Synthesis, structure, and formation mechanism of the halogen-bridged tricobalt clusters, [Co3Cp3(μ3-CPh)2(μ-X)]+ (X=Cl, Br, and I)

A series of benzylidyne-capped, halide-bridged tricobalt clusters [Co3Cp3(μ3-CPh)2(μ-X)]+ (where X = Cl, Br, and I) were synthesized by the reaction of [Co3Cp3(μ3-CPh)2] with halogens, and have been investigated using X-ray diffraction, 1H NMR and UV–Vis absorption spectroscopy. Their formation mech...

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Published inInorganica Chimica Acta Vol. 357; no. 4; pp. 1236 - 1242
Main Authors Ebihara, Masahiro, Iiba, Masami, Matsuoka, Hiroaki, Kawamura, Takashi
Format Journal Article
LanguageEnglish
Published Elsevier B.V 10.03.2004
Subjects
Cobalt complexes
Crystal structures
Halogen-bridges
Halogenation
Redox potentials
Trinuclear clusters
Crystal structures
Halogen-bridges
Trinuclear clusters
Halogenation
Redox potentials
Cobalt complexes
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Abstract A series of benzylidyne-capped, halide-bridged tricobalt clusters [Co3Cp3(μ3-CPh)2(μ-X)]+ (where X = Cl, Br, and I) were synthesized by the reaction of [Co3Cp3(μ3-CPh)2] with halogens, and have been investigated using X-ray diffraction, 1H NMR and UV–Vis absorption spectroscopy. Their formation mechanism is discussed in relation to their redox chemistry. Reactions of a benzylidyne-capped tricobalt cluster, [Co3Cp3(μ3-CPh)2] (1), with halogens (X2 = Cl2, Br2, and I2) in CH2Cl2 afforded halogen-adducts of 1. The structure of four isolated salts [Co3Cp3(μ3-CPh)2(μ-Cl)]PF6·MeCN (2PF6·MeCN), [Co3Cp3(μ3-CPh)2(μ-Br)]SbF6 (3SbF6), [Co3Cp3(μ3-CPh)2(μ-I)]SbF6·CH2Cl2 (4SbF6·CH2Cl2), and [Co3Cp3(μ3-CPh)2(μ-I)]I3 (4I3) determined by X-ray diffraction can be regarded formally as halide-adducts of 12+. The halogen atom in each structure lies in the Co3 plane. The halogen-bridged Co–Co edge was elongated (in 2PF6·MeCN = 2.6072(4), in 3SbF6 = 2.6106(7), in 4SbF6·CH2Cl2 = 2.622(2), and in 4I3=2.6718(9) Å), and the Co–Co distances that had no halogen-bridge remained unchanged from the Co–Co distance of 1 (2.382(8) Å), (in 2PF6=2.4037(8) and 2.3948(7), in 3SbF6=2.3888(6) and 2.4017(7), in 4SbF6·CH2Cl2 = 2.393(2) and 2.388(1), and in 4I3=2.397(1) and 2.3868(9) Å). The UV–Vis absorption spectra of 2+, 3+, and 4+ had characteristic absorption peaks at 796, 819, and 844 nm, respectively. Cyclic voltammograms of 2PF6 in CH2Cl2 with 0.1 M nBu4NPF6 as the supporting electrolyte showed a chemically reversible oxidation (at a potential of 0.75 V versus Fc/Fc+), and an irreversible reduction wave at −0.57 V. The irreversible reduction resulted in the recovery of 1. The redox properties of 3+ and 4+ are very similar to that of 2+. Cyclic voltammetry of 1 in 0.1 M nBu4NCl/MeCN indicates that the formation of 2+ is a multi-step reaction. Initially, 1 is oxidized to 1+, and then, 1+ is coordinated by Cl− followed by immediate oxidation to 2+.
AbstractList A series of benzylidyne-capped, halide-bridged tricobalt clusters [Co3Cp3(μ3-CPh)2(μ-X)]+ (where X = Cl, Br, and I) were synthesized by the reaction of [Co3Cp3(μ3-CPh)2] with halogens, and have been investigated using X-ray diffraction, 1H NMR and UV–Vis absorption spectroscopy. Their formation mechanism is discussed in relation to their redox chemistry. Reactions of a benzylidyne-capped tricobalt cluster, [Co3Cp3(μ3-CPh)2] (1), with halogens (X2 = Cl2, Br2, and I2) in CH2Cl2 afforded halogen-adducts of 1. The structure of four isolated salts [Co3Cp3(μ3-CPh)2(μ-Cl)]PF6·MeCN (2PF6·MeCN), [Co3Cp3(μ3-CPh)2(μ-Br)]SbF6 (3SbF6), [Co3Cp3(μ3-CPh)2(μ-I)]SbF6·CH2Cl2 (4SbF6·CH2Cl2), and [Co3Cp3(μ3-CPh)2(μ-I)]I3 (4I3) determined by X-ray diffraction can be regarded formally as halide-adducts of 12+. The halogen atom in each structure lies in the Co3 plane. The halogen-bridged Co–Co edge was elongated (in 2PF6·MeCN = 2.6072(4), in 3SbF6 = 2.6106(7), in 4SbF6·CH2Cl2 = 2.622(2), and in 4I3=2.6718(9) Å), and the Co–Co distances that had no halogen-bridge remained unchanged from the Co–Co distance of 1 (2.382(8) Å), (in 2PF6=2.4037(8) and 2.3948(7), in 3SbF6=2.3888(6) and 2.4017(7), in 4SbF6·CH2Cl2 = 2.393(2) and 2.388(1), and in 4I3=2.397(1) and 2.3868(9) Å). The UV–Vis absorption spectra of 2+, 3+, and 4+ had characteristic absorption peaks at 796, 819, and 844 nm, respectively. Cyclic voltammograms of 2PF6 in CH2Cl2 with 0.1 M nBu4NPF6 as the supporting electrolyte showed a chemically reversible oxidation (at a potential of 0.75 V versus Fc/Fc+), and an irreversible reduction wave at −0.57 V. The irreversible reduction resulted in the recovery of 1. The redox properties of 3+ and 4+ are very similar to that of 2+. Cyclic voltammetry of 1 in 0.1 M nBu4NCl/MeCN indicates that the formation of 2+ is a multi-step reaction. Initially, 1 is oxidized to 1+, and then, 1+ is coordinated by Cl− followed by immediate oxidation to 2+.
Author Ebihara, Masahiro
Matsuoka, Hiroaki
Kawamura, Takashi
Iiba, Masami
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Cites_doi 10.1016/S0022-328X(00)86849-7
10.1021/ja953220z
10.1016/j.ica.2003.08.010
10.1016/S0277-5387(00)86322-6
10.1016/j.poly.2003.09.001
10.1021/ja00019a041
10.1039/C39820000203
10.1021/ja00354a070
10.1016/j.jorganchem.2003.09.042
10.1107/S0108767383001737
10.1039/c39900000197
10.1002/anie.198005591
10.1016/0010-8545(95)01138-F
10.1021/ic00167a030
10.1021/om980557b
10.1107/S0567739468000707
10.1107/S0365110X65004802
10.1021/om00087a005
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Keywords Crystal structures
Halogen-bridges
Trinuclear clusters
Halogenation
Redox potentials
Cobalt complexes
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References Wadepohl, Gebert (BIB1) 1995; 143
North, Phillips, Mathews (BIB17) 1968; 24
Ebihara, Iiba, Higashi, Tsuzuki, Kawamura, Morioka, Ozawa, Yamabe, Masuda (BIB6) 2003; 22
Colbran, Robinson, Simpson (BIB3) 1984; 3
Sheldrick (BIB13) 1985; vol. 3
Winter, Zsolnai, Huttner (BIB8) 1982; 232
Parthasarathi, Beurskens, Slot (BIB19) 1983; 39
Ebihara, Iiba, Matsuoka, Okuda, Kawamura (BIB7) 2004; 689
Creagh, McAuley (BIB16) 1992; vol. C
Altomare, Burla, Camalli, Cascarano, Giacovazzo, Guagliardi, Polidori (BIB14) 1994; 27
Nagra, Batchelor, Bennet, Einstein, Lathioor, Pomeroy, Wang (BIB11) 1996; 118
Vollhardt, Walborsky (BIB21) 1983; 105
Pulliam, Thoden, Stacy, Spencer, Englert, Dahl (BIB23) 1991; 113
Leong, Liu (BIB9) 1999; 18
Van Horn, Vollhardt (BIB2) 1982
Ebihara, Iiba, Kato, Minami, Kawamura (BIB5) 2004; 357
teXsan: Crystal Structure Analysis Package 1.11, Molecular Structure Corporation, Woodland, TX, 2000
Vollhardt, Walborsky (BIB22) 1988; 7
De Meulenaer, Tompa, Higashi (BIB18) 1965; 19
Fritch, Vollhardt (BIB12) 1980; 19
Cromer, Waber (BIB15) 1974; vol. IV
Enoki, Kawamura, Yonezawa (BIB4) 1983; 22
Sanati, Becalska, Ma, Pomeroy (BIB10) 1990
Sanati (10.1016/j.ica.2003.10.016_BIB10) 1990
Altomare (10.1016/j.ica.2003.10.016_BIB14) 1994; 27
Van Horn (10.1016/j.ica.2003.10.016_BIB2) 1982
Wadepohl (10.1016/j.ica.2003.10.016_BIB1) 1995; 143
Ebihara (10.1016/j.ica.2003.10.016_BIB6) 2003; 22
Leong (10.1016/j.ica.2003.10.016_BIB9) 1999; 18
Winter (10.1016/j.ica.2003.10.016_BIB8) 1982; 232
Enoki (10.1016/j.ica.2003.10.016_BIB4) 1983; 22
Colbran (10.1016/j.ica.2003.10.016_BIB3) 1984; 3
Cromer (10.1016/j.ica.2003.10.016_BIB15) 1974; vol. IV
Higashi (10.1016/j.ica.2003.10.016_BIB18_2) 1999
Fritch (10.1016/j.ica.2003.10.016_BIB12) 1980; 19
De Meulenaer (10.1016/j.ica.2003.10.016_BIB18_1) 1965; 19
Vollhardt (10.1016/j.ica.2003.10.016_BIB22) 1988; 7
Parthasarathi (10.1016/j.ica.2003.10.016_BIB19) 1983; 39
Pulliam (10.1016/j.ica.2003.10.016_BIB23) 1991; 113
Nagra (10.1016/j.ica.2003.10.016_BIB11) 1996; 118
Creagh (10.1016/j.ica.2003.10.016_BIB16) 1992; vol. C
10.1016/j.ica.2003.10.016_BIB20
Ebihara (10.1016/j.ica.2003.10.016_BIB7) 2004; 689
Vollhardt (10.1016/j.ica.2003.10.016_BIB21) 1983; 105
Sheldrick (10.1016/j.ica.2003.10.016_BIB13) 1985; vol. 3
North (10.1016/j.ica.2003.10.016_BIB17) 1968; 24
Ebihara (10.1016/j.ica.2003.10.016_BIB5) 2004; 357
References_xml – volume: 118
  start-page: 1207
  year: 1996
  ident: BIB11
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Wang
– volume: vol. 3
  start-page: 175
  year: 1985
  ident: BIB13
  publication-title: Crystallographic Computing
  contributor:
    fullname: Sheldrick
– volume: 19
  start-page: 1014
  year: 1965
  ident: BIB18
  article-title: Numabs–Numerical Absorption Correction
  publication-title: Acta Crystallogr.
  contributor:
    fullname: Higashi
– volume: 3
  start-page: 1344
  year: 1984
  ident: BIB3
  publication-title: Organometallics
  contributor:
    fullname: Simpson
– start-page: 197
  year: 1990
  ident: BIB10
  publication-title: J. Chem. Soc., Chem. Commun.
  contributor:
    fullname: Pomeroy
– start-page: 203
  year: 1982
  ident: BIB2
  publication-title: J. Chem. Soc., Chem. Commun.
  contributor:
    fullname: Vollhardt
– volume: 19
  start-page: 559
  year: 1980
  ident: BIB12
  publication-title: Angew. Chem., Int. Ed. Engl.
  contributor:
    fullname: Vollhardt
– volume: vol. IV
  year: 1974
  ident: BIB15
  publication-title: International Tables for X-ray Crystallography
  contributor:
    fullname: Waber
– volume: 7
  start-page: 1023
  year: 1988
  ident: BIB22
  publication-title: Polyhedron
  contributor:
    fullname: Walborsky
– volume: 24
  start-page: 351
  year: 1968
  ident: BIB17
  publication-title: Acta Crystallogr., Sect. A
  contributor:
    fullname: Mathews
– volume: 689
  start-page: 146
  year: 2004
  ident: BIB7
  publication-title: J. Organomet. Chem.
  contributor:
    fullname: Kawamura
– volume: 27
  start-page: 435
  year: 1994
  ident: BIB14
  publication-title: J. Appl. Crystallogr.
  contributor:
    fullname: Polidori
– volume: 357
  start-page: 533
  year: 2004
  ident: BIB5
  publication-title: Inorg. Chim. Acta
  contributor:
    fullname: Kawamura
– volume: 105
  start-page: 5507
  year: 1983
  ident: BIB21
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Walborsky
– volume: 113
  start-page: 7398
  year: 1991
  ident: BIB23
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Dahl
– volume: 18
  start-page: 800
  year: 1999
  ident: BIB9
  publication-title: Organometallics
  contributor:
    fullname: Liu
– volume: 39
  start-page: 860
  year: 1983
  ident: BIB19
  publication-title: Acta Crystallogr., Sect. A
  contributor:
    fullname: Slot
– volume: 22
  start-page: 3821
  year: 1983
  ident: BIB4
  publication-title: Inorg. Chem.
  contributor:
    fullname: Yonezawa
– volume: 143
  start-page: 535
  year: 1995
  ident: BIB1
  publication-title: Coord. Chem. Rev.
  contributor:
    fullname: Gebert
– volume: vol. C
  start-page: 219
  year: 1992
  ident: BIB16
  publication-title: International Tables for X-ray Crystallography
  contributor:
    fullname: McAuley
– volume: 22
  start-page: 3413
  year: 2003
  ident: BIB6
  publication-title: Polyhedron
  contributor:
    fullname: Masuda
– volume: 232
  start-page: 47
  year: 1982
  ident: BIB8
  publication-title: J. Organomet. Chem.
  contributor:
    fullname: Huttner
– volume: 27
  start-page: 435
  year: 1994
  ident: 10.1016/j.ica.2003.10.016_BIB14
  publication-title: J. Appl. Crystallogr.
  contributor:
    fullname: Altomare
– volume: 232
  start-page: 47
  year: 1982
  ident: 10.1016/j.ica.2003.10.016_BIB8
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)86849-7
  contributor:
    fullname: Winter
– volume: 118
  start-page: 1207
  year: 1996
  ident: 10.1016/j.ica.2003.10.016_BIB11
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja953220z
  contributor:
    fullname: Nagra
– volume: 357
  start-page: 533
  year: 2004
  ident: 10.1016/j.ica.2003.10.016_BIB5
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/j.ica.2003.08.010
  contributor:
    fullname: Ebihara
– volume: 7
  start-page: 1023
  year: 1988
  ident: 10.1016/j.ica.2003.10.016_BIB22
  publication-title: Polyhedron
  doi: 10.1016/S0277-5387(00)86322-6
  contributor:
    fullname: Vollhardt
– volume: 22
  start-page: 3413
  year: 2003
  ident: 10.1016/j.ica.2003.10.016_BIB6
  publication-title: Polyhedron
  doi: 10.1016/j.poly.2003.09.001
  contributor:
    fullname: Ebihara
– volume: vol. 3
  start-page: 175
  year: 1985
  ident: 10.1016/j.ica.2003.10.016_BIB13
  contributor:
    fullname: Sheldrick
– volume: 113
  start-page: 7398
  year: 1991
  ident: 10.1016/j.ica.2003.10.016_BIB23
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00019a041
  contributor:
    fullname: Pulliam
– start-page: 203
  year: 1982
  ident: 10.1016/j.ica.2003.10.016_BIB2
  publication-title: J. Chem. Soc., Chem. Commun.
  doi: 10.1039/C39820000203
  contributor:
    fullname: Van Horn
– volume: 105
  start-page: 5507
  year: 1983
  ident: 10.1016/j.ica.2003.10.016_BIB21
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00354a070
  contributor:
    fullname: Vollhardt
– ident: 10.1016/j.ica.2003.10.016_BIB20
– volume: 689
  start-page: 146
  year: 2004
  ident: 10.1016/j.ica.2003.10.016_BIB7
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2003.09.042
  contributor:
    fullname: Ebihara
– volume: 39
  start-page: 860
  year: 1983
  ident: 10.1016/j.ica.2003.10.016_BIB19
  publication-title: Acta Crystallogr., Sect. A
  doi: 10.1107/S0108767383001737
  contributor:
    fullname: Parthasarathi
– start-page: 197
  year: 1990
  ident: 10.1016/j.ica.2003.10.016_BIB10
  publication-title: J. Chem. Soc., Chem. Commun.
  doi: 10.1039/c39900000197
  contributor:
    fullname: Sanati
– volume: 19
  start-page: 559
  year: 1980
  ident: 10.1016/j.ica.2003.10.016_BIB12
  publication-title: Angew. Chem., Int. Ed. Engl.
  doi: 10.1002/anie.198005591
  contributor:
    fullname: Fritch
– volume: 143
  start-page: 535
  year: 1995
  ident: 10.1016/j.ica.2003.10.016_BIB1
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/0010-8545(95)01138-F
  contributor:
    fullname: Wadepohl
– volume: vol. IV
  year: 1974
  ident: 10.1016/j.ica.2003.10.016_BIB15
  contributor:
    fullname: Cromer
– volume: 22
  start-page: 3821
  year: 1983
  ident: 10.1016/j.ica.2003.10.016_BIB4
  publication-title: Inorg. Chem.
  doi: 10.1021/ic00167a030
  contributor:
    fullname: Enoki
– volume: 18
  start-page: 800
  year: 1999
  ident: 10.1016/j.ica.2003.10.016_BIB9
  publication-title: Organometallics
  doi: 10.1021/om980557b
  contributor:
    fullname: Leong
– volume: 24
  start-page: 351
  year: 1968
  ident: 10.1016/j.ica.2003.10.016_BIB17
  publication-title: Acta Crystallogr., Sect. A
  doi: 10.1107/S0567739468000707
  contributor:
    fullname: North
– volume: vol. C
  start-page: 219
  year: 1992
  ident: 10.1016/j.ica.2003.10.016_BIB16
  contributor:
    fullname: Creagh
– year: 1999
  ident: 10.1016/j.ica.2003.10.016_BIB18_2
  contributor:
    fullname: Higashi
– volume: 19
  start-page: 1014
  year: 1965
  ident: 10.1016/j.ica.2003.10.016_BIB18_1
  publication-title: Acta Crystallogr.
  doi: 10.1107/S0365110X65004802
  contributor:
    fullname: De Meulenaer
– volume: 3
  start-page: 1344
  year: 1984
  ident: 10.1016/j.ica.2003.10.016_BIB3
  publication-title: Organometallics
  doi: 10.1021/om00087a005
  contributor:
    fullname: Colbran
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Snippet A series of benzylidyne-capped, halide-bridged tricobalt clusters [Co3Cp3(μ3-CPh)2(μ-X)]+ (where X = Cl, Br, and I) were synthesized by the reaction of...
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SubjectTerms Cobalt complexes
Crystal structures
Halogen-bridges
Halogenation
Redox potentials
Trinuclear clusters
Title Synthesis, structure, and formation mechanism of the halogen-bridged tricobalt clusters, [Co3Cp3(μ3-CPh)2(μ-X)]+ (X=Cl, Br, and I)
URI https://dx.doi.org/10.1016/j.ica.2003.10.016
Volume 357
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