Analyses of the electronic structures of FeFe-cofactors compared with those of FeMo- and FeV-cofactors and their P-clusters

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 15; pp. 6529 - 6536
• Main Authors: Xie, Zhen-Lang, Jin, Wan-Ting, Zhou, Zhao-Hui
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 16.04.2024
• Subjects: Clusters; Crystallography; Iron; Mathematical analysis; Molybdenum; Oxidation; Proteins; Valence

The electronic structures of FeFe-cofactors (FeFe-cos) in resting and turnover states, together with their P N clusters from iron-only nitrogenases, have been calculated using the bond valence method, and their crystallographic data were reported recently and deposited in the Protein Data Bank (PDB...