Photoelectron spectroscopy and electronic structures of β-diketonate complexes of rare-earth elements
The electronic structures of lanthanide tris(β-diketonate) complexes and their adducts, being of interest as luminophores, were studied by UV photoelectron spectroscopy of vapors and X-ray photoelectron spectroscopy. The spectral regularities identified by the density functional theory revealed the...
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| Published in | Russian chemical bulletin Vol. 64; no. 8; pp. 1701 - 1712 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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New York
Springer US
01.08.2015
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1066-5285 1573-9171 |
| DOI | 10.1007/s11172-015-1066-4 |
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| Abstract | The electronic structures of lanthanide tris(β-diketonate) complexes and their adducts, being of interest as luminophores, were studied by UV photoelectron spectroscopy of vapors and X-ray photoelectron spectroscopy. The spectral regularities identified by the density functional theory revealed the influence of the substitution of the Me groups in the ligands by Bu
t
, CF
3
, and neutral ligand in the adducts on the electronic structure of the complexing agent from Pr to Lu. |
|---|---|
| AbstractList | The electronic structures of lanthanide tris(β-diketonate) complexes and their adducts, being of interest as luminophores, were studied by UV photoelectron spectroscopy of vapors and X-ray photoelectron spectroscopy. The spectral regularities identified by the density functional theory revealed the influence of the substitution of the Me groups in the ligands by Bu
t
, CF
3
, and neutral ligand in the adducts on the electronic structure of the complexing agent from Pr to Lu. |
| Author | Vovna, V. I. Shurygin, A. V. Cherednichenko, A. I. Korochentsev, V. V. |
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| CitedBy_id | crossref_primary_10_1007_s11172_022_3522_2 crossref_primary_10_1038_s41598_019_51171_3 crossref_primary_10_1016_j_molstruc_2017_10_110 crossref_primary_10_1134_S0022476619120084 crossref_primary_10_1016_j_saa_2019_01_033 crossref_primary_10_1134_S0022476617060087 crossref_primary_10_1016_j_molstruc_2020_128815 crossref_primary_10_1039_C7CP08366A crossref_primary_10_1016_j_sna_2023_114828 crossref_primary_10_1007_s11172_017_1984_4 crossref_primary_10_1007_s11172_022_3485_3 crossref_primary_10_1016_j_saa_2020_119397 crossref_primary_10_1134_S0022476618020105 crossref_primary_10_1039_D5DT00219B crossref_primary_10_1016_j_jlumin_2018_09_027 |
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| Keywords | photoelectron spectroscopy adducts of chelate complexes density functional theory electronic structure lanthanides |
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| Snippet | The electronic structures of lanthanide tris(β-diketonate) complexes and their adducts, being of interest as luminophores, were studied by UV photoelectron... |
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| Title | Photoelectron spectroscopy and electronic structures of β-diketonate complexes of rare-earth elements |
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