Unraveling complexation and enantioseparation of a new chiral‐at‐uranium complex to chiral pesticides R/S‐malaoxons

• Published in: Applied organometallic chemistry Vol. 38; no. 5
• Main Authors: Guo, Meng‐zhen, Ouyang, Wen‐jun, Wang, Yun, Kong, Xiang‐he, Xiao, Xi‐lin, Nie, Chang‐ming, Peng, Guo‐wen
• Format: Journal Article
• Language: English
• Published: Chichester Wiley Subscription Services, Inc 01.05.2024
• Subjects: Bonding strength; Butanol; Carbonyls; chiral pesticides; chiral‐at‐uranium complex; Cyclohexane; Density functional theory; density functional theory (DFT); Dichloromethane; Enantiomers; enantioseparation; Octanol; Pesticides; Propionic acid; Pyrazole; R/S‐malaoxons; Receptors; Separation; Thermodynamic properties; Toluene; Toxicity; Uranium

Unraveling uranium complexes has become a popular study topic in recent years to address the problem of spent fuel treatment. An important and promising investigation is the enantiomer separation of chiral organophosphorus pesticides (OPs) via uranyl‐containing receptors. Among them, malaoxon (MLX),...