Combination of efficient charge separation with the assistance of novel dual Z-scheme system: self-assembly photocatalyst Ag@AgI/BiOI modified oxygen-doped carbon nitride nanosheet with enhanced photocatalytic performance
Natural or artificial Z-scheme systems have been applied for tackling environment pollution and energy crisis owing to the high reduction and oxidation ability driven by the unique interface charge-pairs transfer. However, a dual Z-scheme system combining direct Z-scheme and indirect Z-scheme is sel...
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Published in | Catalysis science & technology Vol. 8; no. 4; pp. 1161 - 1175 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Cambridge
Royal Society of Chemistry
2018
|
Subjects | |
Online Access | Get full text |
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Abstract | Natural or artificial Z-scheme systems have been applied for tackling environment pollution and energy crisis owing to the high reduction and oxidation ability driven by the unique interface charge-pairs transfer. However, a dual Z-scheme system combining direct Z-scheme and indirect Z-scheme is seldom adopted for photocatalysis. In this study, the self-assembly photocatalyst Ag@AgI/BiOI/g-C
3
N
4
was successfully fabricated based on the dual Z-scheme system combining direct and indirect Z-scheme systems. The synergistic effect of the dual Z-scheme system towards tetracycline (TC) degradation over the hybrid composites under visible light irradiation was investigated. Compared with single Z-scheme system composites of BiOI/g-C
3
N
4
and AgI/BiOI, the as-synthesized composite of AgI/BiOI/g-C
3
N
4
exhibited superior photocatalytic performance under identical conditions. The dual Z-scheme system was verified by active species generation (˙O
2
−
, ˙OH and h
+
), trapping experiments and ESR analysis. Furthermore, the photostability and practical application were investigated based on a recycle experiment and controllable experiments. A possible dual Z-scheme mechanism for enhanced photocatalytic performance with ultra-fast charge-separation efficiency and high redox ability was proposed. This study will provide new insight to the design of novel heterojunction composites based on the dual Z-scheme system to deal with organic pollution and energy crisis. |
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AbstractList | Natural or artificial Z-scheme systems have been applied for tackling environment pollution and energy crisis owing to the high reduction and oxidation ability driven by the unique interface charge-pairs transfer. However, a dual Z-scheme system combining direct Z-scheme and indirect Z-scheme is seldom adopted for photocatalysis. In this study, the self-assembly photocatalyst Ag@AgI/BiOI/g-C
3
N
4
was successfully fabricated based on the dual Z-scheme system combining direct and indirect Z-scheme systems. The synergistic effect of the dual Z-scheme system towards tetracycline (TC) degradation over the hybrid composites under visible light irradiation was investigated. Compared with single Z-scheme system composites of BiOI/g-C
3
N
4
and AgI/BiOI, the as-synthesized composite of AgI/BiOI/g-C
3
N
4
exhibited superior photocatalytic performance under identical conditions. The dual Z-scheme system was verified by active species generation (˙O
2
−
, ˙OH and h
+
), trapping experiments and ESR analysis. Furthermore, the photostability and practical application were investigated based on a recycle experiment and controllable experiments. A possible dual Z-scheme mechanism for enhanced photocatalytic performance with ultra-fast charge-separation efficiency and high redox ability was proposed. This study will provide new insight to the design of novel heterojunction composites based on the dual Z-scheme system to deal with organic pollution and energy crisis. Natural or artificial Z-scheme systems have been applied for tackling environment pollution and energy crisis owing to the high reduction and oxidation ability driven by the unique interface charge-pairs transfer. However, a dual Z-scheme system combining direct Z-scheme and indirect Z-scheme is seldom adopted for photocatalysis. In this study, the self-assembly photocatalyst Ag@AgI/BiOI/g-C3N4 was successfully fabricated based on the dual Z-scheme system combining direct and indirect Z-scheme systems. The synergistic effect of the dual Z-scheme system towards tetracycline (TC) degradation over the hybrid composites under visible light irradiation was investigated. Compared with single Z-scheme system composites of BiOI/g-C3N4 and AgI/BiOI, the as-synthesized composite of AgI/BiOI/g-C3N4 exhibited superior photocatalytic performance under identical conditions. The dual Z-scheme system was verified by active species generation (·O2−, ·OH and h+), trapping experiments and ESR analysis. Furthermore, the photostability and practical application were investigated based on a recycle experiment and controllable experiments. A possible dual Z-scheme mechanism for enhanced photocatalytic performance with ultra-fast charge-separation efficiency and high redox ability was proposed. This study will provide new insight to the design of novel heterojunction composites based on the dual Z-scheme system to deal with organic pollution and energy crisis. |
Author | Huang, Da-Wei Liang, Chao Guo, Hai Wen, Xiao-Ju Zeng, Guang-Ming Niu, Cheng-Gang Yang, Shi-Feng |
Author_xml | – sequence: 1 givenname: Chao surname: Liang fullname: Liang, Chao organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 – sequence: 2 givenname: Cheng-Gang orcidid: 0000-0002-5904-9111 surname: Niu fullname: Niu, Cheng-Gang organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 – sequence: 3 givenname: Hai surname: Guo fullname: Guo, Hai organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 – sequence: 4 givenname: Da-Wei surname: Huang fullname: Huang, Da-Wei organization: South China Institute of Environmental Sciences, Ministry of Environmental Protection of PRC, Guangzhou 510655, China – sequence: 5 givenname: Xiao-Ju orcidid: 0000-0002-6450-7244 surname: Wen fullname: Wen, Xiao-Ju organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 – sequence: 6 givenname: Shi-Feng surname: Yang fullname: Yang, Shi-Feng organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 – sequence: 7 givenname: Guang-Ming orcidid: 0000-0001-6496-8123 surname: Zeng fullname: Zeng, Guang-Ming organization: College of Environmental Science Engineering, Key Laboratory of Environmental Biology Pollution Control, Ministry of Education, Hunan University, Changsha 410082 |
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SubjectTerms | Carbon nitride Charge efficiency Charge transfer Environment pollution Heterojunctions Hybrid composites Light irradiation Nanosheets Oxidation Photocatalysis Photocatalysts Self-assembly Separation Synergistic effect |
Title | Combination of efficient charge separation with the assistance of novel dual Z-scheme system: self-assembly photocatalyst Ag@AgI/BiOI modified oxygen-doped carbon nitride nanosheet with enhanced photocatalytic performance |
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