Biochar-based materials and their applications in removal of organic contaminants from wastewater: state-of-the-art review

As a class of famous carbon materials, biochars (BCs) and their derivative materials with excellent physicochemical properties and diversified functionalities present great potential in wastewater treatment fields. This review focuses on the latest development in reported biochar-based materials as...

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Published inBiochar (Online) Vol. 1; no. 1; pp. 45 - 73
Main Authors Huang, Qiang, Song, Shuang, Chen, Zhe, Hu, Baowei, Chen, Jianrong, Wang, Xiangke
Format Journal Article
LanguageEnglish
Published Singapore Springer Singapore 01.03.2019
Subjects
Agriculture
Ceramics
Composites
Earth and Environmental Science
Environment
Environmental Engineering/Biotechnology
Fossil Fuels (incl. Carbon Capture)
Glass
Natural Materials
Renewable and Green Energy
Review
Soil Science & Conservation
Biochar-based materials
Organic contaminants
Adsorption
Water purification
Catalytic degradation
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Abstract As a class of famous carbon materials, biochars (BCs) and their derivative materials with excellent physicochemical properties and diversified functionalities present great potential in wastewater treatment fields. This review focuses on the latest development in reported biochar-based materials as superior adsorbents or catalysts for removing harmful organic contaminants from wastewater. The construction and properties of biochar-based materials are briefly introduced at the beginning. As one of the major factors affecting the properties of BCs, the wide diversity of feedstocks, such as agricultural and forest residues, industrial by-products as well as municipal wastes, endows BCs different chemical compositions and structures. Woody and herbaceous BCs usually have higher carbon contents, larger surface areas and strong aromaticity, which is in favor of the organic contaminant removal. Driven by the desire of more cost-effective materials, several types of biochar-based hybrid materials, such as magnetic BC composites (MBC), nanometal/nanometallic oxides/hydroxide BC composites and layered nanomaterial-coated BCs, as well as physically/chemically activated BCs, have also been developed. With the help of foreign materials, these types of hybrid BCs have excellent capacities to remove a wide range of organic contaminants, including organic dyestuff, phenols and chemical intermediates, as well as pharmaceutically active compounds, from aquatic solutions. Depending on the different types of biochar-based materials, organic contaminants can be removed by different mechanisms, such as physical adsorption, electrostatic interaction, π–π interaction and Fenton process, as well as photocatalytic degradation. In summary, the low cost, tunable surface chemistry and excellent physical–chemical properties of BCs allow it to be a potential material in organic contaminant removal. The combination of BCs with foreign materials endows BCs more functionalities and broader development opportunities. Considering the urgent demand of practical wastewater treatment, we hope more researches will focus on the applications and commercialization of biochar-based materials.
AbstractList As a class of famous carbon materials, biochars (BCs) and their derivative materials with excellent physicochemical properties and diversified functionalities present great potential in wastewater treatment fields. This review focuses on the latest development in reported biochar-based materials as superior adsorbents or catalysts for removing harmful organic contaminants from wastewater. The construction and properties of biochar-based materials are briefly introduced at the beginning. As one of the major factors affecting the properties of BCs, the wide diversity of feedstocks, such as agricultural and forest residues, industrial by-products as well as municipal wastes, endows BCs different chemical compositions and structures. Woody and herbaceous BCs usually have higher carbon contents, larger surface areas and strong aromaticity, which is in favor of the organic contaminant removal. Driven by the desire of more cost-effective materials, several types of biochar-based hybrid materials, such as magnetic BC composites (MBC), nanometal/nanometallic oxides/hydroxide BC composites and layered nanomaterial-coated BCs, as well as physically/chemically activated BCs, have also been developed. With the help of foreign materials, these types of hybrid BCs have excellent capacities to remove a wide range of organic contaminants, including organic dyestuff, phenols and chemical intermediates, as well as pharmaceutically active compounds, from aquatic solutions. Depending on the different types of biochar-based materials, organic contaminants can be removed by different mechanisms, such as physical adsorption, electrostatic interaction, π–π interaction and Fenton process, as well as photocatalytic degradation. In summary, the low cost, tunable surface chemistry and excellent physical–chemical properties of BCs allow it to be a potential material in organic contaminant removal. The combination of BCs with foreign materials endows BCs more functionalities and broader development opportunities. Considering the urgent demand of practical wastewater treatment, we hope more researches will focus on the applications and commercialization of biochar-based materials.
Author Wang, Xiangke
Hu, Baowei
Chen, Jianrong
Chen, Zhe
Huang, Qiang
Song, Shuang
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  surname: Huang
  fullname: Huang, Qiang
  organization: MOE Key Lab of Resources and Environmental System Optimization, College of Environmental Science and Engineering, North China Electric Power University, School of Life Science, Shaoxing University
– sequence: 2
  givenname: Shuang
  surname: Song
  fullname: Song, Shuang
  organization: MOE Key Lab of Resources and Environmental System Optimization, College of Environmental Science and Engineering, North China Electric Power University
– sequence: 3
  givenname: Zhe
  surname: Chen
  fullname: Chen, Zhe
  organization: MOE Key Lab of Resources and Environmental System Optimization, College of Environmental Science and Engineering, North China Electric Power University
– sequence: 4
  givenname: Baowei
  surname: Hu
  fullname: Hu, Baowei
  organization: School of Life Science, Shaoxing University
– sequence: 5
  givenname: Jianrong
  surname: Chen
  fullname: Chen, Jianrong
  organization: College of Geography and Environmental Science, Zhejiang Normal University
– sequence: 6
  givenname: Xiangke
  surname: Wang
  fullname: Wang, Xiangke
  email: xkwang@ncepu.edu.cn
  organization: MOE Key Lab of Resources and Environmental System Optimization, College of Environmental Science and Engineering, North China Electric Power University
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Snippet As a class of famous carbon materials, biochars (BCs) and their derivative materials with excellent physicochemical properties and diversified functionalities...
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Publisher
StartPage 45
SubjectTerms Agriculture
Ceramics
Composites
Earth and Environmental Science
Environment
Environmental Engineering/Biotechnology
Fossil Fuels (incl. Carbon Capture)
Glass
Natural Materials
Renewable and Green Energy
Review
Soil Science & Conservation
Title Biochar-based materials and their applications in removal of organic contaminants from wastewater: state-of-the-art review
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