Pseudocapacitive NiO Fine Nanoparticles for Supercapacitor Reactions

We report nickel oxide (NiO) fine nanoparticles with an average diameter of 5.3 ± 1.3 nm as an electrode material for supercapacitor reactions. The superior pseudocapacitive behavior of NiO nanoparticles was demonstrated in three-electrode half-cells and two-electrode button cells, with a maximum sp...

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Published inJournal of the Electrochemical Society Vol. 159; no. 10; pp. A1598 - A1603
Main Authors Yeager, Matthew P., Su, Dong, Marinković, Nebojsa S., Teng, Xiaowei
Format Journal Article
LanguageEnglish
Published United States The Electrochemical Society 01.01.2012
Subjects
29
electrochemical
functional nanomaterials
in situ XANES
NiO
Supercapacitor
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Abstract We report nickel oxide (NiO) fine nanoparticles with an average diameter of 5.3 ± 1.3 nm as an electrode material for supercapacitor reactions. The superior pseudocapacitive behavior of NiO nanoparticles was demonstrated in three-electrode half-cells and two-electrode button cells, with a maximum specific capacitance of 243 F/g. In situ X-ray absorption near edge structure spectroscopy was used for the first reported time to study the evolution of the electronic structures of NiO during the charge-transfer reactions. We observed that a predominant change of valence state occurred between 0.35 V and 0.50 V (vs. Hg/HgO). The development of NiO nanomaterials in the present study provides a new approach in fabricating advanced pseudocapacitors by utilizing highly cost-effective transition metal oxide electrode materials.
AbstractList We report nickel oxide (NiO) fine nanoparticles with an average diameter of 5.3 ± 1.3 nm as an electrode material for supercapacitor reactions. The superior pseudocapacitive behavior of NiO nanoparticles was demonstrated in three-electrode half-cells and two-electrode button cells, with a maximum specific capacitance of 243 F/g. In situ X-ray absorption near edge structure spectroscopy was used for the first reported time to study the evolution of the electronic structures of NiO during the charge-transfer reactions. We observed that a predominant change of valence state occurred between 0.35 V and 0.50 V (vs. Hg/HgO). The development of NiO nanomaterials in the present study provides a new approach in fabricating advanced pseudocapacitors by utilizing highly cost-effective transition metal oxide electrode materials.
Author Su, Dong
Yeager, Matthew P.
Teng, Xiaowei
Marinković, Nebojsa S.
Author_xml – sequence: 1
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  surname: Yeager
  fullname: Yeager, Matthew P.
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  surname: Su
  fullname: Su, Dong
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  givenname: Nebojsa S.
  surname: Marinković
  fullname: Marinković, Nebojsa S.
  organization: University of Delaware Center for Catalytic Science and Technology, Newark, Delaware 19716, USA
– sequence: 4
  givenname: Xiaowei
  surname: Teng
  fullname: Teng, Xiaowei
  organization: University of New Hampshire Department of Chemical Engineering, Durham, New Hampshire 03824, USA
BackLink https://www.osti.gov/biblio/1068815$$D View this record in Osti.gov
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Snippet We report nickel oxide (NiO) fine nanoparticles with an average diameter of 5.3 ± 1.3 nm as an electrode material for supercapacitor reactions. The superior...
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SubjectTerms 29
electrochemical
functional nanomaterials
in situ XANES
NiO
Supercapacitor
Title Pseudocapacitive NiO Fine Nanoparticles for Supercapacitor Reactions
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