Syntheses, structures and magnetic properties of three 1-D chain metal–nitroxide coordination polymers bridged by e,e-trans-1,4-cyclohexanedicarboxylate

• Published in: Inorganica Chimica Acta Vol. 375; no. 1; pp. 298 - 304
• Main Authors: Wei, Hai-Xia, Chen, Yi-Wen, Gao, Dong-Zhao, Sun, Ya-Qiu, Zhang, Guo-Ying, Xu, Yan-Yan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.09.2011
• Subjects: 1,4-Cyclohexanedicarboxylic acid; Magnetic property; Metal complex; Nitronyl nitroxide radical; Magnetic property; Metal complex; 1,4-Cyclohexanedicarboxylic acid; Nitronyl nitroxide radical

Three one-dimensional metal–nitroxide polymers have been synthesized. They all crystallize in neutral 1-D chains where metal–nitroxide units [M(NIT4Py)2(H2O)2] are linked by the linear 1,4-cyclohexanedicarboxylate dianion with the 1,4-chdc only possessing the e,e-trans-conformation. The magnetic mea...