Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results

[Display omitted] •Water-soluble ligands and metal complexes are considered valuable tools for sustainable processes in water.•PTA and derivatives have shown interesting properties as ligands in various catalytic applicatons.•In this review article, the latest results published in 2018–2024 on this...

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Published inInorganica Chimica Acta Vol. 572; p. 122295
Main Authors Guerriero, Antonella, Gonsalvi, Luca
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2024
Online AccessGet full text
ISSN0020-1693
DOI10.1016/j.ica.2024.122295

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Abstract [Display omitted] •Water-soluble ligands and metal complexes are considered valuable tools for sustainable processes in water.•PTA and derivatives have shown interesting properties as ligands in various catalytic applicatons.•In this review article, the latest results published in 2018–2024 on this subject are discussed. In this review article, we present a brief survey of the recent contributions (2018–2024) appeared in the scientific literature, describing the use of the cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (also known as 1,3,5-triaza-7-phosphadamantane, PTA), some of its derivatives and a higher homologue as stabilizing ligands for precious and non-precious metal complexes, with various applications in homogeneous catalytic processes in water and biphasic media.
AbstractList [Display omitted] •Water-soluble ligands and metal complexes are considered valuable tools for sustainable processes in water.•PTA and derivatives have shown interesting properties as ligands in various catalytic applicatons.•In this review article, the latest results published in 2018–2024 on this subject are discussed. In this review article, we present a brief survey of the recent contributions (2018–2024) appeared in the scientific literature, describing the use of the cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (also known as 1,3,5-triaza-7-phosphadamantane, PTA), some of its derivatives and a higher homologue as stabilizing ligands for precious and non-precious metal complexes, with various applications in homogeneous catalytic processes in water and biphasic media.
ArticleNumber 122295
Author Gonsalvi, Luca
Guerriero, Antonella
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Snippet [Display omitted] •Water-soluble ligands and metal complexes are considered valuable tools for sustainable processes in water.•PTA and derivatives have shown...
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Title Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results
URI https://dx.doi.org/10.1016/j.ica.2024.122295
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