Synthesis and optical properties of N→Ga coordinated gallium boroxines

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 5; no. 48; pp. 18164 - 18172
• Main Authors: Milasheuskaya, Yaraslava, Schwarz, Ji í, Dostál, Libor, R i ková, Zdenka, Bouška, Marek, Olmrová Zmrhalová, Zuzana, Syrový, Tomáš, Jambor, Roman
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 14.12.2021
• Subjects: Electrical resistivity; Gallium; Molecular structure; Optical properties; Refractivity; Spin coating; Thin films

Reactions of the N,C,N-chelated organogallium amide LGa(NEt 2 ) 2 ( 1 ), where L is {2,6-(Me 2 NCH 2 ) 2 C 6 H 3 } − , with organoboronic acids RB(OH) 2 yielded molecular gallium boroxines LGa(O 3 B 2 R 2 ) ( 2 : R = OH, 3 : R = Ph, 4 : R = 4-MeO-C 6 H 4 , 5 : R = 4-CHO-C 6 H 4 , 6 : R = Fc), neutra...