohd.yusuf@uregina.ca, yusufshaikh.amu@gmail.com organization: Clean Energy Technologies Research Institute (CETRI), Process Systems Engineering, Faculty of Engineering & Applied Science, University of Regina, 3737 Wascana Parkway, SK S4S 0A2, Canada |
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Cites_doi | 10.1002/clen.201300827 10.1016/j.jmrt.2024.02.134 10.1016/j.saa.2011.03.040 10.1016/S2221-1691(11)60096-8 10.1016/j.memsci.2011.05.054 10.1016/j.cej.2013.12.049 10.1007/s41742-019-00187-8 10.1016/j.scitotenv.2012.12.033 10.1016/j.chemosphere.2011.11.041 10.3390/nano10050917 10.1039/b804703k 10.1021/es970039c 10.1016/j.indcrop.2024.118969 10.1016/j.surfin.2023.103088 10.1080/10408430601057611 10.1039/b909148c 10.1016/j.jksus.2024.103426 10.1021/bp034070w 10.1039/B921203P 10.1016/j.jhazmat.2014.01.009 10.1007/s40033-024-00772-y 10.1111/j.1365-2621.2011.02576.x |
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Keywords | Nanoparticles Pollution Energy Volume of solvent Antioxidant capacity Environment Sustainable Waste Leaf mass ratio |
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