Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are conside...

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Bibliographic Details
Published inRussian journal of organic chemistry Vol. 50; no. 4; pp. 489 - 493
Main Authors Kiselev, V. D., Kornilov, D. A., Kashaeva, E. A., Potapova, L. N., Konovalov, A. I.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.04.2014
Springer Nature
Subjects
Chemistry
Chemistry and Materials Science
Chemistry, Organic
Organic Chemistry
Physical Sciences
Science & Technology
Maleic Anhydride
Cyclopentadiene
Dimethyl Fumarate
Fumaric Acid
Alder Reaction
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Summary:The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428014040071