Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids as carriers of Fe(III) picrates
Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids, exhibiting anti-tubercular activity, transport Fe(III) through liquid chloroform membrane which models a cell membrane. It is revealed that fluxes and anti-tubercular activity increase, as the length of the chain (spacer) between...
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Published in | Journal of Inclusion Phenomena and Macrocyclic Chemistry Vol. 60; no. 1-2; pp. 51 - 58 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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Dordrecht
Springer Netherlands
01.02.2008
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Abstract | Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids, exhibiting anti-tubercular activity, transport Fe(III) through liquid chloroform membrane which models a cell membrane. It is revealed that fluxes and anti-tubercular activity increase, as the length of the chain (spacer) between two
ent
-beyran skeletons of diesters increases. Computations on the level DFT/PBE explain the dependence of complexes stability on a structure of diterpenoid ligands. The structures of three diesters were established by single crystal X-ray analysis. |
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AbstractList | Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids, exhibiting anti-tubercular activity, transport Fe(III) through liquid chloroform membrane which models a cell membrane. It is revealed that fluxes and anti-tubercular activity increase, as the length of the chain (spacer) between two
ent
-beyran skeletons of diesters increases. Computations on the level DFT/PBE explain the dependence of complexes stability on a structure of diterpenoid ligands. The structures of three diesters were established by single crystal X-ray analysis. |
Author | Gubaidullin, Aidar T. Zverev, Vladislav V. Strobykina, Irina Yu Valova, Marina S. Kataev, Vladimir E. Kataeva, Olga N. Militsina, Olesya I. Fedorova, Olga V. Rusinov, Gennadiy L. |
Author_xml | – sequence: 1 givenname: Vladimir E. surname: Kataev fullname: Kataev, Vladimir E. email: kataev@iopc.knc.ru organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 2 givenname: Olesya I. surname: Militsina fullname: Militsina, Olesya I. organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 3 givenname: Irina Yu surname: Strobykina fullname: Strobykina, Irina Yu organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 4 givenname: Aidar T. surname: Gubaidullin fullname: Gubaidullin, Aidar T. organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 5 givenname: Vladislav V. surname: Zverev fullname: Zverev, Vladislav V. organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 6 givenname: Olga N. surname: Kataeva fullname: Kataeva, Olga N. organization: A. E. Arbuzov Institute of Organic and Physical Chemistry – sequence: 7 givenname: Olga V. surname: Fedorova fullname: Fedorova, Olga V. organization: Institute of Organic Synthesis UrB RAS – sequence: 8 givenname: Marina S. surname: Valova fullname: Valova, Marina S. organization: Institute of Organic Synthesis UrB RAS – sequence: 9 givenname: Gennadiy L. surname: Rusinov fullname: Rusinov, Gennadiy L. organization: Institute of Organic Synthesis UrB RAS |
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Keywords | Siderophores Diterpenoids Isosteviol Beyerans Anti-tubercular activity Transport of Fe(III) |
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Snippet | Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids, exhibiting anti-tubercular activity, transport Fe(III) through liquid chloroform membrane... |
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SubjectTerms | Chemistry Chemistry and Materials Science Crystallography and Scattering Methods Food Science Organic Chemistry Original Article |
Title | Diesters on the basis of 16-hydroxyisosteviol and dicarboxylic acids as carriers of Fe(III) picrates |
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