Catalytic systems based on the organic nickel(ii) complexes in chronoamperometric determination of urea and creatinine

The organic nickel( ii ) complexes with catalytic activity in the electrochemical oxidation of creatinine and urea were synthesized and studied. The signals of electrocatalytic oxidation of the studied carbonyl-containing amines in model solutions were obtained. The detection limit (by the 3σ-criter...

Full description

Saved in:
Bibliographic Details
Published inRussian chemical bulletin Vol. 58; no. 6; pp. 1119 - 1125
Main Authors Kozitsina, A. N., Shalygina, Zh. V., Dedeneva, S. S., Rusinov, G. L., Tolshchina, S. G., Verbitskiy, E. V., Brainina, Kh. Z.
Format Journal Article
LanguageEnglish
Published Boston Springer US 01.06.2009
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
creatinine
voltammetry
organic nickel
chronoamperometry
electrocatalysis
urea
complexes
Online AccessGet full text

Cover

More Information
Summary:The organic nickel( ii ) complexes with catalytic activity in the electrochemical oxidation of creatinine and urea were synthesized and studied. The signals of electrocatalytic oxidation of the studied carbonyl-containing amines in model solutions were obtained. The detection limit (by the 3σ-criterion) is 8.7·10 −6 and 2.7·10 −5 mol L −1 for urea and creatinine, respectively.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-009-0145-9