New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: synthesis, structure and magnetic properties

• Published in: New journal of chemistry Vol. 42; no. 2; pp. 1347 - 1355
• Main Authors: Di Santo, A., Osiry, H., Reguera, E., Alborés, P., Carbonio, R. E., Ben Altabef, A., Gil, Diego M.
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 2018
• Subjects: Antiferromagnetism; Chemical synthesis; Coordination polymers; Crystal structure; Crystallization; Diffraction; Ferromagnetism; Interlayers; Iron; Magnetic measurement; Magnetic properties; Manganese; Nickel; Organic solids; Polymers

Four coordination polymers obtained by the intercalation of 2-methylimidazole into transition metal nitroprussides T[Fe(CN) 5 NO] with T = Mn, Fe, Co and Ni were synthesized and characterized. The resulting hybrid inorganic–organic solids crystallize as dihydrates. All the solids were crystallized i...