Recent advancements in synthesis of cyclic oligosaccharides

The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also...

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Published inChemical communications (Cambridge, England) Vol. 61; no. 23; pp. 4483 - 4494
Main Authors Endo, Hirofumi, Sun, Yu-Cong, Sasaki, Norihiko, Nokami, Toshiki
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 13.03.2025
Subjects
Chemical synthesis
Glycosylation
Oligosaccharides
Oligosaccharides - chemical synthesis
Oligosaccharides - chemistry
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Abstract The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also for the chemical synthesis of cyclic oligosaccharides. In this review, recent syntheses of nonnatural cyclic oligosaccharides are also introduced, and glycosylation methodologies are focused on. The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides.
AbstractList The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also for the chemical synthesis of cyclic oligosaccharides. In this review, recent syntheses of nonnatural cyclic oligosaccharides are also introduced, and glycosylation methodologies are focused on.
The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also for the chemical synthesis of cyclic oligosaccharides. In this review, recent syntheses of nonnatural cyclic oligosaccharides are also introduced, and glycosylation methodologies are focused on. The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides.
The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also for the chemical synthesis of cyclic oligosaccharides. In this review, recent syntheses of nonnatural cyclic oligosaccharides are also introduced, and glycosylation methodologies are focused on.The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic oligosaccharides. Electrochemical glycosylation is an enabling technology not only for automated solution-phase synthesis of linear oligosaccharides but also for the chemical synthesis of cyclic oligosaccharides. In this review, recent syntheses of nonnatural cyclic oligosaccharides are also introduced, and glycosylation methodologies are focused on.
Author Sasaki, Norihiko
Nokami, Toshiki
Endo, Hirofumi
Sun, Yu-Cong
AuthorAffiliation Tottori University
Department of Chemistry and Biotechnology
Faculty of Engineering
Centre for Research on Green Sustainable Chemistry
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Notes This article is dedicated to late Professor Sir Fraser Stoddart.
Hirofumi Endo was born in Tottori, Japan. He obtained his master's degree from Tottori University in 2022. He is continuing his PhD study and spent 4 months in the Baran group at the Scripps Research Institute in La Jolla. His research interests include synthetic organic chemistry, organic electrochemistry, and carbohydrate chemistry. Yu-Cong Sun was born in China and grew up in both China and Japan. He received his bachelor's degree from Tottori University in 2024. He started his master's studies in the same group. His research interests include synthetic organic chemistry, carbohydrate chemistry, and organic electrochemistry. Norihiko Sasaki was born in Okayama, Japan. He received his PhD from Kyushu University under the supervision of Professor Kazunori Sugiyasu in 2021. He spent one year as a postdoc in the same group at the National Institute for Materials Science (NIMS) and rejoined Tottori University as an Assistant Professor in 2022. His research interests include supramolecular chemistry, carbohydrate chemistry, organic electrochemistry, organofluorine chemistry, and ionic liquids. Toshiki Nokami was born in Wakayama, Japan. He obtained his PhD from Kyoto University under the supervision of late Professor Jun-ichi Yoshida in 2004. He spent 11 months at ETH Zurich as a postdoc under the supervision of Professor Peter H. Seeberger. He joined the Yoshida group as an Assistant Professor and moved to the Itoh group at Tottori University as an Associate Professor in 2012. He was promoted to Professor in 2019. His research interests include synthetic organic chemistry, carbohydrate chemistry, and organic electrochemistry.
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Snippet The development of synthetic methods for chemical glycosylation enables the synthesis of various oligosaccharides, including nonnatural cyclic...
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SubjectTerms Chemical synthesis
Glycosylation
Oligosaccharides
Oligosaccharides - chemical synthesis
Oligosaccharides - chemistry
Title Recent advancements in synthesis of cyclic oligosaccharides
URI https://www.ncbi.nlm.nih.gov/pubmed/40007235
https://www.proquest.com/docview/3176676890
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