Oxygen‐Linked Cyclopentadienyl Rhodium(III) Complexes‐Catalyzed Asymmetric C−H Arylation of Benzo[h]quinolines with 1‐Diazonaphthoquinones

• Published in: Angewandte Chemie International Edition Vol. 60; no. 28; pp. 15510 - 15516
• Main Authors: Pan, Chongqing, Yin, Si‐Yong, Wang, Shao‐Bo, Gu, Qing, You, Shu‐Li
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 05.07.2021
• Subjects: axial chirality; Chemistry; Chemistry, Multidisciplinary; chiral cyclopentadienyl; heterobiaryl; Physical Sciences; rhodium; Science & Technology; heterobiaryl; ACTIVATION; ENANTIOSELECTIVE SYNTHESIS; CHIRAL (CPRH)-RH-X; ALKYLATION; BIARYL COMPOUNDS; axial chirality; FUNCTIONALIZATION; OLEFINATION; LIGANDS; CONSTRUCTION; chiral cyclopentadienyl; BOND; rhodium

Chiral cyclopentadienyl rhodium (CpRh) complex‐catalyzed asymmetric C−H functionalization reactions have witnessed a significant progress in organic synthesis. In sharp contrast, the reported chiral Cp ligands are limited to C‐linked Cp and are often synthetically challenging. To address these issue...