Accessing Equilibrious Modulation of Activity, Molecular Weight, and Tacticity for Syndiotactic Propylene Polymerization at Industrial Relevant Temperatures via Rational Design of Single‐Site Catalysts

• Published in: Macromolecular rapid communications. p. e00517
• Main Authors: Li, Yong‐Qing, Peng, Yu‐Qing, Cao, Gui‐Ping, Cao, Yu‐Cai
• Format: Journal Article
• Language: English
• Published: Germany 10.07.2025
• Subjects: gradient modulation; remote modulation; substituent effect; metallocene; syndiotactic polypropylene

Single‐site catalysts (SSC) have been widely applied for olefin coordination polymerization to generate high performance polyolefins. However, regular optimization of the structures of SSC would only enhance certain polymerization behaviors, such as polymerization activity, molecular weight, and syn...