In-Situ Studies of Structure Transformation and Al Coordination of KAl(MoO4)2 during Heating by High Temperature Raman and 27Al NMR Spectroscopies

• Published in: Materials Vol. 10; no. 3; p. 310
• Main Authors: Wang, Min, You, Jinglin, Sobol, Alexander, Lu, Liming, Wang, Jian, Xie, Yingfang
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 17.03.2017; MDPI
• Subjects: 27Al MAS NMR; Al coordination environment; Alkali metals; Aluminum; Coordination; double molybdate KAl(MoO4)2; First principles; first principles calculation; High temperature; in-situ Raman spectroscopy; Iron; NMR; NMR spectroscopy; Nuclear magnetic resonance; Raman spectra; Resonance scattering; Room temperature; Solid state lasers; structure transformation

Recent interest in optimizing composition and synthesis conditions of functional crystals, and the further exploration of new possible candidates for tunable solid-state lasers, has led to significant research on compounds in this family MIMIII(MVIO4)2 (MI = alkali metal, MIII = Al, In, Sc, Fe, Bi,...