Structural characterization of Cu2SnS3 and Cu2(Sn,Ge)S3 compounds
Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were successfully prepared by a powder technology using a combination of mechanical alloying (MA) and spark plasma sintering (SPS). Structural, compositional and optical properties were studied. A true alloy with composition similar to the startin...
Saved in:
Published in | Journal of alloys and compounds Vol. 682; pp. 489 - 494 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.10.2016
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were successfully prepared by a powder technology using a combination of mechanical alloying (MA) and spark plasma sintering (SPS). Structural, compositional and optical properties were studied. A true alloy with composition similar to the starting constituents was formed after 2 h of MA at 400 rpm. Subsequently, SPS was performed at 600 °C for 5 min under a pressure of 50 MPa. The Cu/(Sn + Ge) composition ratios of the MA and SPS materials, determined by wavelength dispersive X-ray spectroscopy, are in the range of 1.84–1.94. Rietveld refinements of the powder X-ray diffraction data show a good agreement with the monoclinic crystal structure already for the MA materials. No structural changes were observed after SPS. Raman measurements coincide with XRD results in the identification of the characteristic peaks from phonon vibrational modes of monoclinic CTS phase. Band gaps between 1.24 eV and 1.34 eV were determined by diffuse reflectance for the mechanically alloyed and sintered samples.
•Monoclinic Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were synthesized directly by a short mechanical alloying step.•Upon SPS at 600 °C under a pressure of 50 MPa no phase transformation or decomposition occurs.•Band gaps were estimated to be in the range of 1.24 eV–1.34 eV, increasing when Sn is replaced by Ge. |
---|---|
AbstractList | Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were successfully prepared by a powder technology using a combination of mechanical alloying (MA) and spark plasma sintering (SPS). Structural, compositional and optical properties were studied. A true alloy with composition similar to the starting constituents was formed after 2 h of MA at 400 rpm. Subsequently, SPS was performed at 600 °C for 5 min under a pressure of 50 MPa. The Cu/(Sn + Ge) composition ratios of the MA and SPS materials, determined by wavelength dispersive X-ray spectroscopy, are in the range of 1.84–1.94. Rietveld refinements of the powder X-ray diffraction data show a good agreement with the monoclinic crystal structure already for the MA materials. No structural changes were observed after SPS. Raman measurements coincide with XRD results in the identification of the characteristic peaks from phonon vibrational modes of monoclinic CTS phase. Band gaps between 1.24 eV and 1.34 eV were determined by diffuse reflectance for the mechanically alloyed and sintered samples.
•Monoclinic Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were synthesized directly by a short mechanical alloying step.•Upon SPS at 600 °C under a pressure of 50 MPa no phase transformation or decomposition occurs.•Band gaps were estimated to be in the range of 1.24 eV–1.34 eV, increasing when Sn is replaced by Ge. |
Author | Gunder, R. Schorr, S. Correia, J.B. Hanada, K. Neves, F. Santos, L.F. |
Author_xml | – sequence: 1 givenname: F. surname: Neves fullname: Neves, F. email: filipe.neves@lneg.pt organization: LNEG, Laboratório Nacional de Energia e Geologia, Estrada do Paço do Lumiar, 22, 1649-038, Lisboa, Portugal – sequence: 2 givenname: J.B. surname: Correia fullname: Correia, J.B. organization: LNEG, Laboratório Nacional de Energia e Geologia, Estrada do Paço do Lumiar, 22, 1649-038, Lisboa, Portugal – sequence: 3 givenname: K. surname: Hanada fullname: Hanada, K. organization: AIST, National Institute of Advanced Industrial Science and Technology, 1-2-1 Namiki, Tsukuba, Ibaraki, 305-8564, Japan – sequence: 4 givenname: L.F. surname: Santos fullname: Santos, L.F. organization: Departamento de Engenharia Química/CQE, Instituto Superior Técnico/Univ. Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal – sequence: 5 givenname: R. surname: Gunder fullname: Gunder, R. organization: Helmholtz-Zentrum Berlin für Materialien und Energie, Department Crystallography, Hahn-Meitner Platz 1, 14109, Berlin, Germany – sequence: 6 givenname: S. surname: Schorr fullname: Schorr, S. organization: Helmholtz-Zentrum Berlin für Materialien und Energie, Department Crystallography, Hahn-Meitner Platz 1, 14109, Berlin, Germany |
BookMark | eNqFkE1LwzAYx4NMcJt-BKFHBVvz0nTJScbQKQw8VM8heZJiSpeOpBX009ux3T09L_B_4bdAs9AHh9AtwQXBpHpsi1Z3HfT7gk5ngXmBMb9AcyJWLC-rSs7QHEvKc8GEuEKLlFqMMZGMzNG6HuIIwxh1l8GXjhoGF_2vHnwfsr7JNiOtQ80yHexxv6vDw9bdT48p7tCPwaZrdNnoLrmb81yiz5fnj81rvnvfvm3WuxyoxENOKiMYL5m1htpGNGBYA4RRIqVhRpbUGlZZyhyhEqyogAu3AmqpxSXnwrAl4idfiH1K0TXqEP1exx9FsDpyUK06c1BHDgpzNXGYdE8nnZvKfXsXVQLvAjjro4NB2d7_4_AHmZFqIg |
CitedBy_id | crossref_primary_10_1016_j_jallcom_2017_05_291 crossref_primary_10_1016_j_optlastec_2019_105748 crossref_primary_10_1016_j_physb_2016_08_004 crossref_primary_10_1016_j_ijleo_2022_169364 crossref_primary_10_1166_jno_2022_3299 crossref_primary_10_1016_j_solmat_2017_08_008 crossref_primary_10_7567_JJAP_57_08RC12 crossref_primary_10_1016_j_jallcom_2017_09_029 crossref_primary_10_3390_ma15113842 crossref_primary_10_1007_s11468_023_02189_x crossref_primary_10_1016_j_materresbull_2017_11_004 crossref_primary_10_1016_j_actamat_2018_03_043 |
Cites_doi | 10.1088/0022-3727/44/47/475302 10.7567/APEX.6.045501 10.1016/j.solener.2013.04.017 10.1107/S0021889869006558 10.1016/j.solmat.2014.11.024 10.1155/2013/726080 10.1063/1.4851896 10.1016/S0079-6425(99)00010-9 10.1016/j.jallcom.2015.09.232 10.1149/1.3384660 10.1063/1.4712623 10.1021/ar9001069 10.1016/j.matlet.2015.10.153 10.1016/j.jcis.2012.03.015 10.1088/0022-3727/43/21/215403 10.7567/JJAP.51.10NC34 10.1016/j.solmat.2015.04.030 10.1088/0953-8984/20/02/025205 10.1007/s00339-014-8484-2 10.1002/pip.2637 10.1080/0141159031000076110 10.1016/S0025-5408(00)00347-0 |
ContentType | Journal Article |
Copyright | 2016 Elsevier B.V. |
Copyright_xml | – notice: 2016 Elsevier B.V. |
DBID | AAYXX CITATION |
DOI | 10.1016/j.jallcom.2016.05.005 |
DatabaseName | CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry Physics |
EISSN | 1873-4669 |
EndPage | 494 |
ExternalDocumentID | 10_1016_j_jallcom_2016_05_005 S0925838816312993 |
GroupedDBID | --K --M -~X .~1 0R~ 1B1 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAXUO ABFNM ABJNI ABMAC ABXRA ABYKQ ACDAQ ACGFS ACIWK ACNCT ACRLP ADBBV ADEZE AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AGHFR AGUBO AGYEJ AHHHB AIEXJ AIKHN AITUG AJBFU AJOXV ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FIRID FNPLU FYGXN G-Q GBLVA IHE J1W KOM M24 M41 MAGPM MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SDF SDG SES SPC SPCBC SPD SSM SSZ T5K TWZ XPP ZMT ~G- 29J AAQXK AAXKI AAYXX ABXDB ACNNM ADMUD AFJKZ AKRWK ASPBG AVWKF AZFZN CITATION FEDTE FGOYB G-2 HVGLF HZ~ R2- SEW SMS T9H WUQ |
ID | FETCH-LOGICAL-c290t-16b83543ddb2df8fcb3fc132199b3b942db36d23e129cd86c58e7c2d2d04558b3 |
IEDL.DBID | AIKHN |
ISSN | 0925-8388 |
IngestDate | Thu Sep 26 19:06:13 EDT 2024 Fri Feb 23 02:15:21 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Keywords | Cu2SnS3 (CTS) Cu2(Sn,Ge)S3 (CTGS) Powder technology Semiconductors Electron microprobe analysis Rietveld analysis |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c290t-16b83543ddb2df8fcb3fc132199b3b942db36d23e129cd86c58e7c2d2d04558b3 |
PageCount | 6 |
ParticipantIDs | crossref_primary_10_1016_j_jallcom_2016_05_005 elsevier_sciencedirect_doi_10_1016_j_jallcom_2016_05_005 |
PublicationCentury | 2000 |
PublicationDate | 2016-10-15 |
PublicationDateYYYYMMDD | 2016-10-15 |
PublicationDate_xml | – month: 10 year: 2016 text: 2016-10-15 day: 15 |
PublicationDecade | 2010 |
PublicationTitle | Journal of alloys and compounds |
PublicationYear | 2016 |
Publisher | Elsevier B.V |
Publisher_xml | – name: Elsevier B.V |
References | Smith, Nie (bib25) 2010; 43 Tiwari, Chaudhuri, Shripathi, Deshpande, Sathe (bib21) 2014; 117 Beleanu, Mondeshki, Juan, Casper, Felser, Porcher (bib24) 2011; 44 Avellaneda, Nair, Nair (bib12) 2010; 157 Kroumov, Aroyo, Perez-Mato, Kirov, Capillas, Ivantchev (bib23) 2003; 76 Htay, Mandokoro, Seki, Sakaizawa, Momose, Taishi (bib20) 2015; 140 Onoda, Chen, Sato, Wada (bib18) 2000; 35 Neves, Correia, Hanada (bib5) 2016; 164 Rietveld (bib15) 1969; 2 Koike, Chino, Aihara, Araki, Nakamura, Jimbo, Katagiri (bib10) 2012; 51 Zhao, Cheng (bib9) 2013; 2013 Unifantowicz, Vaucher, Lewandowska, Kurzydłowski (bib19) 2008; 20 Lokhande, Gurav, Jo, Lokhande, Kim (bib6) 2016; 656 Zawadzki, Baranowski, Peng, Toberer, Ginley (bib4) 2013; 103 Rodriguez-Carvajal (bib16) 2001 Abermann (bib3) 2013; 94 Suryanarayana (bib17) 2001; 46 Green, Emery, Hishikawa, Warta, Dunlop (bib2) 2015; 23 Kanai, Aihara, Toyonaga, Araki, Takeuchi, Katagiri (bib7) 2014 Umehara, Takeda, Motohiro, Sakai, Awano, Maekawa (bib8) 2013; 6 Chen, Dou, Ni, Cheng, Zhuang (bib11) 2012; 376 Berg, Djemour, Gutay, Siebentritt, Dale, Fontane (bib22) 2012; 100 (bib1) 2015 Fernandes, Salomé, da Cunha (bib13) 2010; 43 Umehara, Takeda, Oh-ishi, Aoki, Motohiro, Sakai, Maekawa (bib14) 2015; 134 Kanai (10.1016/j.jallcom.2016.05.005_bib7) 2014 Onoda (10.1016/j.jallcom.2016.05.005_bib18) 2000; 35 Beleanu (10.1016/j.jallcom.2016.05.005_bib24) 2011; 44 Smith (10.1016/j.jallcom.2016.05.005_bib25) 2010; 43 Abermann (10.1016/j.jallcom.2016.05.005_bib3) 2013; 94 Lokhande (10.1016/j.jallcom.2016.05.005_bib6) 2016; 656 Rietveld (10.1016/j.jallcom.2016.05.005_bib15) 1969; 2 Neves (10.1016/j.jallcom.2016.05.005_bib5) 2016; 164 Tiwari (10.1016/j.jallcom.2016.05.005_bib21) 2014; 117 Umehara (10.1016/j.jallcom.2016.05.005_bib8) 2013; 6 Zhao (10.1016/j.jallcom.2016.05.005_bib9) 2013; 2013 Koike (10.1016/j.jallcom.2016.05.005_bib10) 2012; 51 Green (10.1016/j.jallcom.2016.05.005_bib2) 2015; 23 Fernandes (10.1016/j.jallcom.2016.05.005_bib13) 2010; 43 Unifantowicz (10.1016/j.jallcom.2016.05.005_bib19) 2008; 20 Suryanarayana (10.1016/j.jallcom.2016.05.005_bib17) 2001; 46 Zawadzki (10.1016/j.jallcom.2016.05.005_bib4) 2013; 103 (10.1016/j.jallcom.2016.05.005_bib1) 2015 Umehara (10.1016/j.jallcom.2016.05.005_bib14) 2015; 134 Berg (10.1016/j.jallcom.2016.05.005_bib22) 2012; 100 Kroumov (10.1016/j.jallcom.2016.05.005_bib23) 2003; 76 Avellaneda (10.1016/j.jallcom.2016.05.005_bib12) 2010; 157 Htay (10.1016/j.jallcom.2016.05.005_bib20) 2015; 140 Chen (10.1016/j.jallcom.2016.05.005_bib11) 2012; 376 Rodriguez-Carvajal (10.1016/j.jallcom.2016.05.005_bib16) 2001 |
References_xml | – volume: 2 start-page: 65 year: 1969 end-page: 71 ident: bib15 article-title: A profile refinement method for nuclear and magnetic structures publication-title: J. Appl. Crystallogr. contributor: fullname: Rietveld – volume: 51 start-page: 10NC34 year: 2012 ident: bib10 article-title: Cu publication-title: Jpn. J. Appl. Phys. contributor: fullname: Katagiri – volume: 43 start-page: 190 year: 2010 end-page: 200 ident: bib25 article-title: Semiconductor nanocrystals: structure, properties, and band gap engineering publication-title: Acc. Chem. Res. contributor: fullname: Nie – volume: 376 start-page: 327 year: 2012 end-page: 330 ident: bib11 article-title: Study and enhance the photovoltaic properties of narrow-bandgap Cu publication-title: J. Colloid Interface Sci. contributor: fullname: Zhuang – volume: 164 start-page: 165 year: 2016 end-page: 168 ident: bib5 article-title: Spark plasma sintering of Cu publication-title: Mater. Lett. contributor: fullname: Hanada – volume: 44 start-page: 475302 year: 2011 ident: bib24 article-title: Systematical, experimental investigations on LiMgZ (Z = P, As, Sb) wide band gap semiconductors publication-title: J. Phys. D Appl. Phys. contributor: fullname: Porcher – volume: 117 start-page: 1139 year: 2014 end-page: 1146 ident: bib21 article-title: Microwave-assisted rapid synthesis of tetragonal Cu publication-title: Appl. Phys. A contributor: fullname: Sathe – volume: 46 start-page: 1 year: 2001 end-page: 184 ident: bib17 article-title: Mechanical alloying and milling publication-title: Prog. Mater. Sci. contributor: fullname: Suryanarayana – volume: 76 start-page: 155 year: 2003 end-page: 170 ident: bib23 article-title: Bilbao crystallographic server : useful databases and tools for phase-transition studies publication-title: Ph. Transit contributor: fullname: Ivantchev – volume: 20 start-page: 025205 year: 2008 ident: bib19 article-title: Structural changes of silicon upon high-energy milling investigated by Raman spectroscopy publication-title: J. Phys. Condens. Matter contributor: fullname: Kurzydłowski – volume: 23 start-page: 805 year: 2015 end-page: 812 ident: bib2 article-title: Solar cell efficiency tables (version 46) publication-title: Prog. Photovolt. Res. Appl. contributor: fullname: Dunlop – volume: 94 start-page: 37 year: 2013 end-page: 70 ident: bib3 article-title: Non-vacuum processed next generation thin film photovoltaics: towards marketable efficiency and production of CZTS based solar cells publication-title: Sol. Energy contributor: fullname: Abermann – start-page: 1805 year: 2014 end-page: 1808 ident: bib7 article-title: Improving the Cu publication-title: Proceedings of the 29th European Photovoltaic Solar Energy Conference and Exhibition contributor: fullname: Katagiri – volume: 100 start-page: 192103 year: 2012 ident: bib22 article-title: Raman analysis of monoclinic Cu publication-title: Appl. Phys. Lett. contributor: fullname: Fontane – volume: 6 start-page: 045501 year: 2013 ident: bib8 article-title: Cu publication-title: Appl. Phys. Express contributor: fullname: Maekawa – year: 2001 ident: bib16 article-title: An Introduction to the Program Fullprof contributor: fullname: Rodriguez-Carvajal – volume: 140 start-page: 312 year: 2015 end-page: 319 ident: bib20 article-title: Influence of Ge composition in the Cu publication-title: Sol. Energy Mat. Sol. C. contributor: fullname: Taishi – volume: 35 start-page: 1563 year: 2000 end-page: 1570 ident: bib18 article-title: Crystal structure and twinning of monoclinic Cu publication-title: Mat. Res. Bull. contributor: fullname: Wada – volume: 134 start-page: 1 year: 2015 end-page: 4 ident: bib14 article-title: Energy level diagram around Ge-rich grain boundaries in Cu publication-title: Sol. Energy Mat. Sol. Cell. contributor: fullname: Maekawa – volume: 2013 start-page: 4 year: 2013 ident: bib9 article-title: Influence of sulfurization temperature on photoelectric properties Cu publication-title: Adv. Mater. Sci. Eng. contributor: fullname: Cheng – volume: 656 start-page: 295 year: 2016 end-page: 310 ident: bib6 article-title: chemical synthesis of Cu2SnS3 (CTS) nanoparticles: a status review publication-title: J. Alloys Compd. contributor: fullname: Kim – year: 2015 ident: bib1 publication-title: Fraunhofer ISE: Photovoltaics Report – volume: 43 start-page: 215403 year: 2010 ident: bib13 article-title: A study of ternary Cu publication-title: J. Phys. D Appl. Phys. contributor: fullname: da Cunha – volume: 103 start-page: 253902 year: 2013 ident: bib4 article-title: Evaluation of photovoltaic materials within the Cu-Sn-S family publication-title: Appl. Phys. Lett. contributor: fullname: Ginley – volume: 157 start-page: D346 year: 2010 end-page: D352 ident: bib12 article-title: Cu publication-title: J. Electrochem. Soc. contributor: fullname: Nair – volume: 44 start-page: 475302 year: 2011 ident: 10.1016/j.jallcom.2016.05.005_bib24 article-title: Systematical, experimental investigations on LiMgZ (Z = P, As, Sb) wide band gap semiconductors publication-title: J. Phys. D Appl. Phys. doi: 10.1088/0022-3727/44/47/475302 contributor: fullname: Beleanu – volume: 6 start-page: 045501 year: 2013 ident: 10.1016/j.jallcom.2016.05.005_bib8 article-title: Cu2Sn1-xGexS3 (x = 0.17) thin-film solar cells with high conversion efficiency of 6.0% publication-title: Appl. Phys. Express doi: 10.7567/APEX.6.045501 contributor: fullname: Umehara – volume: 94 start-page: 37 year: 2013 ident: 10.1016/j.jallcom.2016.05.005_bib3 article-title: Non-vacuum processed next generation thin film photovoltaics: towards marketable efficiency and production of CZTS based solar cells publication-title: Sol. Energy doi: 10.1016/j.solener.2013.04.017 contributor: fullname: Abermann – volume: 2 start-page: 65 issue: 2 year: 1969 ident: 10.1016/j.jallcom.2016.05.005_bib15 article-title: A profile refinement method for nuclear and magnetic structures publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889869006558 contributor: fullname: Rietveld – volume: 134 start-page: 1 year: 2015 ident: 10.1016/j.jallcom.2016.05.005_bib14 article-title: Energy level diagram around Ge-rich grain boundaries in Cu2Sn1-xGexS3 (CTGS) thin-film solar cells publication-title: Sol. Energy Mat. Sol. Cell. doi: 10.1016/j.solmat.2014.11.024 contributor: fullname: Umehara – volume: 2013 start-page: 4 year: 2013 ident: 10.1016/j.jallcom.2016.05.005_bib9 article-title: Influence of sulfurization temperature on photoelectric properties Cu2SnS3 thin films deposited by magnetron sputtering publication-title: Adv. Mater. Sci. Eng. doi: 10.1155/2013/726080 contributor: fullname: Zhao – volume: 103 start-page: 253902 year: 2013 ident: 10.1016/j.jallcom.2016.05.005_bib4 article-title: Evaluation of photovoltaic materials within the Cu-Sn-S family publication-title: Appl. Phys. Lett. doi: 10.1063/1.4851896 contributor: fullname: Zawadzki – volume: 46 start-page: 1 year: 2001 ident: 10.1016/j.jallcom.2016.05.005_bib17 article-title: Mechanical alloying and milling publication-title: Prog. Mater. Sci. doi: 10.1016/S0079-6425(99)00010-9 contributor: fullname: Suryanarayana – volume: 656 start-page: 295 year: 2016 ident: 10.1016/j.jallcom.2016.05.005_bib6 article-title: chemical synthesis of Cu2SnS3 (CTS) nanoparticles: a status review publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2015.09.232 contributor: fullname: Lokhande – year: 2001 ident: 10.1016/j.jallcom.2016.05.005_bib16 contributor: fullname: Rodriguez-Carvajal – year: 2015 ident: 10.1016/j.jallcom.2016.05.005_bib1 – start-page: 1805 year: 2014 ident: 10.1016/j.jallcom.2016.05.005_bib7 article-title: Improving the Cu2SnS3 PV cell efficiency via post treatment of co-evaporated thin films contributor: fullname: Kanai – volume: 157 start-page: D346 issue: 6 year: 2010 ident: 10.1016/j.jallcom.2016.05.005_bib12 article-title: Cu2SnS3 and Cu4SnS4 thin films via chemical deposition for photovoltaic application publication-title: J. Electrochem. Soc. doi: 10.1149/1.3384660 contributor: fullname: Avellaneda – volume: 100 start-page: 192103 year: 2012 ident: 10.1016/j.jallcom.2016.05.005_bib22 article-title: Raman analysis of monoclinic Cu2SnS3 thin films publication-title: Appl. Phys. Lett. doi: 10.1063/1.4712623 contributor: fullname: Berg – volume: 43 start-page: 190 year: 2010 ident: 10.1016/j.jallcom.2016.05.005_bib25 article-title: Semiconductor nanocrystals: structure, properties, and band gap engineering publication-title: Acc. Chem. Res. doi: 10.1021/ar9001069 contributor: fullname: Smith – volume: 164 start-page: 165 year: 2016 ident: 10.1016/j.jallcom.2016.05.005_bib5 article-title: Spark plasma sintering of Cu2SnS3 powders synthesized by mechanical alloying publication-title: Mater. Lett. doi: 10.1016/j.matlet.2015.10.153 contributor: fullname: Neves – volume: 376 start-page: 327 year: 2012 ident: 10.1016/j.jallcom.2016.05.005_bib11 article-title: Study and enhance the photovoltaic properties of narrow-bandgap Cu2SnS3 solar cell by p–n junction interface modification publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2012.03.015 contributor: fullname: Chen – volume: 43 start-page: 215403 year: 2010 ident: 10.1016/j.jallcom.2016.05.005_bib13 article-title: A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors publication-title: J. Phys. D Appl. Phys. doi: 10.1088/0022-3727/43/21/215403 contributor: fullname: Fernandes – volume: 51 start-page: 10NC34 year: 2012 ident: 10.1016/j.jallcom.2016.05.005_bib10 article-title: Cu2SnS3 thin-film solar cells from electroplated precursors publication-title: Jpn. J. Appl. Phys. doi: 10.7567/JJAP.51.10NC34 contributor: fullname: Koike – volume: 140 start-page: 312 year: 2015 ident: 10.1016/j.jallcom.2016.05.005_bib20 article-title: Influence of Ge composition in the Cu2Sn1-xGexS3 thin-film photovoltaic absorber prepared by sulfurization of laminated metallic precursor publication-title: Sol. Energy Mat. Sol. C. doi: 10.1016/j.solmat.2015.04.030 contributor: fullname: Htay – volume: 20 start-page: 025205 issue: 2 year: 2008 ident: 10.1016/j.jallcom.2016.05.005_bib19 article-title: Structural changes of silicon upon high-energy milling investigated by Raman spectroscopy publication-title: J. Phys. Condens. Matter doi: 10.1088/0953-8984/20/02/025205 contributor: fullname: Unifantowicz – volume: 117 start-page: 1139 year: 2014 ident: 10.1016/j.jallcom.2016.05.005_bib21 article-title: Microwave-assisted rapid synthesis of tetragonal Cu2SnS3 nanoparticles for solar photovoltaics publication-title: Appl. Phys. A doi: 10.1007/s00339-014-8484-2 contributor: fullname: Tiwari – volume: 23 start-page: 805 year: 2015 ident: 10.1016/j.jallcom.2016.05.005_bib2 article-title: Solar cell efficiency tables (version 46) publication-title: Prog. Photovolt. Res. Appl. doi: 10.1002/pip.2637 contributor: fullname: Green – volume: 76 start-page: 155 year: 2003 ident: 10.1016/j.jallcom.2016.05.005_bib23 article-title: Bilbao crystallographic server : useful databases and tools for phase-transition studies publication-title: Ph. Transit doi: 10.1080/0141159031000076110 contributor: fullname: Kroumov – volume: 35 start-page: 1563 year: 2000 ident: 10.1016/j.jallcom.2016.05.005_bib18 article-title: Crystal structure and twinning of monoclinic Cu2SnS3 publication-title: Mat. Res. Bull. doi: 10.1016/S0025-5408(00)00347-0 contributor: fullname: Onoda |
SSID | ssj0001931 |
Score | 2.3136652 |
Snippet | Cu2SnS3 (CTS) and Cu2Sn0.83Ge0.17S3 (CTGS) compounds were successfully prepared by a powder technology using a combination of mechanical alloying (MA) and... |
SourceID | crossref elsevier |
SourceType | Aggregation Database Publisher |
StartPage | 489 |
SubjectTerms | Cu2(Sn,Ge)S3 (CTGS) Cu2SnS3 (CTS) Electron microprobe analysis Powder technology Rietveld analysis Semiconductors |
Title | Structural characterization of Cu2SnS3 and Cu2(Sn,Ge)S3 compounds |
URI | https://dx.doi.org/10.1016/j.jallcom.2016.05.005 |
Volume | 682 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LS8NAEB76QNSDaFWsj5KDBwXTJrvJdvdYirUq9lILvYXsI9BS0kLr1d_ubB61gnjwlixZWL6Eb77dzHwDcCuk0Ip0fWS_IHGDWAuXU65daSiV3FexT2xx8tuIDSfByzScVqBf1sLYtMqC-3NOz9i6GOkUaHZWs1ln7Ali__lxVBQYtAStQh3DURDUoN57fh2OtoSMGiVrnIfP24Xw70Kezrw9jxcLmzeCgZBlHp62kd1vIWon7AyO4ajQi04vX9IJVEzagP1-2aatAYc7joIN2MsyOtX6FPkyc4a1rhqO2roy50WXzjJx-h9knI6pE6faXt-N04cnc48DNsnc9lpan8Fk8PjeH7pFvwRXEeFtXJ9Je4xDtZZEJzxRkiYKd5u-EJJKERAtKdOEGoRLac5UyE1XEU006rqQS3oOtXSZmgtw4pCzMBbGMK4C4enYQxnDUI3rkJmYB01olxBFq9wWIyrzxeZRgWlkMY28MEJMm8BLIKMf7zdC6v576uX_p17Bgb2zscYPr6GGwJsbFBEb2YJq-9NvFZ_KF7s6xNM |
link.rule.ids | 315,786,790,4521,24144,27955,27956,45618,45712 |
linkProvider | Elsevier |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1NS8NAEB20ItWDaFWsnzl4UDBtsptsd48S1Pp5iUJvS_Yj0FLSQuvV3-5smmgF8eAtbLKwvF3evCRvZgDOhRJGk16I7BflfpQZ4XPKja8spYqHOguJS05-fmH9t-hhEA9WIKlzYZytsuL-BaeXbF2NdCs0u9PhsJsGgrh_fhwVBQYtQVdhzakB5-vqfHz7PFChlG3z8Gm3DP6dxtMddUbZeOxcIxgGWVnB07Wx-y1ALQWd223YqtSid71Y0A6s2KIFzaRu0taCzaV6gi1YL_2ceraLbFnWhXU1NTz9VZN5kXLpTXIveSdpkVIvK4y7vkiLqzt7iQPOYu46Lc324O325jXp-1W3BF8TEcz9kCn3EYcao4jJea4VzTW-a4ZCKKpERIyizBBqESxtONMxtz1NDDGo6mKu6D40iklhD8DLYs7iTFjLuI5EYLIARQxDLW5iZjMetaFTQySni6IYsnaLjWSFqXSYyiCWiGkbeA2k_LG7Eon776mH_596Bs3-6_OTfLp_eTyCDXfHRZ0wPoYGboI9QTkxV6flcfkEchvFqA |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Structural+characterization+of+Cu2SnS3+and+Cu2%28Sn%2CGe%29S3+compounds&rft.jtitle=Journal+of+alloys+and+compounds&rft.au=Neves%2C+F.&rft.au=Correia%2C+J.B.&rft.au=Hanada%2C+K.&rft.au=Santos%2C+L.F.&rft.date=2016-10-15&rft.issn=0925-8388&rft.volume=682&rft.spage=489&rft.epage=494&rft_id=info:doi/10.1016%2Fj.jallcom.2016.05.005&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_jallcom_2016_05_005 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0925-8388&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0925-8388&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0925-8388&client=summon |