Implanting multi-functional ionic liquids into MOF nodes for boosting CO2 cycloaddition under solventless and cocatalyst-free conditions

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 490; p. 151657
• Main Authors: Chen, Yan, Li, Fangfang, Liu, Laiyao, Zhou, Ying-Hua
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.06.2024
• Subjects: CO2; Epoxide cycloaddition; Heterogeneous catalysis; Ionic liquid; MIL-101; MIL-101; Epoxide cycloaddition; Heterogeneous catalysis; CO2; Ionic liquid

•MIL-101(Cr) nodes were tethered by ionic liquids bearing hydrogen-bond donor.•MIL-101(Cr) derivative as catalyst boosted the epoxide cycloaddition with CO2.•The heterogeneous catalyst containing carboxyl displayed superior activity.•The catalyst exhibited the great durability and recyclability. It...