Strong and highly conductive cellulose nanofibril/silver nanowires nanopaper for high performance electromagnetic interference shielding
Recently, the rapid popularization of modern communication technologies represented by 5G will inevitably aggravate the deterioration of the electromagnetic environment. Electromagnetic interference (EMI) and electromagnetic radiation have more and more serious impacts on human production and life,...
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Published in | Advanced composites and hybrid materials Vol. 5; no. 2; pp. 1078 - 1089 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Cham
Springer International Publishing
01.06.2022
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Online Access | Get full text |
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Abstract | Recently, the rapid popularization of modern communication technologies represented by 5G will inevitably aggravate the deterioration of the electromagnetic environment. Electromagnetic interference (EMI) and electromagnetic radiation have more and more serious impacts on human production and life, and EMI shielding materials have emerged as the times require. Herein, we reported a cellulose nanofibril/silver nanowire (CNF/AgNW) nanopaper, manufactured through a step-by-step (SbS) self-assembly process, which has a unique layered structure and improved two-sidedness. The results showed that the obtained AgNWs have an ultra-high aspect ratio (up to 2857), which enabled them to form conductive paths in nanopaper at low addition levels (0.5 wt.%). When the AgNW content was 5.0 wt.%, the obtained nanopaper with a thickness of ~ 50 μm exhibited an excellent tensile strength of ~ 98.6 MPa and a high conductivity of ~ 1673 S/cm. The unique layered structure of CNF/AgNW nanopaper and the excellent synergistic interaction between CNF and AgNWs enabled the optimized CNF/AgNW nanopaper to exhibit a high EMI shielding effectiveness (SE) of up to 67.27 dB in the X band. Therefore, this strong and highly conductive CNF/AgNW nanopaper is expected to broaden new application areas including smart clothing, wearable electronic devices, and other emerging applications.
Graphical abstract
A strong and highly conductivity cellulose nanofibrils/silver nanowires (CNF/AgNWs) nanopaper has been manufactured through the step-by-step self-assembly process. Abundant conductive network and special interlayer structure make the CNF/AgNWs nanopaper holds high EMI shielding performance at a low thickness. |
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AbstractList | Recently, the rapid popularization of modern communication technologies represented by 5G will inevitably aggravate the deterioration of the electromagnetic environment. Electromagnetic interference (EMI) and electromagnetic radiation have more and more serious impacts on human production and life, and EMI shielding materials have emerged as the times require. Herein, we reported a cellulose nanofibril/silver nanowire (CNF/AgNW) nanopaper, manufactured through a step-by-step (SbS) self-assembly process, which has a unique layered structure and improved two-sidedness. The results showed that the obtained AgNWs have an ultra-high aspect ratio (up to 2857), which enabled them to form conductive paths in nanopaper at low addition levels (0.5 wt.%). When the AgNW content was 5.0 wt.%, the obtained nanopaper with a thickness of ~ 50 μm exhibited an excellent tensile strength of ~ 98.6 MPa and a high conductivity of ~ 1673 S/cm. The unique layered structure of CNF/AgNW nanopaper and the excellent synergistic interaction between CNF and AgNWs enabled the optimized CNF/AgNW nanopaper to exhibit a high EMI shielding effectiveness (SE) of up to 67.27 dB in the X band. Therefore, this strong and highly conductive CNF/AgNW nanopaper is expected to broaden new application areas including smart clothing, wearable electronic devices, and other emerging applications.
Graphical abstract
A strong and highly conductivity cellulose nanofibrils/silver nanowires (CNF/AgNWs) nanopaper has been manufactured through the step-by-step self-assembly process. Abundant conductive network and special interlayer structure make the CNF/AgNWs nanopaper holds high EMI shielding performance at a low thickness. |
Author | Si, Chuanling Liu, Kun Duan, Yaxin Du, Haishun Liu, Wei Ni, Shuzhen Li, Wei Zhou, Keyu Zhang, Shu Xu, Ting |
Author_xml | – sequence: 1 givenname: Kun surname: Liu fullname: Liu, Kun organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 2 givenname: Wei surname: Liu fullname: Liu, Wei organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 3 givenname: Wei surname: Li fullname: Li, Wei organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 4 givenname: Yaxin surname: Duan fullname: Duan, Yaxin organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 5 givenname: Keyu surname: Zhou fullname: Zhou, Keyu organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 6 givenname: Shu surname: Zhang fullname: Zhang, Shu organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology – sequence: 7 givenname: Shuzhen surname: Ni fullname: Ni, Shuzhen organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences) – sequence: 8 givenname: Ting surname: Xu fullname: Xu, Ting email: xuting@tust.edu.cn organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences) – sequence: 9 givenname: Haishun surname: Du fullname: Du, Haishun email: hzd0024@auburn.edu organization: Department of Chemical Engineering, Auburn University – sequence: 10 givenname: Chuanling surname: Si fullname: Si, Chuanling email: sichli@tust.edu.cn organization: Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology |
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Keywords | Cellulose nanopaper Silver nanowires Conductive films Cellulose nanofibril EMI shielding |
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