P atom as ligand in transition metal chemistry: Structural aspects
[Display omitted] •Structural features of phosphide complexes have been revised and analysed.•Bonding patterns of the different coordination modes have been rationalised.•31P{1H} NMR spectral data of these phosphide complexes have been examined. The chemistry of transition metal compounds that conta...
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Published in | Coordination chemistry reviews Vol. 434; p. 213730 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.05.2021
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Abstract | [Display omitted]
•Structural features of phosphide complexes have been revised and analysed.•Bonding patterns of the different coordination modes have been rationalised.•31P{1H} NMR spectral data of these phosphide complexes have been examined.
The chemistry of transition metal compounds that contain a phosphorus atom acting as ligand, sometimes called “naked” phosphorus, started at the end of the last century. However, it is still an area of permanent interest and expansion, in which new examples of complexes with novel structural features are appearing in the literature. In this review, the phosphide complexes are classified based on the different coordination modes found in structurally characterised complexes for coordination numbers from 1 to 4 at the phosphorous atom. Structural aspects are discussed and, in some cases, the bonding patterns rationalised. Additionally to the structural analysis, data from 31P NMR spectroscopy, as a potent characterization tool, are also revised and briefly analysed. |
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AbstractList | [Display omitted]
•Structural features of phosphide complexes have been revised and analysed.•Bonding patterns of the different coordination modes have been rationalised.•31P{1H} NMR spectral data of these phosphide complexes have been examined.
The chemistry of transition metal compounds that contain a phosphorus atom acting as ligand, sometimes called “naked” phosphorus, started at the end of the last century. However, it is still an area of permanent interest and expansion, in which new examples of complexes with novel structural features are appearing in the literature. In this review, the phosphide complexes are classified based on the different coordination modes found in structurally characterised complexes for coordination numbers from 1 to 4 at the phosphorous atom. Structural aspects are discussed and, in some cases, the bonding patterns rationalised. Additionally to the structural analysis, data from 31P NMR spectroscopy, as a potent characterization tool, are also revised and briefly analysed. |
ArticleNumber | 213730 |
Author | Galindo, Agustín Conejo, María del Mar Montilla, Francisco Pastor, Antonio |
Author_xml | – sequence: 1 givenname: María del Mar surname: Conejo fullname: Conejo, María del Mar – sequence: 2 givenname: Antonio surname: Pastor fullname: Pastor, Antonio – sequence: 3 givenname: Francisco surname: Montilla fullname: Montilla, Francisco – sequence: 4 givenname: Agustín surname: Galindo fullname: Galindo, Agustín email: galindo@us.es |
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CitedBy_id | crossref_primary_10_1002_anie_202212488 crossref_primary_10_1021_acs_inorgchem_2c02646 crossref_primary_10_1021_acs_inorgchem_3c00518 crossref_primary_10_1039_D2NR05076E crossref_primary_10_1039_D4CC01001A crossref_primary_10_1002_ange_202212488 crossref_primary_10_1039_D3DT02472E crossref_primary_10_3390_molecules29092025 crossref_primary_10_1039_D3DT03490A |
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