Sharp and bright photoluminescence emission of single-crystalline diacetylene nanoparticles

Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The si...

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Published inJournal of the Korean Physical Society Vol. 69; no. 3; pp. 412 - 415
Main Authors Kim, Seokho, Kim, Hyeong Tae, Park, Dong Hyuk, Xianling, Piao, Cui, Chunzhi
Format Journal Article
LanguageEnglish
Published Seoul The Korean Physical Society 01.08.2016
Springer Nature B.V
한국물리학회
Subjects
Crystal structure
Mathematical and Computational Physics
Nanoparticles
Particle and Nuclear Physics
Photoluminescence
Physics
Physics and Astronomy
Single crystals
Theoretical
Transmission electron microscopy
물리학
Solvent-vapor annealing
Crystallinity
PCDA
Photoluminescence
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Abstract Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The single crystal structure of DA NPs was confirmed by using high-resolution transmission electron microscopy (HR-TEM) and wide angle X-ray scattering (WAXS). The luminescence color and the photoluminescence (PL) characteristics of the DA NPs were measured using color charge-coupled device (CCD) images and high-resolution laser confocal microscope (LCM). The crystalline DA NPs, emit bright green light compared with amorphous DA NPs and the main PL peak of the crystalline DA NPs exhibits relatively narrow, blue-shift phenomena due to enhanced interactions between the DA molecules in the nano-size crystal structure.
AbstractList Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The single crystal structure of DA NPs was confirmed by using high-resolution transmission electron microscopy (HR-TEM) and wide angle X-ray scattering (WAXS). The luminescence color and the photoluminescence (PL) characteristics of the DA NPs were measured using color charge-coupled device (CCD) images and high-resolution laser confocal microscope (LCM). The crystalline DA NPs, emit bright green light compared with amorphous DA NPs and the main PL peak of the crystalline DA NPs exhibits relatively narrow, blue-shift phenomena due to enhanced interactions between the DA molecules in the nano-size crystal structure.
Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The single crystal structure of DA NPs was confirmed by using high-resolution transmission electron microscopy (HR-TEM) and wide angle X-ray scattering (WAXS). The luminescence color and the photoluminescence (PL) characteristics of the DA NPs were measured using color charge-coupled device (CCD) images and high-resolution laser confocal microscope (LCM). The crystalline DA NPs, emit bright green light compared with amorphous DA NPs and the main PL peak of the crystalline DA NPs exhibits relatively narrow, blue-shift phenomena due to enhanced interactions between the DA molecules in the nano-size crystal structure. KCI Citation Count: 0
Author Cui, Chunzhi
Xianling, Piao
Park, Dong Hyuk
Kim, Seokho
Kim, Hyeong Tae
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Snippet Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through a solvent-vapor...
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StartPage 412
SubjectTerms Crystal structure
Mathematical and Computational Physics
Nanoparticles
Particle and Nuclear Physics
Photoluminescence
Physics
Physics and Astronomy
Single crystals
Theoretical
Transmission electron microscopy
물리학
Title Sharp and bright photoluminescence emission of single-crystalline diacetylene nanoparticles
URI https://link.springer.com/article/10.3938/jkps.69.412
https://www.proquest.com/docview/1880742393
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Volume 69
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ispartofPNX Journal of the Korean Physical Society, 2016, 69(3), , pp.412-415
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