Multi-hydrophilic groups synergistic assembly ionic HOFs with multiple-water clusters and superprotonic single-crystal conductivity
Two ionic hydrogen-bonded organic frameworks ( iHOF-43 and iHOF-44 ) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a -axis attained 1.66 × 10 −1 S cm −1 , which provided a guid...
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| Published in | Chemical communications (Cambridge, England) Vol. 61; no. 2; pp. 434 - 437 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
04.03.2025
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| Subjects | |
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| Abstract | Two ionic hydrogen-bonded organic frameworks (
iHOF-43
and
iHOF-44
) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of
iHOF-43
along the
a
-axis attained 1.66 × 10
−1
S cm
−1
, which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters.
In this paper,
iHOF-43
and
iHOF-44
, which contain multiple water clusters, were prepared by introducing ligands that contain three hydrophilic functional groups. The proton conductivity (
a
-axis) of
iHOF-43
at 90 °C and 98% RH was 1.66 × 10
−1
S cm
−1
. |
|---|---|
| AbstractList | Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a-axis attained 1.66 × 10-1 S cm-1, which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters.Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a-axis attained 1.66 × 10-1 S cm-1, which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters. Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the -axis attained 1.66 × 10 S cm , which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters. Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a-axis attained 1.66 × 10−1 S cm−1, which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters. Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a -axis attained 1.66 × 10 −1 S cm −1 , which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters. Two ionic hydrogen-bonded organic frameworks ( iHOF-43 and iHOF-44 ) containing multiple-water clusters were prepared through the synergistic induction strategy of the multi-hydrophilic groups. The proton conductivity of iHOF-43 along the a -axis attained 1.66 × 10 −1 S cm −1 , which provided a guiding direction for the design of superprotonic conductive materials with multiple-water clusters. In this paper, iHOF-43 and iHOF-44 , which contain multiple water clusters, were prepared by introducing ligands that contain three hydrophilic functional groups. The proton conductivity ( a -axis) of iHOF-43 at 90 °C and 98% RH was 1.66 × 10 −1 S cm −1 . |
| Author | Bai, Xiang-Tian Cao, Li-Hui Chen, Xu-Yong Zhang, Wenmin Li, Shu-Hui |
| AuthorAffiliation | Department of Chemical Engineering and Food Science College of Chemistry and Chemical Engineering Zhengzhou University of Technology Shaanxi Key Laboratory of Chemical Additives for Industry Shaanxi University of Science and Technology |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI 2406278 Electronic supplementary information (ESI) available: Materials, experimental details, crystal data, crystal structures, thermogravimetric analysis, Fourier-transform infrared, proton conductivity, and digital images. CCDC 2406277 https://doi.org/10.1039/d4cc06654e and ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
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| Snippet | Two ionic hydrogen-bonded organic frameworks (
iHOF-43
and
iHOF-44
) containing multiple-water clusters were prepared through the synergistic induction... Two ionic hydrogen-bonded organic frameworks (iHOF-43 and iHOF-44) containing multiple-water clusters were prepared through the synergistic induction strategy... |
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| SubjectTerms | Clusters Hydrogen bonding Hydrophilicity Single crystals |
| Title | Multi-hydrophilic groups synergistic assembly ionic HOFs with multiple-water clusters and superprotonic single-crystal conductivity |
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