Trichloro- and methyldichlorogermyl monochelates and dibromo- and dichlorogermyl bischelates derived from N,N-disubstituted amides of 2-hydroxycarboxylic acids

• Published in: Russian chemical bulletin Vol. 61; no. 3; pp. 642 - 651
• Main Authors: Airapetyan, D. V., Murasheva, T. P., Bylikin, S. Yu, Korlyukov, A. A., Shipov, A. G., Gruener, S. V., Kramarova, E. P., Negrebetskii, Vad. V., Pogozhikh, S. A., Zueva, G. Ya, Antipin, M. Yu, Baukov, Yu. I.
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.03.2012
• Subjects: Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Full Article; Inorganic Chemistry; Organic Chemistry; synthesis; X-ray diffraction study; penta- and hexacoordinate germanium compounds

The reactions of GeCl 4 , GeBr 4 , and MeGeCl 3 with O -trimethylsilyl derivatives of N,N -disubstituted amides of 2-hydroxycarboxylic acids afforded pentacoordinate and hexacoordinate neutral (O,O)-mono- and (O,O)-bischelates. The reactions of glycolic acid derivatives with GeX 4 produced bischelat...