Single-phase forming ability of high-entropy ceramics from a size disorder perspective: A case study of (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7

A newly five-component equimolar high-entropy ceramic – (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7 with a mixture phase of pyrochlore and fluorite structure was successfully synthesized. On this basis, a series of systematically designed and synthesized high or medium-entropy ceramics, accompanied by a large...

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Published inCeramics international Vol. 48; no. 5; pp. 6956 - 6965
Main Authors Yang, Hongbo, Lin, Guangqiang, Bu, Huanpeng, Liu, Huijun, Yang, Lingxu, Wang, Wenjun, Lin, Xiaohuan, Fu, Chao, Wang, Yuansheng, Zeng, Chaoliu
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.03.2022
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Abstract A newly five-component equimolar high-entropy ceramic – (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7 with a mixture phase of pyrochlore and fluorite structure was successfully synthesized. On this basis, a series of systematically designed and synthesized high or medium-entropy ceramics, accompanied by a large number of previous reports on multi-component rare earth zirconates, were summarized to jointly investigate the single-phase forming ability of high-entropy rare earth zirconates ceramics (HE-RE2Zr2O7 for short) in terms of entropy value and cationic radius difference (δ). Subsequently, the forming process and mechanism of dual-phase solid solution were analyzed. The conclusions indicated that the single-phase forming ability was more determined by the cationic radius difference rather than the entropy value,and the critical value of δ distinguishing single-phase between dual-phase zone was around 5.2%. In addition, the formation of dual-phase solid solution was essentially driven by the size disorder resulting from rattler effect of cations with significant difference in radius. This work is the first report on the single-phase forming ability of HE-RE2Zr2O7 and would pave new ways for predicting the formation of high-entropy phases.
AbstractList A newly five-component equimolar high-entropy ceramic – (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7 with a mixture phase of pyrochlore and fluorite structure was successfully synthesized. On this basis, a series of systematically designed and synthesized high or medium-entropy ceramics, accompanied by a large number of previous reports on multi-component rare earth zirconates, were summarized to jointly investigate the single-phase forming ability of high-entropy rare earth zirconates ceramics (HE-RE2Zr2O7 for short) in terms of entropy value and cationic radius difference (δ). Subsequently, the forming process and mechanism of dual-phase solid solution were analyzed. The conclusions indicated that the single-phase forming ability was more determined by the cationic radius difference rather than the entropy value,and the critical value of δ distinguishing single-phase between dual-phase zone was around 5.2%. In addition, the formation of dual-phase solid solution was essentially driven by the size disorder resulting from rattler effect of cations with significant difference in radius. This work is the first report on the single-phase forming ability of HE-RE2Zr2O7 and would pave new ways for predicting the formation of high-entropy phases.
Author Yang, Lingxu
Wang, Yuansheng
Lin, Guangqiang
Lin, Xiaohuan
Fu, Chao
Liu, Huijun
Zeng, Chaoliu
Bu, Huanpeng
Yang, Hongbo
Wang, Wenjun
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High-entropy ceramics
Single-phase forming ability
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Snippet A newly five-component equimolar high-entropy ceramic – (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7 with a mixture phase of pyrochlore and fluorite structure was...
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SubjectTerms High-entropy ceramics
Rare earth zirconates
Single-phase forming ability
Size disorder
Title Single-phase forming ability of high-entropy ceramics from a size disorder perspective: A case study of (La0.2Eu0.2Gd0.2Y0.2Yb0.2)2Zr2O7
URI https://dx.doi.org/10.1016/j.ceramint.2021.11.252
Volume 48
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