Cobalt catalyzed carboxylation reaction of saturated hydrocarbons with CO in the presence of K2S2O8 and TFA under mild conditions
Cobalt(II) acetate (Co(OAc)(2)) has been found to be an efficient catalyst for the carboxylation reaction of saturated hydrocarbons with CO to yield the corresponding carboxylic acids in high yields in the presence of K2S2O8 and CF3COOH. About 89.5% conversion of propane is obtained in this reaction...
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| Published in | Tetrahedron letters Vol. 40; no. 50; pp. 8867 - 8871 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
OXFORD
Elsevier
10.12.1999
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0040-4039 1873-3581 |
| DOI | 10.1016/S0040-4039(99)01863-8 |
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| Abstract | Cobalt(II) acetate (Co(OAc)(2)) has been found to be an efficient catalyst for the carboxylation reaction of saturated hydrocarbons with CO to yield the corresponding carboxylic acids in high yields in the presence of K2S2O8 and CF3COOH. About 89.5% conversion of propane is obtained in this reaction. The activation parameters of the reaction of propane have been determined by Arrhenius and Eyring plots. (C) 1999 Elsevier Science Ltd. All rights reserved. |
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| AbstractList | Cobalt(II) acetate (Co(OAc)(2)) has been found to be an efficient catalyst for the carboxylation reaction of saturated hydrocarbons with CO to yield the corresponding carboxylic acids in high yields in the presence of K2S2O8 and CF3COOH. About 89.5% conversion of propane is obtained in this reaction. The activation parameters of the reaction of propane have been determined by Arrhenius and Eyring plots. (C) 1999 Elsevier Science Ltd. All rights reserved. |
| Author | Asadullah, Mohammad Taniguchi, Yuki Kitamura, Tsugio Fujiwara, Yuzo |
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| Cites_doi | 10.1021/ic00024a009 10.1055/s-1996-5541 10.1002/(SICI)1099-0739(199907)13:7<539::AID-AOC883>3.0.CO;2-2 10.1627/jpi1958.41.236 10.1021/ol990073r 10.1021/ic960500m 10.1021/cr00036a005 10.1021/ja00100a024 10.1002/anie.199509701 10.1021/jo00301a015 10.1016/0022-328X(94)80134-7 10.1038/368613a0 10.1016/0022-328X(94)05153-3 |
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| Keywords | OXIDATION ACTIVATION COMPLEX METHANE CARBON-MONOXIDE CHEMISTRY CYCLOHEXANE ACETIC-ACID ALKANES |
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| Title | Cobalt catalyzed carboxylation reaction of saturated hydrocarbons with CO in the presence of K2S2O8 and TFA under mild conditions |
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